Alejandro Sánchez Valenzuela

Michel De Saint Blanquat

Francisco Hervé

Mireille Polvé

Diego Morata

Phillipe De Parseval

Benoit Benoit

Alejandro Sánchez
email: alejandro.sanchez.v@usach.cl

Michel De Saint-Blanquat

Mathieu Benoit

Geochemistry of Cenozoic plutonic rocks in the extra-Andean southern Patagonia as evidence for a magmatic arc migration process

Keywords: Plutonism, Cenozoic, Patagonia, geochemistry, back-arc Plutonismo, Cenozoico, Patagonia, geoquímica, tras-arco

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Introduction

Igneous rocks are widely distributed in southern Patagonia, from the latitude of the Chile Triple Junction to the south, in the form of several magmatic units. Among these rocks, the South Patagonian batholith (SPB) records episodic Jurassic to Neogene arc magmatism (e.g., [START_REF] Weaver | The Patagonian Batholith at 48°S latitude, Chile: geochemical and isotopic variations[END_REF][START_REF] Bruce | Temporal and spatial variations in the southern Patagonian batholith; constraints on magmatic arc development[END_REF], Hervé et al., 2007), while effusive rocks (plateau lavas and volcanic fields), distributed throughout the Patagonian back-arc region (Fig. 1), have been emplaced since the Paleocene (see reviews in D' Orazio et al., 2004;[START_REF] Guivel | Miocene to Late Quaternary Patagonian basalts (46-478S): Geochronometric and geochemical evidence for slab tearing due to active spreading ridge subduction[END_REF]. Arc and back-arc magmatism have been the focus of several studies aimed to decipher the genesis, magmatic evolution, and/or emplacements of the magmas in a continental crust environment, as well as to determine the extent to which subduction of active ridges under Patagonia has been involved in these processes since the Eocene, especially in the back-arc domain (e.g. [START_REF] Charrier | K-Ar ages of basalt flows of the Meseta Buenos Aires in southern Chile and their relation to the southeast Pacific triple junction[END_REF][START_REF] Cande | Late Cenozoic tectonics of the Southern Chile Trench[END_REF][START_REF] Stern | Trace element and Sr, Nd, Pb, and O isotopic composition of Pliocene and Quaternary alkali basalts of the Patagonian Plateau lavas of southernmost South America[END_REF][START_REF] Ramos | Southern Patagonian plateau basalts and deformation: backarc testimony of ridge collision[END_REF][START_REF] Gorring | Neogene Patagonian plateau lavas; continental magmas associated with ridge collision at the Chile triple junction[END_REF][START_REF] Gorring | Plio-pleistocene basalts from the Meseta del Lago Buenos Aires, Argentina: evidence for asthenospherelithosphere interactions during slab window magmatism[END_REF][START_REF] D'orazio | Slab window-related magmatism from southernmost South America: the Late Miocene mafic volcanics from the Estancia Glencross Area; ~52°S, Argentina-Chile[END_REF][START_REF] D'orazio | The Late Pliocene mafic lavas from the Camusú Aike volcanic field (~50°S, Argentina): Evidences for a geochemical variability in slab window Andean[END_REF][START_REF] Espinoza | Petrogenesis of the Eocene and Mio-Pliocene alkaline basaltic magmatism in Meseta Chile Chico, Southern Patagonia, Chile: evidence for the participation of two slab windows[END_REF][START_REF] Espinoza | Volcanismo calcoalcalino durante el Mioceno Medio en Patagonia Central (47°S): petrogénesis e implicaciones en la dinámica de placas[END_REF][START_REF] Guivel | Miocene to Late Quaternary Patagonian basalts (46-478S): Geochronometric and geochemical evidence for slab tearing due to active spreading ridge subduction[END_REF]. Using geochemistry and geochronology as main tools, some of the plateau lavas have been linked genetically to a slab window beneath Patagonia, which opened due to the subduction of the Chile Rise active spreading center. Some hypotheses suggest a slab tear -instead of a slab window-previous to the opening of the slab window to explain some of the magmatism, while others suggest a transitional geochemical character from arc to back-arc setting (reviews in D' Orazio et al., 2004;[START_REF] Guivel | Miocene to Late Quaternary Patagonian basalts (46-478S): Geochronometric and geochemical evidence for slab tearing due to active spreading ridge subduction[END_REF][START_REF] Espinoza | Volcanismo calcoalcalino durante el Mioceno Medio en Patagonia Central (47°S): petrogénesis e implicaciones en la dinámica de placas[END_REF]. and 3 boxes. Map after [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF].

Andean Geology 48 (3): xxx-xxx. September, 2021 doi: 10.5027/andgeoV48n3-3158

I N P R E S S

In this work we present new field relationships, petrographic and geochemical (major, trace elements and Sr-Nd isotope ratios) data for 7 plutons of the intrusive bodies mentioned above, 4 at the northern end of the belt and 3 in the southern part (Fig. 1). The geochemical data show varying patterns, which

Between the SPB and the plateaus lavas, in the extra-Andean region, a belt of plutons crops out with a north-south trend, firstly recognized by [START_REF] Michael | Emplacement and differentiation of Miocene plutons in the Andean[END_REF] (Fig. 1). Even though, several studies have been carried out in these plutons to decipher the nature of the magmatism that generates them, most of them have been focused on single plutons or restricted areas (e.g. [START_REF] Nullo | Estratigrafía y tectónica de la vertiente este del hielo continental patagónico, Argentina-Chile[END_REF][START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF][START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF][START_REF] Welkner | Geología del área del cerro San Lorenzo: Cordillera Patagónica Oriental, XI Región de Aysén[END_REF][START_REF] Michel | Incremental growth of the Patagonian Torres del Paine laccolith over 90 k.y[END_REF][START_REF] Ramírez De Arellano | Magmatic history of the Fitz Roy Plutonic Complex, Southern Patagonia (Argentina)[END_REF], 2012a;[START_REF] Leuthold | Time resolved construction of a bimodal laccolith (Torres del Paine, Patagonia)[END_REF][START_REF] Leuthold | A detailed geochemical study of a shallow, arc-related laccolith: the Torres del Paine mafic complex, Patagonia[END_REF]. As for the plateau lavas, the ridge collision and its subsequent subduction beneath the South American Plate has also been proposed as a trigger process for the plutonism of this belt [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF], because the age of the Torres del Paine laccolith -one of these plutonscoincides roughly with the timing of the Chile Rise collision. This interpretation has been made assuming that this whole plutonic suite shares common characteristics, a reasoning that could easily lead to erroneous conclusions.

Furthermore, this belt has not been studied in detail and, as already indicated by [START_REF] Sánchez | Different plutonic events in extra-andine southern Patagonia, Chile[END_REF] or Ramírez de Arellano (2012b), these plutons do not exhibit a homogeneous geochemical character. Thus, a more detailed and integrative work was conducted on them with the main aim to elucidate the geochemical features along the plutonic suite and to find possible patterns to enlighten the nature of this heterogeneity.

Andean Geology 48 (3): xxx-xxx. September, 2021 doi: 10.5027/andgeoV48n3-3158 6 I N P R E S S evidence a more complex origin for this belt than previously thought, with a range in alkalinity from calc-alkaline (s.s.) to alkaline (s.s.). We propose a subdivision of the transitional character based on petrography and geochemical data of the studied and reviewed plutons. Finally, we use these data to explore possible geological scenarios during the Miocene that could explain this wide geochemical range observed in the plutonism, considering previously proposed hypotheses for single plutons and the role of the Chile Rise subduction. The arc migration hypothesis believed to be a main process at the mid-Miocene (following [START_REF] Gorring | Neogene Patagonian plateau lavas; continental magmas associated with ridge collision at the Chile triple junction[END_REF][START_REF] Espinoza | Volcanismo calcoalcalino durante el Mioceno Medio en Patagonia Central (47°S): petrogénesis e implicaciones en la dinámica de placas[END_REF], where arc magmatism shifted eastward, involves several factors with a variable degree of importance, such as crust/sublithospheric mantle/astenospheric mantle melt interaction [START_REF] Espinoza | Volcanismo calcoalcalino durante el Mioceno Medio en Patagonia Central (47°S): petrogénesis e implicaciones en la dinámica de placas[END_REF].

In this sense, the melting, assimilation, storage and homogenization (MASH) zone hypothesis [START_REF] Hildreth | Crustal contributions to arc magmatism in the Andes of Central Chile[END_REF] allows us to consider all these variables to support geochemical diversity, supposing that this MASH zone was generated the extra-Andean domain by arc migration and evolved in different ways according to the particular tectonic scenarios at the time and location of the studied plutons.

The plutons included in this work are divided in two areas accord to its geographic location and tectonic particularities (Figure 1): the northern area includes the Miocene Paso de Las Llaves, Cerro Negro del Ghío, and San Lorenzo plutons and the Pliocene Río de las Nieves, and alkaline plutons in Meseta del Lago Buenos Aires (Figure 2). In the southern area Torres del Paine and Monte Balmaceda intrusive complexes, the Paine External Gabbros and the Cerro Donoso pluton are considered (Figure 3). complex, the Paine External Gabbros, Cerro Donoso pluton and Monte Balmaceda intrusive complex. Geology after [START_REF] Stewart | Estudio geológico económico de la Cordillera Patagónica entre los paralelos 51º00 y 53º30 Lat. S, provincia de Magallanes[END_REF]; [START_REF] Muñoz | Geología y petrología de las rocas igneas e inclusiones ultramáficas del sector SW de Meseta Las Vizcachas[END_REF]; [START_REF] Soffia | Interpretación estructural del sector Laguna Amarga, Parque Nacional Torres del Paine. Región de Ultima Esperanza, Magallanes-Chile[END_REF]; [START_REF] Wilson | Transition from a back-arc to foreland basin development in the southernmost Andes: Stratigraphic record from the Ultima Esperanza District, Chile[END_REF]; [START_REF] Sernageomin | Mapa Geológico de Chile[END_REF]; [START_REF] Fildani | Initiation of the Magallanes foreland basin: timing of the southernmost Patagonian Andes orogeny revised by detrital zircon provenance analysis[END_REF]; Fault zones from [START_REF] Altenberger | of the Cenozoic magmatism at the Torres del Paine, southern Andes (Chile, 51°10'S)[END_REF].

Andean Geology 48 (3): xxx-xxx. September, 2021 doi: 10.5027/andgeoV48n3-3158 9 I N P R E S S

Geological Setting

All along the southwestern Patagonia margin, from the Chile Triple Junction (ca. 46° 30' S) to the south, metasedimentary rocks crop out. They consist predominantly of polydeformed metaturbidites originally deposited in a passive continental margin [START_REF] Faúndez | Provenance and depositional setting of pre-Late Jurassic turbidite complexes in Patagonia, Chile[END_REF] between late Devonian and late

Permian [START_REF] Hervé | Detrital zircon age patterns and provenance of the metamorphic complexes of southern Chile[END_REF]. They are unconformably covered by Upper Jurassic -Lower Cretaceous silicic volcanic rocks associated to rift processes pre Gondwana break-up [START_REF] Feraud | Ar/Ar dating of the Jurassic volcanic province of Patagonia: migrating magmatism related to Gondwana break-up and subduction[END_REF][START_REF] Pankhurst | Episodic silicic volcanism in Patagonia and the Antarctic peninsula: chronology of magmatism associated with the breakup of Gondwana[END_REF]. These rocks are widely distributed in south Patagonia and are locally known by various formation names, for example, Ibáñez, El Quemado, Tobífera and Lemaire in northern, central, and southern Patagonia, and Tierra del Fuego (Argentina), respectively. In the north of the studied area (El Quemado and Ibáñez formations, hereafter Ibáñez Group), they consist of Upper Jurassic subaerial rhyolites (Suárez and De la Cruz, 2000;[START_REF] Pankhurst | Episodic silicic volcanism in Patagonia and the Antarctic peninsula: chronology of magmatism associated with the breakup of Gondwana[END_REF], whereas in the south they are considered to have been deposited in a submarine environment prior to and contemporaneous with the opening of the Rocas Verdes Marginal Basin [START_REF] Dalziel | Fossil marginal basin in the southern Andes[END_REF][START_REF] Bruhn | Field and geochemical data bearing on the development of a Mesozoic volcano-tectonic rift zone and back-arc basin in southernmost South America[END_REF][START_REF] Allen | Geología de la Cordillera Sarmiento, Andes Patagónicos, entre los 51º00' y 52º15' Lat S, Magallanes, Chile[END_REF][START_REF] Wilson | Transition from a back-arc to foreland basin development in the southernmost Andes: Stratigraphic record from the Ultima Esperanza District, Chile[END_REF][START_REF] Stern | Rocas Verdes ophiolites, southernmost South America: remnants of progressive stages of development on oceanic-type crust in a continental margin back-arc basin[END_REF]Calderón et al., 2007a). The Magallanes (Austral, in Argentina) foreland basin overlies the Rocas Verdes basin, initially developed as a sag basin (Late Jurassic -Early Cretaceous Zapata Formation) which evolved to a foreland basin since the mid-Cretaceous [START_REF] Biddle | The stratrigraphic and structural evolution of the central and eastern Magallanes Basin, southern South America[END_REF]. This basin has continental facies in the north and east, and deep marine facies southward and close to the main cordillera [START_REF] Biddle | The stratrigraphic and structural evolution of the central and eastern Magallanes Basin, southern South America[END_REF][START_REF] Macellari | Upper Cretaceous to Paleocene depositional sequences and sandstone petrography of southwestern Patagonia (Argentina and Chile)[END_REF][START_REF] Wilson | Transition from a back-arc to foreland basin development in the southernmost Andes: Stratigraphic record from the Ultima Esperanza District, Chile[END_REF]. In the north, this basin was not connected to an open sea; therefore, Cretaceous sedimentary deposits are scarce, whilst in the Paleogene there were volcano-sedimentary successions within restricted sub-basins (see review in [START_REF] Giacosa | Hojas Geológicas 4772-III y 4772-IV, Lago Belgrano y Lago Posadas. Provincia de Santa Cruz[END_REF].

The major magmatic units in the southern Patagonia are shown simplified in Figure 1, summarized into two plutonic and two volcanic units. The main plutonic unit comprises the Mesozoic-Cenozoic South Patagonian batholith (SPB), which intrudes the metasedimentary basement [START_REF] Stewart | Estudio geológico económico de la Cordillera Patagónica entre los paralelos 51º00 y 53º30 Lat. S, provincia de Magallanes[END_REF][START_REF] Weaver | The Patagonian Batholith at 48°S latitude, Chile: geochemical and isotopic variations[END_REF][START_REF] Bruce | Temporal and spatial variations in the southern Patagonian batholith; constraints on magmatic arc development[END_REF][START_REF] Hervé | The South Patagonian batholith: 150 my of granite magmatism on a plate margin[END_REF]. The Neogene plutons in the batholith are considered to be formed from mantle-derived magmas, with scarce crustal assimilation [START_REF] Hervé | The South Patagonian batholith: 150 my of granite magmatism on a plate margin[END_REF][START_REF] Fanning | Multi-dimensional Zircon Tracking: A Case Study Using The 150 My Evolution Of The South Patagonian Batholith[END_REF]. The other plutonic unit is the focus of this paper. It was firstly considered as an approximate N-S trending belt of Cenozoic plutons, satellites to the SPB, located in the extra-Andean zone [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF], they intrude volcanic rocks of the Ibáñez Group or the metasedimentary basement (northern area), or sedimentary rocks of the Magallanes (Austral) foreland basin (southern area) (figures 1, 2 and 3). They are mostly granitoids, and further geological data is presented in section 4. The Fitz Roy pluton (Chalten plutonic complex) is an exception, as this complex has a range of lithologies from ultramafic to granitic rocks (Ramírez de [START_REF] Ramírez De Arellano | Magmatic history of the Fitz Roy Plutonic Complex, Southern Patagonia (Argentina)[END_REF] with typical calc-alkaline geochemical features [START_REF] Michael | Emplacement and differentiation of Miocene plutons in the Andean[END_REF]Kosmal and Spikermann, 2002;[START_REF] Ramírez De Arellano | Petrology and chemistry of the Chaltén Plutonic Complex and implications on the magmatic and tectonic evolution of the Southernmost Andes (Patagonia) during the Miocene[END_REF]. The latter author proposed that subduction-derived fluids triggered the magma-genesis of this complex. It has a K-Ar age of 18 Ma [START_REF] Nullo | Estratigrafía y tectónica de la vertiente este del hielo continental patagónico, Argentina-Chile[END_REF], and an emplacement time span between 16.95 and 16.35 Ma has been determined for the suite (Ramírez de Arellano et al., 2012a).

P R E S S

The Cenozoic, mainly Miocene-Pleistocene, basaltic plateau lavas are located predominantly in the Argentinean pampa, in a back-arc position. Other minor but key mid-Miocene extrusive units are the Chile Chico rhyolites [START_REF] Espinoza | Petrogenesis of the Eocene and Mio-Pliocene alkaline basaltic magmatism in Meseta Chile Chico, Southern Patagonia, Chile: evidence for the participation of two slab windows[END_REF], and Cerro Zeballos lavas [START_REF] Espinoza | Volcanismo calcoalcalino durante el Mioceno Medio en Patagonia Central (47°S): petrogénesis e implicaciones en la dinámica de placas[END_REF], which outcrop in the northern area and are used for comparison. Lastly, the active volcanic arc is located in the cordilleran axis (Fig. 1), conformed by at least six Holocene volcanic centers of the Andean Austral Volcanic Zone (49-54ºS) [START_REF] Stern | Isotope and trace element data for orogenic andersites in the Austral Andes[END_REF][START_REF] Stern | 3158 continental crust in the generation of from the Andean Austral Volcanic Zone[END_REF]. Geochemical characteristic of these magmatic units are summarized in Figure 4. Chico [START_REF] Espinoza | Petrogenesis of the Eocene and Mio-Pliocene alkaline basaltic magmatism in Meseta Chile Chico, Southern Patagonia, Chile: evidence for the participation of two slab windows[END_REF], and MLBA [START_REF] Guivel | Miocene to Late Quaternary Patagonian basalts (46-478S): Geochronometric and geochemical evidence for slab tearing due to active spreading ridge subduction[END_REF]; 4: SPB: Neogene South Patagonian batholith [START_REF] Hervé | The South Patagonian batholith: 150 my of granite magmatism on a plate margin[END_REF]. B. Southern area lavas from volcanic fields: Glencross Area [START_REF] D'orazio | Slab window-related magmatism from southernmost South America: the Late Miocene mafic volcanics from the Estancia Glencross Area; ~52°S, Argentina-Chile[END_REF] and Camusú-Aike [START_REF] D'orazio | The Late Pliocene mafic lavas from the Camusú Aike volcanic field (~50°S, Argentina): Evidences for a geochemical variability in slab window Andean[END_REF].

Andean Geology 48 (3): xxx-xxx. September, 2021 doi: 10.5027/andgeoV48n3-3158

I N P R E S S

The tectonic scenario in south Patagonia has grosso modo two elements important to this work. First, the Magallanes Fold and Thrust Belt (review in Suárez et al., 2000), which thrusts principally Magallanes foreland basin rocks, but also the Jurassic rhyolites. And second, the collision of segments of an active spreading center (Chile Rise) with the South American Plate first at 55º S at ca.

15 Ma, which generated a tectonic triple junction [START_REF] Cande | Late Cenozoic tectonics of the Southern Chile Trench[END_REF]) that migrated northward to its present position (~46º30' S) (see [START_REF] Breitsprecher | Neogene kinematic history of Nazca-Antarctic-Phoenix slab windows beneath Patagonia and the Antarctic Peninsula[END_REF]. Major elements analyses were conducted for samples from different facies of the Paso de Las Llaves, Cerro Negro del Ghío, and San Lorenzo plutons, in the northern area; and at the Monte Balmaceda intrusive complex and Cerro Donoso pluton in the southern area. The analyses used the ICP-AES plasma 400 of the Departamento de Geología, Universidad de Chile and RGM-1 and QLO-1 were employed as standards. Procedures are in Calderón et al. (2007b). The results for the northern and southern areas are listed on tables 3 and 4, respectively.

Methods

Field

Trace elements measurements were performed in samples from the same plutons mentioned above, and in samples from different facies from the Torres del Paine Intrusive Complex in the southern area. All the trace elements analyses were carried out using a quadrupole ICP-MS 7500 ce. from Agilent Technologies.

The analytical drift was controlled and calibrated by an internal Re-In standard at the LMTG (now GET). Procedures are described in [START_REF] Aries | A routine method for oxide and hydroxide interference corrections in ICP-MS chemical analyses of environmental and geological samples[END_REF]. GS-N, AC-E and GA were used as standards. The results for the northern and southern areas are listed on tables 3 and 4, respectively.

We used the traditional major element classification of [START_REF] Irvine | A guide to the chemical classification of the common volcanic rocks[END_REF] and the alumina saturation index (A/CNK-A/NK) diagram with A/CNK=Al2O3/(CaO+Na2O+K2O) (mol.%) and A/NK=Al2O3/(Na2O+K2O) (mol.%) [START_REF] Shand | Eruptive Rocks. Their Genesis, Composition, Classification, and their Relation to Ore Deposits, with a chapter on Meteorites[END_REF]; but also some trace elements diagrams were used in order to dismiss possible alteration (s.l.) effects on major elements content. To control the alkaline character, the Nb/Y ratio and Co-Th diagrams were employed. The former is considered an alkaline indicator [START_REF] Pearce | Tectonic setting of basic volcanic rocks determined using trace element analyses[END_REF]Winchester and Floyd, Andean Geology 48 (3): xxx-xxx. September, 2021 doi: 10.5027/andgeoV48n3-3158

14 1977), while the latter may be indicative of a transport mechanism in subduction settings, similar to K [START_REF] Hastie | Classification of altered volcanic island arc rocks using immobile trace elements: Development of the Andean Geology[END_REF]. The REE (Rare Earth Elements) diagrams used are normalized to chondrites and so is Eu/Eu*=EuN/sqr(SmN*GdN) [START_REF] Nakamura | Determination of REE, Ba, Fe, Mg, Na and K in carbonaceous Andean[END_REF]. In order to discriminate arc signatures, MORB normalized [START_REF] Pearce | Role of sub-continental lithosphere in magma genesis at active continental margins[END_REF] spider diagrams were used. In the latter diagrams, data from previous works on magmatic units are plotted for comparison.

I N P R E S S
The Nd and Sr isotopic measurement listed on Tables 5 and6 were made on whole rocks powders from the same samples used for the trace elements measurements, with an upgraded MAT 261 thermal ionization mass spectrometer at the LMTG, Toulouse (GET). La Jolla and NBS 987 reference material were used as standards for Nd and Sr ratios, respectively.

To compare the results, all the new data are plotted in similar diagrams together with data from the SPB (representing arc signature) and from the plateau lavas (Fig. 4).

Field relations -Petrography

Based in our field studies and in results of previous work, as indicated in the text, the field relationships for the different plutons, are indicated below.

Additionally, some key data in each pluton, namely previous geochronology, are presented according to their geographic location from north to south.

Paso de Las Llaves Pluton

This pluton has a near elliptical shape with an E-W long axis of ca. 12 km.

P R E S S

There are two main outcrop areas, one in the coast of the General Carrera -Buenos Aires lake (Paso de Las Llaves area), and the other in the valley of the Río Avilés (Fig. 2), both heavily covered by forest. In the Paso de Las Llaves area, biotite-amphibole tonalite to granodiorite facies predominate. In the contact areas, the pluton hosts mostly gneissic xenoliths up to 20 cm in length with preferred vertical disposition (Fig. 5A). Near the southwestern side of the pluton, the tonalites intrude pyroxene dioritic facies. In the tonalites, plagioclase is the main component, usually with a calcium rich core (An50-80) with a poikilitic texture and a zoned sodium-rich rim (commonly around An25) (Table 1), whereas Kfeldspar-quartz inter-growth, pyroxene, apatite, titanite and zircon appear as minor phases. The diorites have porphyritic texture and, in general terms, they have similar mineralogy than the tonalites, but with higher content of pyroxene, and lesser content of amphibole and biotite. The plagioclase is calcic-rich (An 60-90 ) with zoned border. In addition, a porphyritic granitic facies is present in the northeast margin of the pluton, with quartz, plagioclase, mica and garnet phenocrysts (sample 07LL3). Otherwise, [START_REF] Vargas | Emplazamiento hipabisal tardío del stock de Paso de Las Llaves en la región de tras arco[END_REF] have described miarolitic cavities within granodioritic facies in the Paso de Las Llaves area, ascribing these facies to a shallow emplacement level (< 5 km).

P R E S S

In the Río Avilés area, the scarce outcrops are mainly of the granitic facies, with lobate contacts with the diorites (Fig. 5B) that suggest their synchronous emplacement. This unit is called Granito Avilés and its granitic rocks are biotiterich, have relict pyroxenes in association with biotite and, close to the diorites, are amphibole rich. The diorites exhibit similar petrographic characteristics to those observed in Paso de Las Llaves area.

Previous radiometric data, with different geochronological methods, indicate an age range from 8.9 to 11.1 Ma [START_REF] Petford | of igneous rocks around Coyhaique, S. Chile (45º30'-47ºS)[END_REF][START_REF] Pankhurst | Mesozoic-Cenozoic evolution of the North Patagonian Batholith in Aysén, southern Chile[END_REF][START_REF] Suárez | Jurassic to Miocene K-Ar dates from eastern central Patagonian Cordillera plutons, Chile (45°-48° S)[END_REF]. [START_REF] Pankhurst | Mesozoic-Cenozoic evolution of the North Patagonian Batholith in Aysén, southern Chile[END_REF] referred to this pluton as a satellite body of the South Patagonian batholith.

Cerro Negro del Ghío Pluton

The main outcrop of this pluton is nearly round in shape, approximately 1.8 km in diameter, with a horizontal tabular disposition (Fig. 5D). Another outcrop area appears as a smaller (< 1 km in diameter) isolated body on the top of a hill a few kilometers northward (Fig. 5C). The contact relationships can be observed at the bottom of the main outcrop and in the northern margin of the smaller outcrop (Fig. 5C) where quartz diorites intrude host lavas. The eastern and northern margins of the largest outcrop are cut by normal faults.

This pluton consists mainly of porphyritic quartz-diorites with large plagioclase (An 45-57 , up to An 63 cores; Table 1) and hornblende phenocrysts , minor phases are pyroxene and biotite. In the groundmass an intergrowth of quartz with Na-rich plagioclase (Ab84-91) predominates. Other phases are pyroxene, hornblende and opaque minerals, and glass is also present locally.

I N P R E S S
Mafic enclaves are rare and they have sharp contacts with the quartz-diorite. A second major facies of the pluton is observed in the core of the outcrop where a more whitish facies seems to have been intruded into the main quartz-diorite (Fig. 5D). The Cerro Negro del Ghío pluton has a K-Ar hornblende age of 15.8 ± 0.6 Ma [START_REF] Ramos | El magmatismo neógeno de la Cordillera Patagónica[END_REF], and two bulk rock K-Ar determinations yielding 15.8 ± 0.7 and 18 ± 1.2 Ma [START_REF] Ramos | El magmatismo neógeno de la Cordillera Patagónica[END_REF].

San Lorenzo Pluton

This intrusive is part of a plutonic complex composed by the Sobral (ca. 143

Ma), Tranquilo (ca. 84 Ma), Del Salto (ca. 84 Ma) and San Lorenzo (6.2 ±0.12 Ma; ( 40 Ar/ 39 Ar in biotite; [START_REF] Welkner | Geología del área del cerro San Lorenzo: Cordillera Patagónica Oriental, XI Región de Aysén[END_REF][START_REF] Welkner | Geocronología de los plutones del área del cerro San Lorenzo, XI Región Aysén. In: Congreso Geológico Chileno[END_REF]) plutons. Del Salto pluton is the only one of the complex with alkaline mineralogy [START_REF] Welkner | Peralkaline rocks in the Late Cretaceous Del Salto Pluton, Eastern Patagonian Andes, Aisén, Chile (47°35'S)[END_REF]. The San Lorenzo pluton intrudes the Jurassic Sobral pluton [START_REF] Welkner | Geología del área del cerro San Lorenzo: Cordillera Patagónica Oriental, XI Región de Aysén[END_REF][START_REF] Welkner | Geocronología de los plutones del área del cerro San Lorenzo, XI Región Aysén. In: Congreso Geológico Chileno[END_REF] (Fig. 2), where biotite syenogranite is the predominant facies. In addition, monzonites and hornblende and biotite granodiorite horizontally layered enclaves are common in monzogranite facies [START_REF] Welkner | Geología del área del cerro San Lorenzo: Cordillera Patagónica Oriental, XI Región de Aysén[END_REF]. In this work, we studied monzogranite samples with similar characteristics to those mentioned by [START_REF] Welkner | Geología del área del cerro San Lorenzo: Cordillera Patagónica Oriental, XI Región de Aysén[END_REF], but we also found that they have abundant granophyric textures (e.g. mirmekites), and an andesitic facies with unexposed contact relation with the other facies, probably corresponding to a dike (sample COY0234).

Río de Las Nieves Pluton

This pluton has a near elliptical outcrop shape, with a ca. 6 km long axis and a ca. 3.5 km short axis (Figure 2). Difficult access has precluded detailed descriptions of this unit and its field relations. Nonetheless, [START_REF] Morata | Early Pliocene magmatism and high exhumation rates in the Patagonian Cordillera (46°40′S) K-Ar and fission track data[END_REF] described it as a biotite quartz-monzonite. In this work we studied a biotite and hornblende monzo-granite with perthite phases and oscillatory-zoned plagioclase

I N P R E S S
as major mineral phases and Fe-Ti oxides, apatite and zircon as minor mineral phases. A K-Ar age determination in biotite gave 3.2 ± 0.4 Ma [START_REF] Morata | Early Pliocene magmatism and high exhumation rates in the Patagonian Cordillera (46°40′S) K-Ar and fission track data[END_REF].

Alkaline plutons in the Meseta del Lago Buenos Aires

There are 3 intrusions, the Pico Rojo syeno-diorite of circular shape [START_REF] Espinoza | Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)[END_REF], the Mifeldi pluton, a laccolith-shaped microsyenite, and the Cerro Lápiz volcanic neck, composed by micro-granites. They are all alkaline felsic rocks [START_REF] Espinoza | Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)[END_REF] that crop out in the west border of the Meseta del Lago Buenos Aires basaltic plateau (Fig. 2). Both, Mifeldi and Cerro Lápiz, have an intrusive relationship with the lavas. The Pico Rojo contact with the lavas is not exposed [START_REF] Espinoza | Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)[END_REF]. These plutons have ages which range between 3.98 ± 0.1 (K-Ar in whole rock), and 3.29 ± 0.22 ( 40 Ar/ 39 Ar in groundmass) [START_REF] Brown | Paleomagnetism and 40Ar/39Ar chronology of lavas from Meseta del Lago Buenos Aires, Patagonia[END_REF][START_REF] Espinoza | Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)[END_REF].

Torres del Paine intrusive complex

This complex has a nearly elliptical shape covering an area of 150 Km 2 [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF], with a maximum E-W elongation of 16 km (Fig. 3). It is shaped and has an exposed maximum vertical elevation of over 2,500 m [START_REF] Michel | Incremental growth of the Patagonian Torres del Paine laccolith over 90 k.y[END_REF]. Country rocks show variable degrees of deformation at the roof and eastern edge of the complex, and a contact metamorphic aureole that obliterates the ubiquitous slaty cleavage of the host rock. This complex is constituted by the basal Paine Mafic Complex (PMC) and by the Paine Granite (PG). The PMC restricted outcrops are overlain by the PG at a nearly constant altitude of 1,000 m a.s.l. [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF]. The PMC consists of a ca. 400 m thick layer of mafic facies, mainly composed by gabbros, monzodiorites, quartz monzodiorites and large granite patches [START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF], but also gabbronorites [START_REF] Leuthold | A detailed geochemical study of a shallow, arc-related laccolith: the Torres del Paine mafic complex, Patagonia[END_REF]. The gabbros are located at the lowest levels and they grade into quartz-monzodiorites near the PG contact in the upper 300 m of the PMC [START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF]. Some of the gabbros have cumulate and/or layering textures. The mafic and intermediate rocks are often in sharp irregular contact and no smooth progression of composition is observed. The granite patches have engulfed contacts with the mafic rocks [START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF]. The base of the PMC does not crop out, and there is no reported contact between this unit and the country rocks. Plagioclase crystals in the gabbros are usually large (up to 4 mm) and are strongly and discontinuously zoned, having An70 cores and An15 rims, with a narrow transition between An55

and An 25 [START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF].

The PG has a maximum vertical extent of about 2000 m [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF].

Some glacial valleys expose many contact zones with the country rocks, where aplitic spires into the host rocks are visible. In the upper part, stepping (staircase-shaped) contact is a frequent feature of the intrusion, and in some cases the aplitic spires are linked to steps. In the eastern part of the pluton, the bottom of the granite is not in contact with PMC rocks but directly with the country rocks, suggesting that the PMC has a smaller extension than the PG. The eastern termination of the pluton is underlain by a giant magmatic breccia (up to metric sized blocks), suggesting an eastward magma propagation during pluton construction. The PG can be subdivided into three units [START_REF] Michel | Incremental growth of the Patagonian Torres del Paine laccolith over 90 k.y[END_REF], [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF].

Unit III is younger than Unit I [START_REF] Michel | Incremental growth of the Patagonian Torres del Paine laccolith over 90 k.y[END_REF]. It is the most voluminous and consists in a grey-weathering biotite and hornblende granite, which corresponds to the white granite of [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF]. The base of this unit is in contact with the basal PMC. The plagioclase within the granite commonly shows a strong zonation from An50 cores to An15 rims and some crystals have discontinuously zoned calcic cores, up to An 78 [START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF] with rare large crystals up to 3 mm in diameter with An 25-10 [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF]. On the basis of petrographic evidence, geochemistry and microprobe analyses, [START_REF] Michael | Emplacement and differentiation of Miocene plutons in the Andean[END_REF][START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF][START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF] considered the Paine Granite and the Paine Mafic Complex as co-magmatic and consangineous (sic) units.

Dating in the PG gave ages mostly between 12.5 and 13 Ma [START_REF] Halpern | Regional Geochronology of Chile south of 50° S latitude[END_REF][START_REF] Sánchez | A Shrimp U-Pb zircon late Miocene crystallization age for the Torres del Paine Pluton, Chile[END_REF][START_REF] Michel | Incremental growth of the Patagonian Torres del Paine laccolith over 90 k.y[END_REF][START_REF] Leuthold | Time resolved construction of a bimodal laccolith (Torres del Paine, Patagonia)[END_REF].

Paine External Gabbros

These rocks correspond to isolated outcrops in the neighbourhood of the Torres del Paine Intrusive Complex, in the form of sills and dikes. [START_REF] Michael | Emplacement and differentiation of Miocene plutons in the Andean[END_REF] described olivine-two pyroxene gabbros and bronzite orthoclase gabbros, with geochemical analyses showing a calc-alkaline trend. [START_REF] Altenberger | of the Cenozoic magmatism at the Torres del Paine, southern Andes (Chile, 51°10'S)[END_REF] found that some of these rocks are folded together with the country rocks, and thus pre-date the regional deformation and the Torres del Paine intrusive complex emplacement. These authors described the gabbros as composed by plagioclase, hornblende, clinopyroxene, biotite, apatite and opaque minerals; and with a geochemical alkaline composition (Altenberger et al., 2003, and references therein). A K-Ar age determination in biotite yielded 29.4 ± 0.8 [START_REF] Altenberger | of the Cenozoic magmatism at the Torres del Paine, southern Andes (Chile, 51°10'S)[END_REF]. A U-Pb determination in zircons, in rocks from the same area studied by [START_REF] Altenberger | of the Cenozoic magmatism at the Torres del Paine, southern Andes (Chile, 51°10'S)[END_REF], gave 16.9 ± 0.2 Ma [START_REF] Fosdick | Kinematic evolution of the Patagonian retroarc fold-and-thrust belt and Magallanes foreland basin, Chile and Argentina, 51°30′S[END_REF], but the gabbros studied by the later authors are undeformed.

Thus, these "external gabbros" represent at least two pulses of basic magmas at the Oligocene (deformed) and at the Miocene (undeformed).

Cerro Donoso Pluton

This pluton has an approximately circular shape, with a 750 m diameter in plan view, with vertical discordant contacts with the host rocks (Fig. 6A). Country rocks are smoothly plunging sandstones dominated turbidites from the Punta Barrosa Formation (Cretaceous) in which the Cerro Donoso pluton generated a contact metamorphic aureole tens of meters wide [START_REF] Muñoz | Geología y petrología de las rocas igneas e inclusiones ultramáficas del sector SW de Meseta Las Vizcachas[END_REF]. The main facies consists in a medium grained hornblende and biotite-bearing granodiorite. At lower levels, it also bears some mafic enclaves and quartz veins (Fig. 6B). In an internal area of the pluton there is a vertical fabric highlighted by the hornblende alignment (Fig. 6C). The pluton locally has a porphyritic texture with large (1-4 mm) plagioclase crystals set within a recrystallized quartz mass.

A common feature of the plagioclases are re-absorption/re-crystallization textures (Fig. 7A). Some of them are strongly zoned (e.g. from an An 68 core to An 16 rim) (Table 2), and/or with a sieve-like texture and sericitic alteration. Many plagioclase grains are around 0.5 mm in diameter and compositionally An42-44, some have Na-rich rims. The orthoclase is perthitic and partially replaced by muscovite. The biotite is partially replaced by chlorite.

Andean Geology 48 ( 3 Within the pluton, a quartz diorite facies crops out as a sill (Fig. 6D), which is a hornblende and biotite-rich facies, with large (>1 mm) and highly altered hornblende crystals, coexisting with small, fresh and euhedral ones. A particular characteristic of this facies is that some hornblende seems to form by replacement of older biotite. This appears to correlate with plagioclase growth, in which two step developments can be recognized: 1) a relatively homogeneous core with sieve texture and 2) zoned borders. These features may be indicative of strong compositional variations during the crystallization of the magma.

The vertical fabric revealed by the hornblende orientation, as well as by all vertical contacts of the main pluton, together with the circular outcrop shape, suggests that the granitic intrusion cooled while the magma was ascending by a cheminée conduit.

In the surroundings of the pluton outcrop area, there are several rhyolitic and andesitic-basalt dikes, most of them with a N-S to N10ºW strike. One of the rhyolitic dikes is faulted (Fig. 6E), so at least this dike pre-dates regional deformation, similarly to the Paine External Gabbros. No dikes were found cutting the main pluton, which is undeformed. Therefore, the deformation events predate the main pluton intrusion.

Monte Balmaceda intrusive complex

This complex is composed of apparently disconnected bodies (Fig. 8A), but our mapping shows that all outcrops probably belong to the same intrusion. It has an N-S elongated outcrops area, which covers around 180 km 2 (Fig. 3). The 3-D The Balmaceda leucogranites are found mainly on the northern slope of the mountain (over 700 m a.s.l.) in a near circular outcrop, having vertical intrusive contacts with the host rocks, which are horizontal to sub-horizontally layered hornfelsic shales (Fig. 8A,B). It consists mainly of yellow perthite or alkali feldspar-rich (Or1-Ab89 to Or95-Ab5; Table 2) granites (syenogranites and alkali feldspar granites) with coarse to fine grained textures. At higher altitude (at 1045 m a.s.l.) it has centimetric (1 to ca.15 cm) miarolitic cavities, although, cavities larger than 5 cm are exceptional. Minor miarolitic cavities are also recognized in the BLG rocks in the Glaciar Serrano area, located only few m a.s.l. The mafic minerals are scarce in this facies, but in one sample sodic amphibole (riebeckite/arfvedsonite) and aegerine (identified by optical properties), as well as epidote phases are present (Fig. 7B-D).

The Balmaceda Mafic Complex consists of gabbro/diorite that have complex intrusive relationships with the leucogranites. Patches of granodiorite and large areas of mafic enclaves within granodiorite crop out in the northern slope area (between 700 and ca. 1000 m a.s.l.). Some characteristic features are the enclave orientations in lower altitude, and sub-horizontal in higher altitude (Fig. Locally, the mafic enclaves host micro-enclaves of coarse grained leucogranite with a rim of chlorite and/or calcite. Intrusive relationships suggest that felsic and mafic facies coexisted as magmas, as there is evidence for the felsic facies intruding the mafic ones generating mafic engulfed enclaves (Fig. 9A).

Several dikes, mainly rhyolitic in composition, are present on the north slope of the mountain around the main outcrops and they have N0-10°W sub-vertical trends.

New geochemical data

Miocene northern area plutons

Paso de Las Llaves, Cerro Negro del Ghío, and San Lorenzo plutons are included in this section (Fig. 2).

Paso de Las Llaves Pluton

Based on silica content (Fig. 10A), this pluton can be divided into two groups: 1) tonalites and diorites, with SiO2= 49.6-53.4 wt.%; and 2) Granito Avilés, with 60-66.7 wt.% SiO 2 . The basaltic and rhyolitic dikes have around 45 and 72 wt.% SiO 2 , respectively. In addition, the tonalites and diorites have an A/NK ratio [START_REF] Shand | Eruptive Rocks. Their Genesis, Composition, Classification, and their Relation to Ore Deposits, with a chapter on Meteorites[END_REF] above 2, while Granito Aviles and the rhyolitic dikes have A/NK between 1.5 and 1.8. All these magmatic units are on and around the [START_REF] Irvine | A guide to the chemical classification of the common volcanic rocks[END_REF] al., 2005), Las Vizcachas plateau [START_REF] Muñoz | Basaltos alcalinos y toleiticos del cenozoico superior en meta Las Vizcachas, Magallanesm Chile[END_REF] and Glenn Cross Area [START_REF] D'orazio | Slab window-related magmatism from southernmost South America: the Late Miocene mafic volcanics from the Estancia Glencross Area; ~52°S, Argentina-Chile[END_REF]; SPB: South Patagonian batholith [START_REF] Hervé | The South Patagonian batholith: 150 my of granite magmatism on a plate margin[END_REF]; AVZ: Austral Volcanic Zone (Stern and Killian, 1996); Adk: extra-andean adakites [START_REF] Ramos | Las adakitas de la Cordillera Patagónica: Nuevas evidencias geoquímicas y geocronológicas[END_REF]. Alkalies and SiO2 content in wt%.

Andean Geology 48 ( 3 The pluton suite has steep patterns in Light Rare Earth Elements (LREE) and flat in the Heavy REE (HREE) (Fig. 12A). In the spider diagrams, a remarkable feature is the similar pattern of the whole suite with SPB (representing a magmatic arc signature) as the Nb-Ta anomalies and the enrichment in Large Ion

Lithophile Elements (LILE) (Fig. 12B). Nevertheless, in this pluton it is possible to distinguish LILE and High Field Strength Elements (HFSE) enrichment in Granito Avilés (GA), with Zr and Hf content similar to OIB averages. The GA unit, therefore, shows a less marked Nb-Ta negative anomaly compared to the suite.

Additionally, GA presents a slight negative anomaly in Ti, Sr and P just enough to be distinguishable from the tonalites and diorites, which have similar patterns to the SPB. The rhyolitic dike has a similar pattern with GA, but more pronounced negative anomalies for the above mentioned elements. [START_REF] Nakamura | Determination of REE, Ba, Fe, Mg, Na and K in carbonaceous Andean[END_REF], and the spider diagrams to MORB [START_REF] Pearce | Role of sub-continental lithosphere in magma genesis at active continental margins[END_REF]. A. Island Basalt average, [START_REF] Sun | Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes[END_REF]; 2: Main Plateau lavas, includes the Meseta Central, Belgrano, Noreste, and Muerte [START_REF] Gorring | Mantle processes and sources of Neogene slab window Andean[END_REF], Meseta Chile Chico [START_REF] Espinoza | Petrogenesis of the Eocene and Mio-Pliocene alkaline basaltic magmatism in Meseta Chile Chico, Southern Patagonia, Chile: evidence for the participation of two slab windows[END_REF], and Meseta del Lago Buenos Aires [START_REF] Guivel | Miocene to Late Quaternary Patagonian basalts (46-478S): Geochronometric and geochemical evidence for slab tearing due to active spreading ridge subduction[END_REF]; 3:SPB: Neogene South Patagonian batholith [START_REF] Hervé | The South Patagonian batholith: 150 my of granite magmatism on a plate margin[END_REF]; 4: samples from [START_REF] Vargas | Emplazamiento hipabisal tardío del stock de Paso de Las Llaves en la región de tras arco[END_REF]; 5: samples from [START_REF] Michael | Emplacement and differentiation of Miocene plutons in the Andean[END_REF] and [START_REF] Welkner | Geología del área del cerro San Lorenzo: Cordillera Patagónica Oriental, XI Región de Aysén[END_REF].

REE pattern for

Andean Geology 48 (3): xxx-xxx. September, 2021 doi: 10.5027/andgeoV48n3-3158

I N P R E S S

The Nd and Sr isotopic composition of the pluton suite (7 analysed samples) display Nd t between +0.7 and +2.3, and ( 87 Sr/ 86 Sr) i ratio from 0.7040 to 0.7050, including the basaltic dike, while the rhyolitic dike has an Nd t =0 and

( 87 Sr/ 86 Sr) i >0.7050 (Table 5; Fig. 13A,B).

Otherwise, the porphyritic garnet bearing granite (07LL3, Paso de Las Llaves pluton) has up to 72.1 wt.% SiO2, an A/NK ratio between 1.5 and 1.8, and is clearly sub-alkaline (Fig. 10A,11A). This granite can also be distinguished from the whole suite due to its remarkable negative Eu anomaly with Eu/Eu*=0.55 (Fig. 12A). In the spider diagram, it exhibits a similar pattern to Granito Avilés (Fig. 12B). Furthermore, this facies has Nd t =-5.3 (Table 5, Fig. 13A) and reflects a magma source different to the rest of the unit, with a consequent difference in its geochemical character (alumina, alkalinity and the trace elements pattern as mentioned above) and in its mineralogy, especially the presence of garnet (Section 4.1).

Cerro Negro del Ghío Pluton

This pluton has a homogeneous composition, with SiO 2 = 58.1-59.6 wt.%, and a A/NK ratio [START_REF] Shand | Eruptive Rocks. Their Genesis, Composition, Classification, and their Relation to Ore Deposits, with a chapter on Meteorites[END_REF] between 1.5 and 1.8. In addition, all samples are located in the alkaline field of [START_REF] Irvine | A guide to the chemical classification of the common volcanic rocks[END_REF] on the TAS diagram (Fig. 10A).

Cerro Negro del Ghío pluton has a steep pattern in LREE (Fig. 12C), which is clearly more enriched compared to SPB, and a flat pattern in HREE, despite

showing a slight upward concave pattern (Fig. 12C). In the spider diagram, its samples exhibit an intermediate pattern between the tonalites and Granito Avilés units from Paso de Las Llaves pluton, with a high LILE/HFSE ratio, a less pronounced Nb-Ta negative anomaly and slight negative Ti anomaly (Fig. 12D).

From the two sampled locations, this pluton shows homogeneous Nd and Sr isotopic composition with Ndt=+2.6 ±0.3 and ( 87 Sr/ 86 Sr) i <0.7050 (0.7039±0.2) (Table 5; Fig. 13A,B).

This pluton has been related to the volcanic units of the neighboring area [START_REF] Espinoza | Volcanismo calcoalcalino durante el Mioceno Medio en Patagonia Central (47°S): petrogénesis e implicaciones en la dinámica de placas[END_REF]Boutonnet et al., 2010). Since the Cerro Negro del Ghío pluton and the Zeballos lavas [START_REF] Espinoza | Volcanismo calcoalcalino durante el Mioceno Medio en Patagonia Central (47°S): petrogénesis e implicaciones en la dinámica de placas[END_REF] share many geochemical characteristics, including their isotopic signature (Figs. 10A, 11B, 13B), these magmatic units are interpreted to be genetically linked, the Cerro Negro del Ghío pluton being the plutonic equivalent of Zeballos lavas.

The San Lorenzo Pluton

This pluton has predominantly SiO2 > 70 wt.%. Only few samples have SiO2 < 65 wt% (Fig. 10A) and among them is the andesitic one (COY0234) with a SiO2 They are in the alkalinecalc-alkaline limit (Fig. 10A; [START_REF] Irvine | A guide to the chemical classification of the common volcanic rocks[END_REF], but plot in the high-K calc-alkaline field of [START_REF] Peccerillo | Geochemistry of eocene calcalkaline volcanic rocks from Kastamonu area, northern Turkey[END_REF] (not shown) and in the Th-Co diagram (Fig. 11B), or even alkaline in the Zr/TiO2-Nb/Y diagram (Fig. 11A), while the intermediate samples have an A/NK ratio [START_REF] Shand | Eruptive Rocks. Their Genesis, Composition, Classification, and their Relation to Ore Deposits, with a chapter on Meteorites[END_REF] between 1.5 and 1.8 and also fall in the high-K calc-alkaline fields (Table 3; Figs. 10A,11B). Many samples have normative corundum reflecting a peraluminous character (Zen, 1988).

This pluton is enriched in LREE with respect to SPB and the HREE show a slight upward concave pattern (Fig. 12E). The granites have a negative Eu anomaly, which is very pronounced in some samples (Eu/Eu*=0.2-0.7). They have no -or very subtle-Nb-Ta anomaly, very pronounced Sr, P and Ti negatives anomalies, as well as high content in LIL and HFS elements (Fig. 12F). The intermediate rocks have less pronounced anomalies in Eu, Sr, P and Ti, or none at all.

The two granite samples from the San Lorenzo pluton have εNdt <0, while the andesite sample has εNd t >0. The Sr i ratio is similar for the 3 analysed samples, around 0.7051 (Table 5; Fig. 13A,B).

Pliocene northern area plutons

New data for a granite sample from the Río de Las Nieves pluton are presented together with new major elements data for the alkaline plutons in Meseta del Lago Buenos Aires (Table 3). These data are compared and complemented with previous published data [START_REF] Espinoza | Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)[END_REF].

Río de Las Nieves

This pluton has between 62 and 64 wt.% SiO2 and plots on the alkaline/subalkaline limit of [START_REF] Irvine | A guide to the chemical classification of the common volcanic rocks[END_REF] (Fig. 10B). The REE show a pronounced steep pattern in LREE and a flat one in HREE, indeed it is very enriched in LREE with respect to the SPB (Fig. 14A). The LILE and HFSE are also enriched in this pluton, with a subtle Nb-Ta negative anomaly and high content on Th, Zr and Hf (Fig. 14B). The trace elements for this pluton follow an intermediate pattern between the alkaline Pliocene plutons [START_REF] Espinoza | Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)[END_REF] and the SPB, very similar to the San Lorenzo pluton signatures (Figs. 12F,14B).

This pluton has isotopic ratios in the range of Paso de Las Llaves pluton suite (Nd t =+1.3 and (Sr/Sr) i =0.7046) ( [START_REF] Espinoza | Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)[END_REF]; Fig. 14C).

Southern area plutons

The dataset used consists in original data (Table 4) complemented with data collected by [START_REF] Michael | Emplacement and differentiation of Miocene plutons in the Andean[END_REF][START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF][START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF] The Nd and Sr isotopic ratios from the pluton are grouped near the bulk Earth intersection, with Ndt= -0.4 to +0.3 and ( 87 Sr/ 86 Sr)i = 0.7046 to 0.7049 (Fig. 13C,D). The rhyolitic and basaltic dikes have the lowest and highest Nd t values of the measured samples in the southern area, respectively (Fig. 13C).

Even the basaltic dike (sample 07DN2) has an anomalous pattern in LILE (Fig. 15B) and a loss on ignition >4 wt.% ( pattern for the HFS elements, so the Nd t value may reflect the closest isotopic composition to the mantle source of all the suites, with Ndt (07DN2)= +5.8.

The Paine External Gabbros

According to [START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF], these rocks have a 43-56 wt.% range of SiO2 content. They are peraluminous, similar to SPB, and mostly either sub-alkaline in the TAS and Zr/TiO 2 -Nb/Y diagrams (Figs. 10D, 11C), or high K calc-alkaline in the [START_REF] Peccerillo | Geochemistry of eocene calcalkaline volcanic rocks from Kastamonu area, northern Turkey[END_REF] and Th-Co diagrams (Fig. 11D).

This unit plots mainly inside the area projected by the Neogene samples from the SPB reflecting arc-signature in the spider diagram pattern (Fig. 15B).

Andean Geology 48 ( 3

Torres del Paine intrusive complex

In this intrusive complex, bimodality is clearly noted, with a SiO 2 content ranging between 45 and 65 wt.% in the Paine Mafic Complex (PMC), and SiO 2 > 69 wt.% in Paine Granite (PG) [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF][START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF]; Fig. 10C). Based on the alumina criteria both the Paine Granite suite and the Paine Mafic Complex are mainly peraluminous, with an A/CKN ratio [START_REF] Shand | Eruptive Rocks. Their Genesis, Composition, Classification, and their Relation to Ore Deposits, with a chapter on Meteorites[END_REF] ranging between 0.8 and 1.2. Nevertheless, the A/KN ratio from PG is lower than the PMC ratio, with ranges between 0.9 to 1.4 and 1.3 to 2.7 respectively [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF][START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF]. In this case, the PG suite limits with the metaluminous and peralkaline fields (their A/KN ratio range just above and below 1), and some samples fall within the peralkaline field (data from [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF][START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF]. Additionally, both units plot in the alkaline or high-K calc-alkaline fields in Zr/TiO2-Nb/Y and Th-Co diagrams, respectively (Fig. 11C,D). One-third of the samples have normative corundum, and 3 of 32 have normative aegerine.

Both units, the Paine Granites (PG) and the Paine Mafic Complex (PMC), have steep and flat patterns in LREE and HREE, respectively (Fig. 15C). Even in this case, the PG can be differentiated by more pronounced Eu negative anomalies, with Eu/Eu*= 0.8 to 0.5 for PG, but up to 0.1 for the most silicic sample of this suite vs. 0.9 to 0.8 for PMC. Instead, PMC is richer in total REE than PG, with REE= 187-223 the former and REE= 126-187 the later. In the spider diagram, the new data has been plotted together with data from [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF][START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF] 15D), showing wide range of values in most elements. In spite of that, there are remarkable features, for example, PG samples show strong negative anomalies in The Nd t values for the Paine Mafic Complex (PMC) are > 0 (+0.9 to +2.6), while the felsic ones are < 0 (-0.2 to -1.1) (Fig. 13C). The PMC displays ( 87 Sr/ 86 Sr) i < 0.7045 while this value is higher in Paine Granite (Fig. 13D).

Monte Balmaceda intrusive complex

Bimodal magmatism is evidenced by the Balmaceda Mafic Complex (BMC), SiO 2 content ranges between 46 and 54 wt.%, while the Balmaceda Leucogranites (BLG) contain between 71 and 79 wt.% (Fig. 10C). Additionally, the BMC has higher A/KN ratios (>1.3), than BLG (<1.3, even <1). Both units plot in the alkaline (Zr/TiO 2 -Nb/Y and TAS diagrams) (Figs 10C, 11C) or high-K calc-alkaline fields (Th-Co) (Fig. 11D). Most of the analysed BMC samples have normative nepheline, whereas one BLG sample has normative acmite (aegerine), which is in accordance with the modal mineralogy description (Section 4.9).

The Balmaceda Leucogranites (BLG) are characterized by REE pattern having slight concave-upward shapes (Fig. 15E) and a strong negative Eu anomaly (Eu/Eu*= 0.2-0.09), while BMC has flat HREE pattern and lacks Eu anomaly. Only the alkaline gabbro from the BMC (07BA25) has a slight steep pattern in HREE (Fig. 15E). In the spider diagram (Fig. 15F), the mafic facies have high LIL/HFS elements ratios, while the felsic ones have negative anomalies in Sr and Ba, the same feature displayed by the evolved granites and aplites from Torres del Paine Intrusive complex suite sampled by [START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF] (Fig. 15D). The BLG also exhibit negative anomalies in P and Ti, as well as an absence of Nb-Ta anomalies, Based on the petrography and the geochemistry, we propose a 4 groups subdivision for the plutons alkalinity: alkaline (sensu stricto), "intra-plate transitional" calc-alkaline, "arc transitional" calc-alkaline, and calc-alkaline rocks.

These groups can be identified in figures 16 and 17, and their characteristics are described below.

Alkaline plutons

The Monte Balmaceda intrusive complex (Fig. 3) and the Pliocene plutons located in Meseta del Lago Buenos Aires (Fig. 2) [START_REF] Espinoza | Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)[END_REF] are included in this group. The presence of hydrated minerals is rare in these plutons.

In addition they have strong "intra-plate" features, specifically high REE content (Fig. 15E) -specially LREE-and HFSE contents, a lack of Nb-Ta negative anomaly, strong negative anomalies in Sr, Ba, P, Ti in the felsic rocks and a flat pattern in the spider diagrams for the mafic rocks (Fig. 15F). The only samples studied with modal and normative alkaline minerals (aegerine) are from the Monte Balmaceda suite. [START_REF] Espinoza | Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)[END_REF] propose that the alkaline Pliocene plutons are derived from evolved magmas, differentiated by AFC processes in a shallow magma chamber filled with OIB-like magmas from enriched basaltic melts. Our data support this hypothesis, as shown in Fig. 17A, where the Pliocene alkali granites plagioclase fractionation is evidenced in Sr/Nd dispersion, and crust assimilation in Nb/La. 12E,F and 15E,F).

"Arc transitional" calc-alkaline plutons

This group comprises the Paso de Las Llaves and Cerro Negro del Ghío plutons from the northern area (Fig. 2), and the Cerro Donoso pluton from the southern area (Fig. 3). They have distinctive arc features such as hydrated mineral phases, clear Nb-Ta negative anomaly, and trace elements pattern correlated with the South Patagonian batholith (SPB) (Figs. 12B and D and 15B).

Notwithstanding, the plutons from this group are subtly more alkaline than SPB, with Na-K content near the Irvine and Baragar (1971) alkaline/sub-alkaline limit (Fig. 10A). Furthermore, they have high content in HFSE (Figs. 12B,D and 15B) that is reflected in the ratio Ba/La< 20, which is commonly >20 for arc rocks, including the Cenozoic SPB (Fig. 16).

Andean Geology 48 ( 3 The Zeballos Group data is from [START_REF] Espinoza | Volcanismo calcoalcalino durante el Mioceno Medio en Patagonia Central (47°S): petrogénesis e implicaciones en la dinámica de placas[END_REF]; References for the Plateau Lavas data as in Fig. 14.

Calc-alkaline plutons

The only known calc-alkaline pluton with "pristine" arc signature in this "extra-Andean" location in Patagonia is the Fitz-Roy pluton [START_REF] Michael | Emplacement and differentiation of Miocene plutons in the Andean[END_REF]Kosmal and Spikermann, 2002;Ramirez de Arellano, 2011).

Other known intrusive with calc-alkaline signature are the Paine External Gabbros studied by Michael (1991) (Figs. 10D and 11C).

Origin of the plutonism: conceptual models

The wide "transitional" alkaline character of the plutons and the proposed subdivision described above, together with their isotopic ratios, suggest multiple scenarios for development of magmatism.

Cerro Negro del Ghío and Paso de Las Llaves plutons

Both units have "arc transitional" characteristics (Fig. 16) compatible with arc-magmatism, but also several geochemical evidences of contributions from an enriched mantle magma source (e.g. high HFSE content). As Cerro Negro del Ghío pluton is considered the intrusive equivalent of the Zeballos Lavas Sequence [START_REF] Espinoza | Volcanismo calcoalcalino durante el Mioceno Medio en Patagonia Central (47°S): petrogénesis e implicaciones en la dinámica de placas[END_REF], the magma source model proposed by these authors is considered for the Cerro Negro del Ghío pluton, including calc-alkaline subduction derived components, and an interaction with an enriched component (Espinoza et al., 2010). Based on [START_REF] Hildreth | Crustal contributions to arc magmatism in the Andes of Central Chile[END_REF] As the rocks from Paso de Las Llaves pluton have a more evolved Nd t signature than Cerro Negro del Ghío pluton (

P R E S S

In the case of Cerro Negro del Ghío pluton, the more enriched magma source evidences are the high alkali, LREE and HFSE contents. Furthermore, the Nd t values point to mantle sources (+2.4 to +2.9). Therefore, a more fertile mantle source with respect to Paso de Las Llaves pluton is proposed, in which subduction-derived fluids, and/or magmas, interacted with the enriched SCLM in the proposed MASH zone in the crust -mantle interface to rise alkali, LREE and HFSE contents.

A completely different magma source is suggested for the garnet bearing porphyritic granite, whose isotopic ratios ( 87 Sr/ 86 Sr, Nd t, Table 5) reflect a major crustal component, which may be due to partial melting of the host rocks of the Paso de Las Llaves pluton, i.e., either the Tobifera Formation, or the metasedimentary rocks (seen in the xenolith in the border of the pluton) (Fig. 5a).

San Lorenzo and Río de las Nieves plutons

Both plutons have "intra-plate transitional" geochemical features (Fig. 16).

The San Lorenzo pluton is more acidic, closer to the peralkaline field (A/CKN and A/NK ratios just above 1), and isotopic evolved (Ndt between +0.3 and -1.4) which may date back to the Paso de Las Llaves plutonism period. This is similar to the model proposed by [START_REF] Welkner | Geología del área del cerro San Lorenzo: Cordillera Patagónica Oriental, XI Región de Aysén[END_REF] for the San Lorenzo pluton. The higher Nd t in Río de las Nieves pluton (+1.3) than in San Lorenzo may implicate more SCLM contribution in this pluton, or alternatively, minor degree of assimilation of the continental crust.

than

Cerro Donoso Pluton and Paine External Gabbros

Both units are "arc-transitional" calc-alkaline (Fig. 16). The slightly larger content in LREE and alkali of these plutons compared to SPB can be explained by their back-arc location with respect to the Neogene arc (Cerro Donoso pluton is between 45 to 100 km eastward the SPB Neogene plutons, according to Hervé et al., 2007) due to a possible more enriched astenosphere partial melting in this back-arc position, similar to what is proposed for the Cerro Negro del Ghío pluton.

Monte Balmaceda Intrusive Complex

The Balmaceda Mafic Complex geochemical signature, resemble those of OIB for most trace elements, especially HFSE (Fig. 15E,F), but also the LILE/HFSE, LREE/HFSE ratios (Fig 17 ), and the Zr/Nb< 10 and La/Ta <15 ratios, or also Ba/La <10 [START_REF] Elliott | Element transport from slab to volcanic front at the Mariana arc[END_REF][START_REF] Kay | Magmatism as a probe to the Neogene shallowing of the Nazca plate beneath the modern Chilean flatslab[END_REF]Fig. 16). This complex shares many geochemical characteristics with the back-arc Neogene volcanic rocks in south Patagonia (e.g. Figs. 16,17B). Otherwise, the isotopic ratio reflects a primitive magma source (Nd t up to +5). All these features combined suggest a mantle source enriched in incompatible elements for the magmas.

Notwithstanding, its high Pb content (up to 51 ppm), as well as its variable high content in Th (3.5 to 13 ppm) and U (1 to 3.5 ppm; [START_REF] Elliott | Element transport from slab to volcanic front at the Mariana arc[END_REF]. plagioclase fractionation [START_REF] Hawkesworth | The differentiation and rates of generation of the continental crust[END_REF]. Samples from the northern and southern areas are plotted together with data from Cenozoic rocks from the SPB and alkaline and "transitional" plateau lavas for comparison (references in Fig. 10), as well as OIB, E-MORB, N-MORB [START_REF] Sun | Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes[END_REF], bulk crust, upper and lower continental crust averages (UCC and LCC respectively) [START_REF] Rudnick | Composition of the continental crust[END_REF]. A. Northern area, the segmented lines enclose: The Balmaceda Leucogranite (BLG) geochemistry evidences a REE-enriched magma source (Fig. 15E). Their distinctive Sr, P, Eu and especially Ba and Ti negative anomalies (Fig. 15F), are characteristic of intraplate granitoids [START_REF] Winter | An Introduction to Igneous and Metamorphic Petrology[END_REF], but these anomalies may also represent strong crystal fractionation of plagiocase (Eu, Sr, minor Ba), amphibole and magnetite (Ti), as these are devoid phases in BLG. Nevertheless, the LILE/HFSE and LREE/HFSE ratios have similar values to those of the OIB like Balmaceda Mafic Complex, with Ba/La <10, La/Ta< 15 and Zr/Nb< 10, reflecting intra-plate signatures [START_REF] Elliott | Element transport from slab to volcanic front at the Mariana arc[END_REF]and Fig. 16). Their isotopic ratios show Nd t values ranging between +2 and +4.6 (Fig. 13). These data discriminate the samples from different areas, where those from the northern slope of the mount have the lowest Ndt values. This difference is not recorded in the mafic facies. In any case, the felsic facies with the lowest Nd t also have high LILE/HFSE and LREE/HFSE ratios, as well as a slight Nb negative anomaly, reflecting subtle subduction components and/or crustal contamination.

These isotopic variations may reflect discontinuous emplacement of different batches of felsic magmas as contact relationship suggests strongly that Nd did not have enough time to evolve in the magma after emplacement.

This intrusive complex reflects the emplacement of magmas probably issued from two different reservoirs. Both the OIB-like alkaline gabbro and the leucogranites have subtle subduction and/or crustal contamination components, but their Ndt (>+4) evidences enriched mantle sources for those magmas.

Neither its bulk chemistry nor its petrography suggests further variation by assimilation-fractional crystallization (AFC) processes after emplacement between further assimilation of crust rocks (with subduction imprints, not reflected in the rocks with Nd t =+4) or they are subduction derived. As the Nd t =+2 rocks have no higher silica or alumina content compared to those with Nd t =+4 (tables 4, 5), assimilation should not be the most important process involved.

A pluton with similar petro-mineralogical characteristics but late Cretaceous in age has been described in Del Salto area in an "extra-Andean" position, specifically at Cordillera San Lorenzo [START_REF] Welkner | Peralkaline rocks in the Late Cretaceous Del Salto Pluton, Eastern Patagonian Andes, Aisén, Chile (47°35'S)[END_REF] (Del Salto pluton in Fig. 2). The similar Ba, Sr and remarkable pronounced Eu negative anomaly, as well as the high Pb content and presence of Na-amphiboles in both intrusives, may be indicative of similar magma sources for the Balmaceda Leucogranites and (2002) proposed an extensive interaction between mantle-derived magmas and the crust during the early relaxation stage that followed the mid-Cretaceous

Andean crustal thickening and marginal basin closure [START_REF] Welkner | Peralkaline rocks in the Late Cretaceous Del Salto Pluton, Eastern Patagonian Andes, Aisén, Chile (47°35'S)[END_REF]. In this sense, the interaction of SCLM-derived magmas with Jurassic and Paleozoic continental crust is a plausible scenario for both igneous bodies. This interaction may have been favored by an extensional setting. Nevertheless, there is no further evidence of extension in the Monte Balmaceda area, so a period of relaxation, prior to ridge subduction, may be a possible scenario for the localized extensional setting in these periods. This scenario has been suggested in the Meseta del Lago Buenos Aires area (see Fig.

Torres del Paine Intrusive Complex

This intrusive complex shows an "intra-plate transitional" calc-alkaline chemical signature (Fig. 16), with many geochemical features similar to the San Lorenzo pluton (e.g. Figs.12,15). Considering its bimodal character, Michael (1991) suggested a common origin for both mafic and silicic magmas of the suite.

This common source for both magmas, was also supported by later geochemical studies by [START_REF] Leuthold | A detailed geochemical study of a shallow, arc-related laccolith: the Torres del Paine mafic complex, Patagonia[END_REF]. (the La/Ta ratio of Cenozoic rocks from SPB is >25) (Fig. 16), and a slight negative Nb-Ta anomaly (Fig. 15D). These features suggest a geochemically intermediate magma affinity for the Torres del Paine intrusive complex, probably formed in a transitional tectonic setting between arc and back-arc (OIB-like), well reflected in the Ba/La ratio (Fig. 16), which is between 10 and 20 for this intrusive complex, between 10 and 12 for the OIB-like back-arc lavas [START_REF] D'orazio | Slab window-related magmatism from southernmost South America: the Late Miocene mafic volcanics from the Estancia Glencross Area; ~52°S, Argentina-Chile[END_REF], and between 15 and 38 in arc granitoids from the Cenozoic SPB [START_REF] Hervé | The South Patagonian batholith: 150 my of granite magmatism on a plate margin[END_REF]. Consequently, we propose that the Torres del Paine suite was probably formed by the emplacement of SCLM-derived magmas stored in the lower crust together with magmas generated by the melting of this crust (a MASH zone), similar to the case of the Monte Balmaceda Intrusive Complex mentioned above, with the difference that the stored magmas for the Torres del Paine

Complex have been metasomatized by subducted slab-derived components (e.g.

Sr, Ba, Th, Ca) and carried by hydrated melts and/or fluids in significantly larger quantities than in Monte Balmaceda Intrusive Complex (if this has any). This process is evidenced either by the higher Ba/La (Fig. 16), Th/Nb and La/Ta (or Nb/La) ratios in Torres del Paine Intrusive Complex (Figs. 16 and17B), where the former ratio reflects slab derived fluids (Elliot et al., 1997), and the others reflect slab derived melts [START_REF] Hawkesworth | Elemental U and Th variations in island arc rocks: implications for U-series isotopes[END_REF], or by the occurrence of hydrated mineral phases in the felsic facies. : Figs. 12,14,15,16), which means that they do not derive from magmas formed in a back-arc environment, and consequently the "extra-Andean" plutons denomination is preferred. In this sense, two hypotheses may explain this magmatism: a lateral expansion of the magmatic arc, or the migration of the arc, either case to the east. Arc migration is preferred, as the scarce volume of igneous rocks which crop out in the region, which is not fully consistent with an expansion of the magmatic arc. Furthermore, the known outcrops are at similar distance from the SPB (see Fig. 1). This arc migration should produce melts from the mantle and/or the crust in diverse amounts according to each region, tectonic feature, and processes involved in the magmatism migration, coherent with the heterogeneous geochemical alkalinity character of the Neogene extra-Andean plutons.

The geochemical diversity found in the studied plutons is put together with their geographic location in Figure 18, where a cartoon illustrates the position of the Chile Rise segments before their collision with the trench at ca. 16 Ma (Fig. 18A), and three successive stages. A remarkable point is that at ca. 14 Ma very young oceanic crust started to subduct beneath almost all the south Patagonian western margin (>700 km), which is linked to three long segments of the Chile Rise. The last of these segments arrived to the trench at ca. 10 Ma (Fig. 18B) [START_REF] Cande | Late Cenozoic tectonics of the Southern Chile Trench[END_REF]. In its foreland region the southern area plutons of this work are located (Fig. 18). Meanwhile in the northern area, the Chile Rise subducted in short segments (around 1/3 compared to the segments in the south) since ca. 6 Ma (Fig. 18C). They had much more separation between them by fault zones than those of the south (Fig. 18). Having this in mind, we propose that even if the arc migration to the east should have occurred more or less simultaneously in all southern Patagonia, the differences in the tectonic configurations between the northern and southern areas contributed to the strong differences in the geochemistry of the studied plutons. In the northern area magmatism is "arc-transitional" calc-alkaline (slightly more alkaline than the SPB) between the period comprised by the magmatism that generated the Zeballos Group Lavas, the Cerro Negro del Ghío and Paso de Las Llaves plutons (between ca. 16 and 8 Ma), while alkaline and "intra-plate transitional" calc-alkaline plutonism took place in the southern area (Monte Balmaceda and Torres del Paine intrusive complexes, respectively). Plate (in gray) have been drawn in approximate locations following [START_REF] Cande | Late Cenozoic tectonics of the Southern Chile Trench[END_REF]. A more precise reconstruction has been made for the northern area at ca. 6 Ma in Figure 19. CNGP:

Cerro Negro del Ghío Puton; SLP: San Lorenzo pluton; PdLLP: Paso de Las Llaves pluton; TdPIC:

Torres del Paine intrusive complex. Cartoons after [START_REF] Cande | Late Cenozoic tectonics of the Southern Chile Trench[END_REF], [START_REF] Lagabrielle | Neogene to Quaternary tectonic evolution of the Patagonian Andes at the latitude of the Chile Triple Junction[END_REF] and [START_REF] Breitsprecher | Neogene kinematic history of Nazca-Antarctic-Phoenix slab windows beneath Patagonia and the Antarctic Peninsula[END_REF]. Southern areas of this work (Fig. 1). These authors argued for subduction erosion as the main process for arc migration, discarding slab flattening because of the need to change the subduction angle from 44 to 29º to fix the magmatism locations; instead, a change in the angle from 34 to 29º with 50 km of subduction erosion is the hypothesis preferred by these authors. However, the geochemical heterogeneity for the plutons compels us not to considerate only one hypothesis.

So if we take subduction erosion as the main factor in all south Patagonia, all the plutons should be calc-alkaline sensu stricto. Nevertheless, as seen in Section 6.1, it is not the case for most of the plutons.

Even if we suppose that arc migration was a simultaneous process in all

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I N P R E S S

south Patagonia, we have to take into account that in the southern area a longer, younger and hotter slab than that in the northern area was subducted at the same time (ca. 16-15 Ma.; Fig. 18), factors which may have helped to increase the partial melting of the SCLM, and therefore, to produce the high Ndt alkaline -OIB like-magmatism. Slab flattening process has been related to strong tectonic coupling, and therefore to upper crust deformation (e.g. Kay and Mpodozs,

The timing of deformation in south Patagonia is poorly constrained (Suárez et al., 2000). [START_REF] Fosdick | Kinematic evolution of the Patagonian retroarc fold-and-thrust belt and Magallanes foreland basin, Chile and Argentina, 51°30′S[END_REF] show that thrust faults were active at ca. 51ºS between 22 and 18 Ma, and propagated eastward after 18 Ma (Fig. 19). This contractional event can be linked to a fast convergence rate period which started at 25 Ma [START_REF] Pardo-Casas | Relative motion of the Nazca (Farallon) and South American plates since Late Cretaceous time[END_REF] and/or to buoyancy of the subducted plate. At 16.5 Ma a climate change in the foreland region is recorded at ca. 49ºS.

This change is related to a 1 km uplift of the Andean range, and to a cease in sedimentary deposition at 14 Ma [START_REF] Blisniuk | Climatic and ecologic changes during Miocene surface upliflt in the southern Patagonian Andes[END_REF]. Both events pre-date the Chile rise subduction south of 49º S. Thus, this strong tectonic coupling previous to the emplacement of the alkaline magmas in the southern area may have been linked to the buoyancy of the hot and young oceanic crust subduction (Suárez et al., 2000; Figure 19), and after the strong coupling, tectonic relaxation may have triggered the Monte Balmaceda alkaline magmatism as in Del Salto pluton proposed model [START_REF] Welkner | Geocronología de los plutones del área del cerro San Lorenzo, XI Región Aysén. In: Congreso Geológico Chileno[END_REF]. This could explain the extra-Andean shown (from [START_REF] Fosdick | Kinematic evolution of the Patagonian retroarc fold-and-thrust belt and Magallanes foreland basin, Chile and Argentina, 51°30′S[END_REF]. Subducted slab geometry is inspired in the present flat slab subduction zone at 27-33ºS in South America (e.g. [START_REF] Kay | Magmatism as a probe to the Neogene shallowing of the Nazca plate beneath the modern Chilean flatslab[END_REF][START_REF] Deshayes | Three-dimensional P-and Swave seismic attenuation models in central Chile -western Argentina (30°-34°S) from local recorded earthquakes[END_REF]. The "Hot Zone" is following [START_REF] Annen | The Genesis of Intermediate and Silicic Magmas in Deep Crustal Hot Zones[END_REF]. SPB: South Patagonian batholith, SCLM:

Sub-Continental Lithospheric Mantle. NAZ: Nazca plate. 11cm/a: average convergence rate between Nazca and South American plates, from Pardo-Casas and Molnar (1987), [START_REF] Somoza | Updated Nazca (Farallon)-South America relative motions during the last 40 My: Implications for mountain building in the central Andean region[END_REF] and [START_REF] Breitsprecher | Neogene kinematic history of Nazca-Antarctic-Phoenix slab windows beneath Patagonia and the Antarctic Peninsula[END_REF] data.

The proposed flat slab model has a variable dipping angle (Fig. 19), instead of a constant one (Ramírez de Arellano et al., 2012a), as observed in the present day Chilean flat subduction zone (e.g. [START_REF] Kay | Magmatism as a probe to the Neogene shallowing of the Nazca plate beneath the modern Chilean flatslab[END_REF][START_REF] Ramos | El magmatismo neógeno de la Cordillera Patagónica[END_REF][START_REF] Deshayes | Three-dimensional P-and Swave seismic attenuation models in central Chile -western Argentina (30°-34°S) from local recorded earthquakes[END_REF]. As Miocene alkaline (s.s.) rocks are not widely known in south Patagonia, this relaxation stage should not produce an important volume of magma, so it might have been a local phenomenon.

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Although mid-Miocene plutons are found in both the northern and southern areas, in the northern area they have more pristine arc signatures -"arc transitional" calc-alkaline (Fig. 16)-; therefore, a different scenario for magmatism, and hence, for magmatic arc migration process, should occur in this region. Contractional tectonism would have occurred sometime between 29 and 15 Ma (Suárez et al., 2000). This again can be linked to fast convergence rates between 25 to 16 Ma [START_REF] Pardo-Casas | Relative motion of the Nazca (Farallon) and South American plates since Late Cretaceous time[END_REF][START_REF] Somoza | Updated Nazca (Farallon)-South America relative motions during the last 40 My: Implications for mountain building in the central Andean region[END_REF] coeval with arc-migration: Neogene plutonism in arc location (SPB) is 25-15 Ma [START_REF] Hervé | The South Patagonian batholith: 150 my of granite magmatism on a plate margin[END_REF], and begins in extra-Andean location with Cerro Negro del Ghío pluton at ca. 15 Ma. Thus, at the end of this period, arc magmatism took place in an extra-Andean location and lasted until, at least, 9 Ma (Paso de Las Llaves intrusive suite). If here the arc shift was linked to buoyancy of the subducted plate, there was no tectonic relaxation like in the southern area, possibly due to the arrival of another Chile Rise short segment at the same latitude, which was coeval with the subduction of young slab (Fig. 18 and 20). Alternatively, subduction erosion may not be dismissed as a factor contributing, together with slab flattening, to shift the arc location and to produce the "arc transitional" calc-alkaline plutons from ca. 15 to 9 Ma (Fig. 18) in this area. Ma. It is assumed that the Chile Rise segments (CRS) generated a slab window (in white in plant view) due to the differences in the convergence rates between the Nazca/South American plates and the Antarctic/South American plates, considering rates of 10.2 cm/a and 3.1 cm/a, respectively (averages values from [START_REF] Cande | Late Cenozoic tectonics of the Southern Chile Trench[END_REF]Leslie (1986), Pardo-Casas and[START_REF] Pardo-Casas | Relative motion of the Nazca (Farallon) and South American plates since Late Cretaceous time[END_REF], [START_REF] Somoza | Updated Nazca (Farallon)-South America relative motions during the last 40 My: Implications for mountain building in the central Andean region[END_REF] and Breitspecher and Thorkelson (2009)). Besides, the distances of the edges of this window to the trench has been calculated considering the angle of subduction, the obliquity angle of the slabs convergence (from the same authors) and considering 4 Ma after the CRS-3 started its subduction [START_REF] Cande | Late Cenozoic tectonics of the Southern Chile Trench[END_REF]. In this model, the wedge of the slab window grows north and eastward. The subducted slabs may contribute fluids to be stored in the astenosphere-sub-continental Lithospheric Mantle (SCLM) interface; and the opening of the window may allow to generate a thermal anomaly, which, together with the addition of fluids, in turn generate a "Hot Zone" triggering underplate and crust melting. This scenario could occur again at ca. 3 Ma, with the opening of a slab window with the CRS-2. The upper crust structures are simplified from [START_REF] Ramos | Southern Patagonian plateau basalts and deformation: backarc testimony of ridge collision[END_REF] and [START_REF] Lagabrielle | Neogene to Quaternary tectonic evolution of the Patagonian Andes at the latitude of the Chile Triple Junction[END_REF]. NAZ: Nazca Plate, FZ:

Fault Zone, SPB: South Patagonian batholith.

Andean Geology 48 (3): xxx-xxx. September, 2021 doi: 10.5027/andgeoV48n3-3158

I N P R E S S

A more complex tectonic scenario occurred after ca. 10 Ma in the northern area with the oblique subduction of the Chile Rise (77-82º in Breitspecher and Thorkelson, 2009), where the Chile Rise Segment (CRS)-3 (Fig. 18) may have developed a slab window, opening north and eastward. Therefore, after 4 Ma of development (at ca. 6 Ma), this slab window (or at least the north-eastern corner of it) must have been in back-arc position at the same latitude than CRS-2 (Figure 20). In this region the "transitional arc" calc-alkaline magmatism evolved to a "transitional intra-plate" magmatism (the San Lorenzo pluton), in which subduction components should had been stored in a MASH zone. Then, lower crust plus SCLM melting should have been triggered by heat influx from the slab window development beneath the South American plate (Figure 20).

At ca. 3 Ma, northward, the tectonic configuration must have been very similar to the one explained at 6 Ma, but with CRS-2 at the foreland position, and CRS-1 in the trench. Here, magmatism resulted in the "transitional intra-plate" calc-alkaline Río de Las Nieves pluton. Eastward, there was bimodal alkaline magmatism expressed into the basaltic Meseta del Lago Buenos Aires plateau lavas and the felsic intrusive bodies [START_REF] Espinoza | Bimodal back-arc alkaline magmatism after ridge subduction: Pliocene felsic rocks from Central Patagonia (47°S)[END_REF]). These authors argued for strong intraplate AFC processes from OIB melts without influence of the subducted slab. Indeed, the melting process they suggested is by decompression due to astenospheric window development, which is fully consistent with our proposed conceptual model at regional scale. -High Pb content: over 6 ppm, up to 51 ppm (tables 3 and4).

-High LREE content.

-Steep LREE and flat HREE pattern.

-Isotopic ratios with ( 87 Sr/ 86 Sr) i < 0.705 and Nd t > -1.4, mostly over 0.

5. An eastward migration of the magmatic arc previous to the Chile Rise arrival to the continent is consistent with the "transitional" geochemistry of the plutons, and the tectonic configuration differences between the northern and southern areas contribute to the particular magmatic evolution of each area.

6. Two ways of magma evolution can be noted: from alkaline to "intraplatetransitional" calc-alkaline (Miocene, southern area) and from "arc transitional" to "intraplate-transitional" calc-alkaline to alkaline (Mio-Pliocene, northern area). Lat. ºS 46,6274 46,6279 46,6282 46,6288 46,6292 46,6296 46,63033 46,63000 46,62950 46,62789 46,62779 46,63092 46,62977 46,62977 46,6165 46,61783 46,61594 46,60019 46,60019 47,11214 47,11268 47,11404 47,08499 47,12116 47,12006 47,08269 Lon. ºW 72,3549 72,3590 72,3597 72,3601 72,3604 72,3605 72,36069 72,36061 72,36047 72,3594 72,35779 72,36006 72,36327 72,36327 72,26566 72,2692 72,26772 72,22856 72,22856 71,85268 71,85264 71,85735

- - - - - - - - - - - - - - - - - - - BaO - - 0 0 0,03 0 0 - - - - - - - - - - - - Na2O
Sample 07LL2 07LL3 07LL4 07LL5 07LL6 07LL7 07LL9 07LL11 07LL12 07LL14 07LL15 0 7LL25 07LL17 07LL18 07LL19 07LL20 07LL22 07LL23 07SM1 07SM6 07SM8 07SM13 COY0230 COY0231 COY0232 COY0233 COY0234 COY0235 CH4131 07SM3 07SM4 07SM2

Figure 1 :

 1 Figure 1: Regional map of south Patagonia illustrating the main magmatic units. The segmented line shows the extra-Andean plutons location, between the South Patagonian batholith to the west and the plateau lavas to the east. Northern and southern areas location are shown as figures 2

Figure 2 :Figure 3 :

 23 Figure 2: Geologic map of the northern area, showing the location of Paso de Las Llaves, Cerro Negro del Ghío, Río de Las Nieves and San Lorenzo plutons. Geology simplified after Welkner (1999); Welkner et al. (2002); Giacosa and Franchi (2001); Lagabrielle et al. (2007); Espinoza et al. (2008); Scalabrino et al. (2010); Espinoza et al. (2010); Boutonnet et al. (2010).

Figure 4 :

 4 Figure 4: MORB normalized spider diagrams (Pearce, 1983) from previous works on magmatic units in Patagonia. A. Northern area, main plateau lavas and post-plateau lavas. 1:OIB: Ocean Island Basalt average (Sun and McDonough, 1989); 2: Post-plateau Lavas includes NPPL: North Patagonian Plateau Lavas, Central, Belgrano, and Muerte plateaus (Gorring and Kay, 2001) and MLBA: Meseta del Lago Buenos Aires (Guivel et al., 2006); 3: MP: Main Plateau lavas, includes the NPPL: Central, Belgrano, Noreste, and Muerte plateaus (Gorring and Kay, 2001); Meseta Chile

  work was performed in the Aysen (Chile) and Santa Cruz (Argentina) regions northern area, during November and December, 2007. Paso de Las Llaves, Cerro Negro del Ghío, and plutons in Meseta del Lago Buenos Aires were sampled then. The samples of San Lorenzo and Río de las Nieves plutons were collected in earlier campaigns by D. Morata. The southern area at Última Esperanza (Chile) region was studied in December 2004, and January and February 2007. Torres del Paine, Balmaceda intrusive complexes and Cerro Donoso pluton were sampled then. Rock samples for geochemical and isotopic analyses consisted of 1-3 kg of material, which were crushed and split to 200 g, and then pulverised in an agate mill. The mineral chemistry analyses were conducted using a Cameca SX50 electronic microprobe at the Laboratoire des Mécanismes et Transfert en Géologie (LMTG), Toulouse (France), now Géosciences Environnement Toulouse (GET). Analytical conditions were 15 kV voltage and 20 nA current. The results for the Andean Geology 48 (3): xxx-xxx. September, 2021 doi: areas are listed on tables 1 and 2, respectively.

Figure 5 :

 5 Figure 5: Field photographs from northern area. A. Schist xenoliths close to a vertical contact of the Paso de Las Llaves pluton. B. Granite (gte) intrusion in diorite (dte) with lobate contacts. Río Avilés area, Paso de Las Llaves pluton. C. Hill top northward of Cerro Negro del Ghío pluton, where quartz-diorite intrude lavas from the Ibañez Group. The sample 07SM13 is from this area. D. Cerro Negro del Ghío pluton. The sill like disposition can be appreciated as well as a distinct whitish facies in the southeast border of the intrusive.

Figure 6 :

 6 Figure 6: Field photographs from cerro Donoso in the southern area. A. Cerro Donoso pluton, panoramic view to the east showing vertical contacts. B. Granodioritic facies in the lower levels of the outcrop (930-1000 m a.s.l.), quartz-veins and mafic enclaves are frequent characteristics inside the granodiorite. C. Vertical fabric given by hornblende crystals orientation in the granodiorite, this facies area is near the "core" of the pluton. D. Quartz-diorite outcrop with subhorizontal disposition, representing the only massive mafic facies found in this pluton. E. A faulted rhyolitic dike in the nearby area of the Cerro Donoso pluton. Dike is ca. 60 cm wide.

Figure 7 :

 7 Figure 7: Micro-photographs. A. Plagioclase with several growth stages, plane light, from the granite in Cerro Donoso pluton. B. Sodic amphiboles in the leucogranite facies, polarized light. C. Aegerine pyroxene in the leucogranites, plane light. D. Idem C, polarized light. E. Titanium-rich augite in the alkaline gabbro. F. Idem E, polarized light. B to F are from the Monte Balmaceda intrusive complex.

Figure 8 :Figure 9 :

 89 Figure 8: Field photographs from the Monte Balmaceda intrusive complex, southern area. A. Panoramic view of the northern face of the Monte Balmaceda. Some of the disconnected outcrops of intrusive rocks are shown highlighted by yellow borders. B. Discordant intrusive contacts with sub-horizontal layered sedimentary rocks. C. Intrusive contact showing some "stepping", a common feature in the Glaciar Serrano area. D. Zig-zag contact between the Leucogranites and the Balmaceda Mafic Complex, the outcrop is in the Monte Balmaceda northern face. This pattern is caused by the subhorizontal contact between these units, with the mafic unit below the felsic one.

  9C, D), evidencing a pseudostratigraphic pattern in the pluton. Mixing and mingling textures between the felsic and mafic facies are present, in which monzonite patches are common, containing alkali feldspar and labradorite/andesine plagioclase. The massive mafic facies comprise alkaline gabbros and quartz-diorites. The gabbros contain pink titaniferous augite (some Andean Geology 48 (3): xxx-xxx. September, 2021 doi: 10.5027/andgeoV48n3-3158 have aegerine rims) (Fig.7E, F), biotite, oxidized amphibole and Kfeldspar, apatite being a frequent accessory mineral. In the mingling facies the diorites do not contain pyroxene but are rich in biotite and oxidized amphiboles.

  alkaline-subalkaline limit, being clearly more alkaline Andean Geology 48 (3): xxx-xxx. September, 2021 doi: (Fig. 10A, 11A). A few mafic rocks from both areas have normative nepheline.

Figure 10 :

 10 Figure 10: TAS diagrams. A. Miocene pluton from the northern area. B. Pliocene plutons from the northern area. C. Miocene Torres del Paine and Monte Balmaceda intrusive complexes. D. Cerro Donoso pluton and Paine External Gabbros. Limit between the alkaline and subalalkaline areas (dashed line) is from Irvine and Baragar (1971). References: 1: Welkner (1999); 2: Michael (1983); 3: Espinoza et al. (2005); 4: Espinoza et al. (2010); 5: Vargas and Hervé (1995); 6: Gorring and Kay (2001); 7: Guivel et al. (2006); 8: Espinoza et al. (2008); 9: Kaeding et al. (1990); 10: Guivel et al. (1999); 11: Anma et al. (2009); 12: Baker et al. (1981); 13: Gorring et al. (2003); 14: Michael (1984); 15: Michael (1991); 16: Camusú Aike volcanic field (D'Orazio et

Figure 11 :

 11 Figure 11: Trace elements alkaline discrimination diagrams. A. Zr/TiO2 vs Nb/Y diagram (Winchester and Floyd, 1977) northern area plutons. B. Th-Co diagram (Hastie et al., 2007) for the northern area plutons. C. Zr/TiO2-Nb/Y diagram for plutons from the southern area. D. Th vs Co diagram for plutons from the southern area. Only two samples from the Balmaceda Leucogranites (07BA22 and 07BA26) have anomalous high Co content for a high silica granite, nevertheless the content in Th is coherent with their K content. On the contrary, sample 07BA25 has lower Co concentrations than less basic samples from the Balmaceda Mafic Complex, so the calc-alkaline plot of this sample may be an artifact. The shaded area in A and C represents the projection of the SPB (South Patagonian batholith) samples (from Hervé et al., 2007) and the dashed areas the Miocene-Pliocene plateau lavas and volcanic field samples from the Camusú Volcanic fields in D: the Aike volcanic field (D'Orazioet al., 2005), and the Glenn Cross Area[START_REF] D'orazio | Slab window-related magmatism from southernmost South America: the Late Miocene mafic volcanics from the Estancia Glencross Area; ~52°S, Argentina-Chile[END_REF]. The other references as in Figure10.

Figure 12 :

 12 Figure 12: Trace elements patterns for plutons from the northern area. REE diagrams are normalized to chondrite[START_REF] Nakamura | Determination of REE, Ba, Fe, Mg, Na and K in carbonaceous Andean[END_REF], and the spider diagrams to MORB[START_REF] Pearce | Role of sub-continental lithosphere in magma genesis at active continental margins[END_REF]. A.

  Paso de Las Llaves pluton. B. Spider diagrams for Paso de Las Llaves pluton. C. REE pattern for Cerro Negro del Ghío pluton. D. Spider diagrams for Cerro Negro del Ghío pluton. E. REE pattern for San Lorenzo pluton. F. Spider diagrams for San Lorenzo pluton. 1: OIB: Ocean

Figure 13 :

 13 Figure 13: Isotopic composition diagrams for Miocene plutons from the northern and southern areas. A. Ndt vs Zr/TiO2 ratio for plutons from the northern area. 1: Zeballos Group Lavas, Espinoza et al. (2010); 2: Miocene rhyolites, Espinoza et al. (2005). B.. Ndt vs ( 87 Sr/ 86 Sr)i ratio for plutons from the northern area, with bulk Earth divisions at present time. Data plotted for comparison: Extra-andean adakites[START_REF] Ramos | Las adakitas de la Cordillera Patagónica: Nuevas evidencias geoquímicas y geocronológicas[END_REF]; Miocene "transitional" and alkaline lavas[START_REF] Gorring | Mantle processes and sources of Neogene slab window Andean[END_REF][START_REF] Espinoza | Petrogenesis of the Eocene and Mio-Pliocene alkaline basaltic magmatism in Meseta Chile Chico, Southern Patagonia, Chile: evidence for the participation of two slab windows[END_REF][START_REF] Guivel | Miocene to Late Quaternary Patagonian basalts (46-478S): Geochronometric and geochemical evidence for slab tearing due to active spreading ridge subduction[END_REF]. C. Ndt vs Zr/TiO2. ratio for plutons from the southern area. D. Ndt vs ( 87 Sr/ 86 Sr)i ratio for plutons from the southern area. Data is compared with the isotopic composition of the Glencross Area and Camusú-Aike volcanic fields[START_REF] D'orazio | Slab window-related magmatism from southernmost South America: the Late Miocene mafic volcanics from the Estancia Glencross Area; ~52°S, Argentina-Chile[END_REF] 2005 respectively). In B and D, SPB data is from[START_REF] Hervé | The South Patagonian batholith: 150 my of granite magmatism on a plate margin[END_REF].

Figure 14 :

 14 Figure 14: Trace elements and isotopic composition diagrams for the Pliocene northern area plutons. A. REE diagrams normalized to chondrite (Nakamura, 1974). B. Spider diagrams normalized to MORB (Pearce, 1983). C. Ndt vs ( 87 Sr/ 86 Sr)i . References: 1: Espinoza et al. (2008); 2: Sun and McDonough, (1989); 3: Gorring and Kay (2001); 4: Hervé et al. (2007).

  from the Torres del Paine and Monte Balmaceda intrusive complexes, and the Cerro Donoso pluton.Andean Geology48 (3): xxx-xxx. September, 2021 doi: 10.5027/andgeoV48n3-3158 The pluton has a restricted range of SiO 2 content, between 55 (the quartz diorite) and 66 wt.%. Out of this range are the basaltic and rhyolitic dikes, with 45 and 70 wt.%, respectively. The pluton samples are peraluminous. Similarly to SPB, they are mostly sub-alkaline in the TAS diagram and according to Nb/Y ratio (Figs. 10D, 11C), or high K calc-alkaline in the Peccerillo and Taylor (1976) (not shown) and Th-Co diagrams (Fig. 11D). Most samples have normative corundum. Their REE plots (Fig. 15A) have a steep pattern, with (La/Yb) N =10.41-18.83. They do not have Eu anomalies, with exception of the quartz-diorite sample (07DN6), which has Eu/Eu*= 0.78. The HREE show a flat pattern, with (Dy/Yb) N =1.11 and 1.33. The analysed samples have REE= 139-164 ppm. Trace elements have high LIL/HFS elements ratios, and their spider diagram shows a very similar pattern to that of SPB (Fig. 15B). Both dike types are characterized by having low REE content, with REE= 100-110. The rhyolitic one has a steeper LREE pattern, with (La/Yb)N up to 24.35, while the basaltic one has an "anomalous" pattern in LILE (noted in its spider diagram, Fig. 15B), probably due to alteration (s.l.) effects.

Figure 15 :

 15 Figure 15: Trace elements patterns for plutons from the southern area. REE diagrams are normalized to chondrite[START_REF] Nakamura | Determination of REE, Ba, Fe, Mg, Na and K in carbonaceous Andean[END_REF], and the spider diagrams to MORB[START_REF] Pearce | Role of sub-continental lithosphere in magma genesis at active continental margins[END_REF]. A. REE pattern for samples from Cerro Donoso pluton. B. Spider diagrams for rock samples from Cerro Donoso pluton. C. REE pattern for samples from Torres del Paine intrusive complex. D.Spider diagrams for rock samples from Torres del Paine Intrusive complex. E. REE pattern for samples from Monte Balmaceda intrusive complex. F. Spider diagrams for rock samples from Monte Balmaceda intrusive complex. 1: OIB: Ocean Island Basalts average,[START_REF] Sun | Chemical and isotopic systematics of oceanic basalts: implications for mantle composition and processes[END_REF]; 2: Pali-Aike volcanic field, Glencross area and Camusú Aike basalts[START_REF] D'orazio | The Pali Aike Volcanic Field, Patagonia: slab-window magmatism near the tip of South America[END_REF][START_REF] D'orazio | Slab window-related magmatism from southernmost South America: the Late Miocene mafic volcanics from the Estancia Glencross Area; ~52°S, Argentina-Chile[END_REF][START_REF] D'orazio | The Late Pliocene mafic lavas from the Camusú Aike volcanic field (~50°S, Argentina): Evidences for a geochemical variability in slab window Andean[END_REF]; 3:SPB: Neogene South Patagonian batholith[START_REF] Hervé | The South Patagonian batholith: 150 my of granite magmatism on a plate margin[END_REF]; 4: data from[START_REF] Michael | Intrusion of basaltic magma into a crystallizing granitic magma chamber: The Cordillera del Paine pluton in southern Chile[END_REF]; 5: data from[START_REF] Michael | Chemical differentiation of the Cordillera Paine granite (southern Chile) by in situ fractional crystallization[END_REF].

  -plate transitional" calc-alkaline plutonsThis group includes the Río de las Nieves and San Lorenzo plutons (Fig.2) in the northern area, and the Torres del Paine intrusive Complex in the southern one (Fig.3). They have calc-alkaline main characteristics, like modal hornblende and/or biotite, also a slight Nb-Ta negative anomaly (Figs. 12F, 14B and 15F), but their trace element patterns are similar to those of the alkaline group (Figs.

Figure 16 :

 16 Figure 16: Ba/Ta vs La/Ta diagram, after Kay and Mpodozis (2002) for plutons from the northern and southern areas. Calc-alkaline arc signature is represented by the North and South Patagonian batholith samples (NPB, SPB), most of them with La/Ta >25 and Ba/La >20 (NPB and SPB data from Pankhurst et al. (1999) and Hervé et al. (2007), respectively). The plateau lavas, and OIBsignatures, are well constrained, mostly with La/Ta between 10 and 20. In general terms, the plutonic samples from this study show two intermediate patterns, both with Ba/La <20 (lower than calc-alkaline arc-like) but with La/Ta either close to the arc, or to the intra-plate signatures.

  model, we propose a melting, assimilation, storage and homogenization (MASH) zone in the mantle-crust transition, an open system, compatible with the alkali variations found in this work, and in accordance to evolving tectono-magmatic scenarios. In which alkalinity and incompatible elements (HFSE) content increase in Cerro Negro/Zeballos magmas with enriched sub-continental lithospheric mantle (SCLM) components.

Figure 17 :

 17 Figure 17: Sr/Nd vs Nb/La diagram for plutons from the northern and southern areas. The Nb/La ratio reflects the Nb-Ta anomaly, while the Sr/Nd ratio the primitive magma evolution with

  (a): the Pliocene alkaline rocks; (b): the Pliocene and Miocene "intra-plate transitional" calcalkaline plutons; (c): the Miocene "arc transitional" calc-alkaline plutons. B.: Southern area, (d): the alkaline gabbros; (e): alkaline leucogranites; (f): the Miocene "intra-plate transitional" calcalkaline mafic rocks; (g): calc-alkaline granites; (h): the "arc transitional" calc-alkaline pluton.

  . The proposed petro-genetic model for the suite is supported by the strong intra-plate signatures of both facies and it requires three evolutionary stages to accommodate all compositional features: (1) Anhydrous melts with alkaline signature, OIB-like trace elements pattern, and high Ndt produced in fertile mantle, probably the SCLM, and stored in the lower crust. (2) Melts produced from (1) stayed in deep crustal levels, where strong in-situ crystal fractionation, and/or crustal assimilation produced the highly acidic felsic magmas. As they have primitive isotopic ratios (Nd t >+4), crystal fractionation is preferred as the main process. (3) The injection of new fresh basaltic magmas into the former accumulated magmas may have triggered the upwelling by batches of both, the stored basic magmas and the felsic derived magmas, to get emplaced in shallow levels of the upper crust (<5 Km of the surface). In stage (3) the new magmas with Ndt ca.+2 should evolve due to 2 possible processes:

  2 for location), where Boutonnet et al. (2010) infer an extensional setting prior to the Chile Rise collision coeval with the start of the Meseta del Lago Buenos Aires (ca. 47ºS, Fig.2 for location) construction, at 12 Ma.

  Some of the geochemical characteristics of the Torres del Paine intrusive complex are shared with the Monte Balmaceda intrusive complex, including the Andean Geology 48 (3): xxx-xxx. September, 2021 doi: the OIB-like signatures for the mafic complexes (e.g. HFSE content, Zr/Nb <10). Nevertheless, subtle arc-like geochemical features are also present, including a Ti content similar to values of the SPB, La/Ta ratio >20

  new and previous geochemical and isotopic data, we discuss an attempt to explain how the MASH zone at the base of the crust may have been generated in the extra-Andean location according to the characteristics of each pluton, most of them with "transitional" geochemical character.First, most of the studied plutonic rocks in this work have subtle to strong subduction signatures (e.g.

Figure 18 :

 18 Figure 18: Sketch of reconstructed Chile Rise Segments (CRS) spreading center locations from Miocene (ca. 16 Ma) to Pliocene (ca. 3 Ma). The spreading centers beneath the South American

  Arc migration itself should control the characteristic of magmatism. Two hypotheses have been proposed to explain arc-plutonism migration,[START_REF] Sánchez | Relations between plutonism in the back-arc region in southern Patagonia and Chile Rise subduction: A geochronological review[END_REF] argued for a migration of the arc in mid-Miocene times because the magmatic arc ceases its plutonism just before the Chile Rise segments collided with the trench (at ca. 16 Ma) and in this moment the Miocene foreland plutonism started. These authors proposed a slab flattening as a possible mechanism for this arc migration, similar to[START_REF] Gorring | Neogene Patagonian plateau lavas; continental magmas associated with ridge collision at the Chile triple junction[END_REF], and Kay et al. (2006) for the Miocene magmatism in the Neuquen Region, Argentina, at 36ºS. Later, Espinoza et al. (2010) also put forward arc migration for the Cerro Plomo/Zeballos lavas (Northern Area). Alternatively, Ramírez de Arellano et al. (2012a) proposed the arc migration mechanism to explain the calc-alkaline (sensu stricto) character of the Chalten (Fitz-Roy) plutonic complex, located between the Northern and

Figure 19 :

 19 Figure 19: Schematic W-E section at ca. 51ºS, illustrating a possible flat slab subduction scenario prior to the Chile Rise collision at ca. 18-16 Ma, for the alkaline magma generation of the Monte Balmaceda intrusive complex. Thrusting in the foreland region, pre-and post-dating the 18 Ma, is

Figure 20 :

 20 Figure 20: Schematic W-E section at ~47º30'S., showing a possible subduction setting at ca. 6

  The new data presented allow us to conclude:1. The geochemistry of the plutons in the "extra-Andean" region shows a wide range in alkalinity. The only sensu stricto alkaline pluton is the Monte Balmaceda intrusive complex, reflecting intra-plate signatures. The rest of the studied plutons have subduction derived components and "transitional" geochemical features between intra-plate and magmatic arc signatures.2. The "arc transitional" calc-alkaline plutons are the Paso de Las Llaves and Cerro Negro del Ghío plutons in the northern area, and the Cerro Donoso pluton in the southern area. While the "intra-plate transitional" calc-alkaline plutons are the San Lorenzo and Río de las Nieves plutons in the northern area, and the Torres del Paine intrusive complex in the southern area. 3. The intra-plate signatures are interpreted as reflecting lower continental crust and/or sub-continental lithospheric mantle melts contributing in different proportion to the magmas, according to the geochemical features of each pluton. 4. The common geochemical characteristics in the studied extra-Andean plutons are:

  shape is laccolithic, and the field relations are similar to those of Torres del Paine Intrusive Complex. Even though not all the outcrops could be examined, two main igneous facies for the intrusive complex have been recognized: a yellow alkali feldspar leucogranite (BLG), and a mafic facies, including massive gabbro and granodiorite with monzonite patches in mafic enclave areas, here called Balmaceda Mafic Complex (BMC) because of their complex intrusive relations 9A-E).

	Andean Geology 48 (3): xxx-xxx. September, 2021 Andean Geology 48 (3): xxx-xxx. September, 2021
	doi: 10.5027/andgeoV48n3-3158 doi: 10.5027/andgeoV48n3-3158
	P R E S S P R E S S
	I N I N
	27 28

  content of 59.3 wt.%. The granite samples have A/NK between 1 and 1.3 (lowest values in the plutons sampled in the Northern Area).

	Andean Geology 48 (3): xxx-xxx. September, 2021
	doi: 10.5027/andgeoV48n3-3158
	P R E S S
	I N
	39

Table 5 ;

 5 Figs 14C and 13A, B).

	Andean Geology 48 (3): xxx-xxx. September, 2021
	doi: 10.5027/andgeoV48n3-3158

2 Alkaline plutons in the Meseta del Lago Buenos Aires

	5.2.The Mifeldi pluton samples have intermediate SiO2 contents between Pico
	Rojo (around 60 wt.%) and Cerro Lápiz (above 65 wt.% in SiO 2 ) (Espinoza et al.,
	2008; this work) and they are all alkaline (Figs. 10B and 11A, B). One sample
	from Cerro Lápiz has normative corundum.
	P R E S S
	I N
	42

Andean Geology

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The alkaline granite from Cerro Lápiz neck has the most radiogenic values, with Nd t <0 and (Sr/Sr) i >0.7055, while the other alkaline plutons have isotopic ratios around the bulk Earth intersection

  Table 4). Finally, there is no anomalous

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  Sr, Ba, Ti and P and neither of the facies follows arc (SPB), nor back-arc rock patterns.

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Graded calc-alkaline to alkaline "transitional" character of the plutons

  except from the northern slope outcrop, where they show a subtle negative anomaly (07BA6,8). Otherwise, the very low Sr content (< 40 ppm) for BLG is consistent with their low CaO content (< 0.19 wt.%) and with their pronounced negative Eu anomaly, and, in turn, these features are in accordance with the scarce plagioclase content in these facies, excluding an important weathering and/or hydrothermal alteration effect in their trace element measurement.The Nd t values for the Balmaceda Mafic Complex samples (+5 to +5.1) are higher than those of the felsic ones (+2.1 to +4.6), and have a ( 87 Sr/ 86 Sr)i isotopic ratio < 0.7040 (Fig.13C,D). The very low Sr concentration (ca. 7-38 ppm, Table4) in the Balmaceda Leucogranites samples implies that they would be susceptible to contamination during analytical procedures, which would result into anomalous high ( 87 Sr/ 86 Sr)i ratios (Table6). Therefore, Sr isotopic ratio of the Balmaceda Leucogranites is not considered further in this study.

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	6. Discussion
	6.1
	P R E S S P R E S S
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	48 49

Table 5

 5

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), together with subtle lower content in alkali and incompatible elements (La/Ta ratio) (Figs. 10A, 16), closer to observed in the diorites and tonalities, is interpreted as indicative of pyroxene and plagioclase fractionation in the diorite to generate the felsic magmas. Elsewhere, the tonalites and Granito Avilés have negative correlations of Al 2 O 3 , CaO, FeOtot, MgO,TiO 2 with increasing SiO 2 content. In addition, Granito Avilés has lower content of Sr, P, Ti and larger negative Eu anomaly. All this data is interpreted as plagiocase, apatite and mafic phases (probably pyroxenes + hornblende) early fractionation in the diorite and tonalite before granite crystallization. This interpretation is consistent with the petrographic evidences (Section 4.1).

Table 4 )

 4 , suggests

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contribution from slab-derived components and/or crustal contamination (eg.

  Del Salto pluton. As a genetic model for the Del Salto pluton,Welkner et al.

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Table 1 : Selected feldspar microanalyses from Paso de Las Llaves and Cerro Negro del Ghío plutons

 1

	Unit	Paso de Las Llaves tonalite				de Las Llaves diorite			Cerro Negro del Ghío diorite
	Sample
	Label	I2	I3	D1	D4	C3	G-4	G-5	D2	D1	D3	A1	A2	K3	A1	A3	I5	I1	I-L1-1	I-L1-17
	cristal loc	rim	core	core	rim	core	core	rim	core	interm	rim	core	interm	mass	core	rim	core	rim	rim	core
	SiO2 wt.%	54,39 47,39	54,98 62,46	49	49,12	57,52	51,79 44,44	54,1	44,38	45,04	67,31	52,04 61,82	53,71 61,31	58,47	56,24
	TiO2	0	0	0,12	0,04	0,12	0,12	0	0	0	0	0	0	0	0	0	0	0	0	0
	Al2O3	28,4 33,01	28,08 22,83	31,76	31,45	26,07	29,06 33,65 27,58	34,07	33,96	21,16	29,67 23,5	28,48 23,75	25,63	26,55
	Fe2O3	0,36	0,56	0,35	0,36	0,44	0,53	0,33	0,32	0,37	0,36	0,34	0,3	0	0,47	0,17	0,38	0,12	0,23	0,38
	MgO	0	0	0	0	0	0	0	0	0	0	0	0	0	0	0	0	0	0	0
	CaO	11,11 16,84	10,73 4,98	15,2	14,87	8,55	12,18	18	10,5	18,6	18,06	1,75	13,02	5,3	11,49 5,65	8,03	9,55
	SrO

Table 2 : Selected feldspar microanalyses from Donoso granite (07DN7) and Balmaceda Leucogranites (07BA4, 07BA7a).

 2

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	Unit	Cerro Donoso Pluton granite					Monte Balmaceda leucogranites
	Sample				07DN7						07BA4					07BA7a
		C1-L1_1 C1-L1_13	C10-L1_1 C10-L1_11	C4-2	C4-3	C9-8	C2-3	C2-4	C2-7	C2-8	C4-14	C2-4	C2-3	C2-6	C2-7	C2-8
	cristal loc	core	rim	rim	core	rim	core	core	core	exol.	rim/int	core	core	Or	Ab		pert.
	SiO2 wt.%	47,42	58,18	65,3	50,92	61,26	56,35	64,15	66,52	65,17	66,23	65,25	64,52	64,2	65,98	66,76	65,25	62,45
	TiO2	0,13	0,04	0	0,01	0,02	0	0	0	0,05	0,21	0	0,15	0	0	0	0,09	0
	Al2O3	34,12	26,76	22,01	31,25	24,27	27,12	19,32	18,81	22,29	20,65	18,94	18,11	18,12 21,06	19,23	18,8	19,34
	Fe2O3 MgO CaO SrO BaO Na2O K2O Rb2O Total Si Ti Al/Al IV Al VI Fe3+ Mg Ca Sr Ba Na K Rb Cation sum Ab An Or	0,28 0 17,37 -0 1,69 0,03 -101,05 2,156 0,005 1,829 0 0,01 0 0,846 -0 0,149 0,002 -4,996 14,97 84,849 0,181	0,18 0 8,83 -0 6,26 0,61 -100,88 2,588 0,001 1,403 0 0,006 0 0,421 -0 0,54 0,035 -4,994 54,229 42,268 3,503	0,09 0 3,67 -0 9,98 0,28 -101,34 2,848 0 1,131 0 0,003 0 0,172 -0 0,844 0,016 -5,014 81,85 16,644 1,506	0,29 0 14,09 -0,01 3,59 0,05 -100,21 2,314 0 1,674 0 0,01 0 0,686 -0 0,317 0,003 -5,004 31,484 68,215 0,278	0,04 0 5,91 -0 8,54 0,32 -100,36 99,12 0,15 0 9,3 -0 5,93 0,27 -2,718 2,551 0,001 0 1,269 1,447 0 0 0,001 0,005 0 0 0,281 0,451 --0 0 0,735 0,521 0,018 0,016 --5,023 4,991 71,093 52,742 27,18 45,683 1,727 1,575 P R 0,14 0,13 0 0 0,02 0,33 --0,22 0,07 0,61 5,63 15,21 8,64 --99,65 100,13 100,34 0,14 0 0,81 -0 9,47 2,4 -2,966 2,993 2,872 0 0 0,002 1,053 0,997 1,157 0 0 0 0,005 0,004 0,005 0 0 0 0,001 0,016 0,038 ---0,004 0,001 0 0,054 0,492 0,809 0,897 0,496 0,135 ---4,98 5 5,018 5,682 48,937 82,412 0,096 1,579 3,877 93,812 49,368 13,71 E S S 0,06 0,11 0 0,01 0 0 0 0 1,87 0,02 0 0 ----0 0 0 0,01 10,79 3,17 0,67 0,26 0,33 12,01 15,88 16,61 ----100,13 99,52 99,34 99,21 100,7 0,06 0 2,27 -0 11,08 0,27 -2,911 2,985 3 2,999 2,891 0,007 0 0,005 0 0 1,069 1,021 0,993 0,997 1,087 0 0 0 0 0 0,002 0,004 0 0 0,002 0 0 0 0 0 0,088 0,001 0 0 0,106 -----0 0 0 0 0 0,919 0,282 0,06 0,023 0,941 0,018 0,701 0,942 0,989 0,015 -----5,015 4,994 5 5,009 5,043 89,656 28,621 6,005 2,29 88,56 8,567 0,112 0 0 10,02 1,777 71,267 93,995 97,683 1,425	0,11 0 0,09 -0,04 7,39 6,5 -100,13 100,06 98,21 0,33 0,09 0 0 0,26 0,07 --0,04 0 3,29 0,35 11,99 15,91 --2,983 2,976 2,943 0 0,003 0 1,013 1,011 1,074 0 0 0 0,004 0,011 0,003 0 0 0 0,005 0,013 0,004 ---0,001 0,001 0 0,64 0,291 0,032 0,37 0,697 0,956 ---5,015 5,004 5,013 63,03 29,062 3,261 0,447 1,261 0,356 36,453 69,605 96,383
	Cation per formula unit based on 8O
				I N
																		90

Table 3 . Chemical composition of pluton samples from the northern area.

 3

Table 4 . Chemical composition of pluton samples from the southern area.

 4

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	sample	07DN4	07DN5	07DN7	07DN9	07DN6	07DN11	07DN2	07BA3	07BA4	07BA6	07BA8	07BA22	07BA25	07BA26	07BA27	TP6		TP7B	TP8	TP9	TP11	TP12	TP14	TP16
	Lat. ºS	51,22947 51,22845 51,22845 51,22774 51,22891 51,22549 51,23376	51,34905 51,34905 51,35416 51,34621 51,41699 51,41142 51,41216 51,41202	50,98109	50,97724	50,97724	50,97731	50,97812 50,97536 50,96836 50,97339	50,97631
	Lon. ºW	73,15697 73,15940 73,15940 73,15582 73,16056 73,13990 73,13631	73,15281 73,15281 73,14961 73,14462 73,10865 73,11229 73,10945 73,11046	73,04750	73,04965	73,04965	73,05135	73,05274 73,04750 73,04015 73,03371	73,03822
	Unit	CDP a	CDP	CDP	CDP	CDP	dyke	dyke	BMC b	BMC	BLG c	BLG	dyke	BMC	BLG	BLG	PMC d	PG e	PMC	PG	PMC	PG	PG	PG	PG
	rock type	granite	granite	granite	granite	qtz diorite	rhyol.	basalt	diorite	diorite	Leucogte Leucogte pink dke.	gabbro	granite	granite	diorite	felsic intrusion	mafic enclave	granite	diorite	granite	granite	granite	miarolitic gte.
	Major elements (wt.%)
	SiO 2	57,3	66,1	65,7	62,4	55,87	69,5	45,7	52	53,4	74,9	78,43	75,69	48,7	75,3	75
	TiO 2	0,77	0,4	0,44	0,53	0,71	0,15	2,63	2,27	1,85	0,21	0,16	0,2	3,1	0,18	0,16
	Al 2 O 3	18,3	17	16,9	17	16	15,9	17,8	16,7	17	13,2	12	11,7	15,5	12	12,5
	Fe 2 O 3	1,15	0,79	0,76	2,12	1,58	1	2,19	1,89	2	1,32	0,34	0,85	2,24	1,52	1,04
	FeO	5,12	2,2	2,6	2,8	5,84	1,4	8,4	7,08	6,12	0,12	0,08	1,76	8,76	0,6	1
	MnO	0,13	0,06	0,06	0,09	0,22	0,09	0,15	0,14	0,13	0,03	0,01	0,05	0,15	0,03	0,03
	MgO	3,14	1,53	1,69	2,19	5,67	0,31	5,14	2,8	2	0,06	0,05	0,05	3,48	0,04	0,06
	CaO	6,04	3,23	3,43	4,94	6,84	1,57	10,14	4,59	4,16	0,16	0,19	0,11	8,62	0,12	0,17
	Na 2 O	3,49	3,51	3,4	3,47	2,79	3,57	2,66	4,85	5,15	3,64	3,35	3,4	4,26	4,13	4,55
	K 2 O	2,51	3,3	3,27	2,55	2,02	3,18	0,1	3,14	3,99	5,3	4,56	4,45	1,88	4,68	4,94
	P 2 O 5	0,4	0,2	0,22	0,32	0,41	0,11	0,48	0,79	0,71	0,05	0,03	0,02	0,52	0,03	0,03
	LOI	1,33	1,5	1,33	1,25	1,92	2,76	4,33	3,67	3,16	0,85	0,46	1,41	2,35	0,88	0,4
	Total	99,68	99,82	99,8	99,66	99,87	99,54	99,72	99,92	99,67	99,84	99,66	99,69	99,56	99,51	99,88
	Trace elements (ppm) Sc 41 Ti V 125 Cr 36 Co 15,1 Ni 31 Cu 19,8 Zn 73 Ga 38,4 Ge 7,1 As 2,35 Se 1,9 Rb 92 Sr 669 Y 19,6 Zr 150 Nb 9,2 Mo 1,015 Rh 0,031 Ag 0,59 Cd l.d Sn 2,2 Sb 0,82 Cs 3,88 Ba 562 La 33,2 Ce 59 Pr 7	40 126,4 34,7 15,1 16,5 6,2 73,6 37,5 6,71 2 l.d 90,6 658 19,3 153 8,69 0,553 0,015 0,7 0,061 1,32 0,459 3,9 562 33,1 57,7 6,8	34 62,9 24,9 5,9 9,8 41,3 36,4 37,9 6,8 2,1 1,5 154 689 11,47 137 8 1,33 0,013 0,718 l.d. 1,25 0,45 5,3 638 36,6 59,7 6,36	33,9 74 25,2 9 22 9,5 51 38,6 7,6 4 0 88,8 793 15,12 147 7,8 2,2 0,022 0,52 l.d 1,6 1,01 2,99 640 40,1 69,3 7,7	24,3 172 215 23,7 71,4 63 115 19,7 2 3,7 122,8 636 28 124 9,72 9,9 l.d 0,5 0,13 4,7 0,37 8,1 461 45,5 67,9 8,9	32 13,5 2,46 3,9 15,7 12,7 65,3 38,9 6 1,5 2,4 119,8 231 8,13 82 14,1 3,3 0,02 0,58 0,05 3,13 1,7 3,35 687 28,4 46,6 5,23	43 205 177 42 57 37 104,3 20,1 4,2 3,8 1,4 0,89 635 18,6 97 19,2 2 0,018 0,58 0,06 1,46 0,44 0,63 89,6 20,2 33,2 4,4	34,2 102 8,8 32 15,8 2,84 132 23,6 9,8 47 4 191,3 493 35,6 333 53,1 1,6 0,023 0,77 0,22 35,422 3,97 23,49 254 49,4 90,5 10,8	33 58,25 7,87 24,606 14,005 4,763 113 24,8 10,1 39 3,1 179 445 40,1 365 55,4 4,2 0,012 0,84 0,4 26 3,92 10,8 411 51,2 95 11,479	25 12,6 2,2 1,045 4,6 2,064 35 19,4 7 3,3 1,2 222 37,9 35,14 116 17,1 4,5 0,009 0,47 l.d 6,7 1,35 11,948 88,2 35,7 67,4 6,45	2,8 5 3,4 0,98 2,39 59,4 26,8 25,5 1,63 2,55 404 22 46,7 192 24,8 1,98 l.d 0,52 0,13 4,15 0,41 5,8 40,2 45,7 64 6,3	3,6 2,9 3,82 47 6,7 9,7 147 38,3 1,5 1,8 141,7 8 44,3 462 65,9 2,56 0,02 0,93 0,32 8,3 0,8 0,833 22,8 62,8 98 10,8 P R 42 26 25 220 13,1 10,567 20,4 14,53 1,753 27,4 43,1 6,762 17,4 4,5 6,692 31,5 1,6 8,069 139 107 89 30,4 31,1 30,475 4,7 12,1 10,513 7 1,45 7,06 2,2 3,2 l.d 41,5 130 131 528 9,1 7,28 25,3 47,4 41,7 206 368 354 41,6 67,6 54,3 2,7 1,7 2,7 0,023 0,0086 0,023 0,736 0,9 0,702 0,25 0,18 0,24 4,8 9,165 7,24 0,49 0,68 0,551 2,49 1,22 1,91 206,4 18,3 18,95 33,3 69,7 56,2 55,8 122 98,6 7,14 13,5 10,78 E S S 71 66 63 7378 1732 11886 106 33,1 189 14,2 4,5 112 14,0 2 35,7 23,5 14,1 115 168 67 246 149 74 222 22,3 18,7 22,6 1,4 1,17 1,6 96 122 195 570 207 741 25,6 10,8 25,5 262 175 212 32,2 19,6 36,6 l.d. l.d. l.d. 24,0 2,6 6,0 0,95 0,86 1,12 4,8 2,87 12,6 656 462 764 44 35,1 53 80 55 88 9,2 5,5 9,7	72 1972 34,7 4,2 5,3 13,9 30,6 96 21,9 1,6 171 307 21,8 208 22,2 l.d. 2,14 1,24 4,1 632 65 94 9,6	70 6017 142 11,7 20,4 18,0 59 150 21,5 1,6 124 814 23,6 200 15,4 l.d. 9,6 1,95 5,3 534 40,8 78 9,2	58 1565 28,8 3,3 2,8 15,9 108 86 19,0 1,45 173 273 25,2 179 22,2 l.d. 14,8 1,06 3,17 549 46,6 80 8,4	66 2360 41 6,3 9,3 13,3 43 116 21,6 1,51 155 312 22,1 212 25,9 0,21 3,7 0,60 5,9 562 50 79 7,9	64 1772 36,6 6,6 3,19 12,6 41,6 128 19,5 1,5 170 240 19,3 188 23,4 0,24 3,1 1,32 8,6 441 41,1 66 6,6	68 397 21,2 3,6 0,64 16,1 41 60 17,4 1,53 202 17,3 28,7 92 23,3 l.d. 3,0 1,14 6,0 23,2 36,5 53 5,5
	Nd	26,8	27	22	28,5	35,5	17,9	20,1	41,8	45,4	21,2	19,4	38,9	30,54	47,8	38	36	19,4	37,4	34,0	35,7	30,2	26,9	22,1	19,8
	Sm Eu Gd Tb Dy Ho Er Tm Yb	5,42 1,45 5,1 0,66 3,71 0,74 2,285 0,28 2,05	5,246 1,55 5 0,68 3,7 0,74 2,2 0,294 2	3,8 1,06 3,37 0,41 2,24 0,41 1,24 0,17 1,3	4,98 1,41 4,2 0,57 3 0,61 1,69 0,23 1,45	7,3 1,8 6,9 0,95 5,6 1,04 3,17 0,45 2,9	3,2 0,95 2,8 0,32 1,57 0,28 0,93 0,107 0,78	4,9 1,91 5,4 0,73 4,3 0,73 2 0,25 1,5	9,4 2,4 9,2 1,239 7,5 1,37 3,84 0,5 3,4	9,75 2,783 10 1,39 8,1 1,57 4,19 0,61 3,83	4,7 0,324 5,2 0,92 6,2 1,29 4 0,58 3,7 I N 4,1 8,4 0,14 0,48 5,1 9,5 1 1,43 7,7 8,6 1,64 1,73 5,6 4,9 0,85 0,64 5,9 4,5	7,1 2,19 7,5 1,05 5,7 1,03 2,7 0,32 2,1	10,1 0,49 10,4 1,6 9,5 1,76 5,185 0,72 4,4	8,2 0,42 8,6 1,39 8,6 1,63 4,7 0,63 3,9	7,3 1,63 5,5 0,85 5,1 1,02 2,8 0,40 2,5	3,5 0,77 2,51 0,36 1,90 0,37 1,04 0,148 1,02	7,2 1,79 5,4 0,81 4,6 0,90 2,5 0,35 2,17	5,8 1,02 3,7 0,60 3,6 0,73 2,06 0,31 2,06	6,6 1,56 4,4 0,70 4,1 0,84 2,3 0,33 2,2	5,6 0,86 4,1 0,66 4,0 0,83 2,4 0,37 2,4	5,0 0,84 3,6 0,59 3,6 0,75 2,21 0,31 2,1	4,1 0,70 2,9 0,48 3,09 0,65 1,9 0,28 1,97	4,4 0,13 3,7 0,69 4,5 0,94 2,9 0,45 2,9
	Lu	0,29	0,33	0,21	0,25	0,47	0,13	0,22	0,46	0,53	0,52	0,77	0,63	0,3	0,58	0,53	0,37	0,16	0,31	0,31	0,32	0,37	0,32	0,33	0,43
	Hf	4,17	4,16	3,69	4,1	3,7	2,8	2,71	8,2	8,3	4,18	6,9	12,5	5,3	10,7	9,9	6,7	4,5	4,8	5,6	5,2	5,0	5,6	5,05	3,5
	Ta	0,97	0,99	1,03	0,96	0,7	1,54	1,72	4,45	4,7	2,75	3,65	4,65	3	5,36	4,52	2,00	0,99	1,92	1,85	1,02	2,16	2,01	1,79	2,77
	W	5,13	6	0,8	0,25	1,38	15,6	47,6	87	47,1	5,56	11,7	270	1,1	291	40,06
	Tl	0,52	0,6	1,16	0,54	0,58	0,93	0,0061	1,64	1,52	0,96	0,84	0,31	0,35	0,7	0,51	0,40	0,48	0,82	0,61	0,54	0,59	0,59	0,72	0,79
	Pb	10,4	10,7	9,9	11,08	6,1	20,8	2,41	51,1	26,5	15,2	8,9	10,9	5,74	6,5	9,9	12,0	14,9	6,4	16,8	8,8	13,5	17,4	16,6	19,2
	Bi	0,15	5,2	5,2	4,2	1,8	0,377	7,3	3,6	4	4,6	2,46	0,22	3,3	5	0,29	0,23	l.d	4,9	2,55	0,17	8,2	8,4	0,13	0
	Th	8,77	8,9	13,5	12,4	7,35	11,2	1,7	13,3	12,17	36,1	44	12,95	3,76	18	14,7	12,1	20,1	7,5	27,8	12,4	20,9	20,7	21,5	30,1
	U	1,26	1,29	3,7	1,45	1,9	3,93	0,49	3,6	3,36	8,5	9,6	3,65	1,37	4,1	4,4	3,2	2,53	2,31	3,9	2,52	3,3	2,7	1,79	5,3
	a: CDP= Cerro Donoso pluton
	b: BMC= Monte Balmaceda Mafic Complex
	c: BLG= Monte Balmaceda Leucogranites
	d: PMC= Torres del Paine Mafic Complex
	e: PG= Torres del Paine granites
	l.d: Under detection limit
																Page 1
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Table 5 . Whole rock Sr and Nd isotopic data of pluton samples from the northern area. Sample Unit Age (Ma) Sm (ppm) Nd (ppm) 147 Sm/ 144 Nd Nd/ 144 Nd ( 143 Nd/ 144 Nd) t eps(Nd) Rb (ppm) Sr (ppm) 87 Rb/ 86 Sr 87 Sr/ 86 Sr ( 87 Sr/ 86 Sr) t

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	07LL2	TLLP a	9	5,6	25,8	0,1312	0,512688	0,512680	1,1		59,9	828	0,2092	0,704778	0,704751
	07LL3	Gt-granite b	9	5,9	30,8	0,1158	0,512362	0,512354	-5,3		169	69,4	7,0548	0,721085	0,720083
	07LL5	dike	9	3,5	14,5	0,1459	0,512633	0,512623	0	117,8	202	1,6869	0,705277	0,705037
	07LL6 07LL10 07LL11 07LL25 07LL18 07LL19 07LL20 07SM6 07SM13 CH4131 COY0231 COY0234 COY0235 a: TLLP= Tonalite in Paso de Las Llaves area dike 9 TLLP 9 diorite Las Llaves 9 TLLP 9 GA c 8 GA 8 diorite Avilés 8 CNGP d 15 CNGP 15 RLNP e 3 SLP f 6 SLP g 6 SLP 6 b: Porphyritic garnet bearing granite c: GA= Avilés Granite d: CNGP= Cerro Negro del Ghío pluton e: RLNP= Río de las Nieves pluton f: SLP= San Lorenzo pluton (granites)	6,7 5,7 6,42 6,9 6 5,4 4,3 6,6 6,1 6,6 4,3 6,8 4,15	34 25,7 32,3 32,3 31,4 27,2 16,4 34 32,4 37,4 19,53 33,8 23,8	0,1191 0,1341 0,1202 0,1292 0,1155 0,1200 0,1585 0,1174 0,1138 0,1067 0,1331 0,1216 0,1054 P R 0,512722 0,512703 0,512702 0,512752 0,512669 0,512708 0,512730 0,512779 0,512754 0,512701 0,512561 0,512651 0,512609 E S S 0,512715 1,7 0,512695 1,3 0,512695 1,3 0,512744 2,3 0,512663 0,7 0,512701 1,4 0,512721 1,8 0,512768 2,9 0,512743 2,4 0,512699 1,3 0,512555 -1,4 0,512646 0,3 0,512605 -0,5	28,1 38,2 63 55 123 177 44,1 105 71 127 199 77 154	1057 808 820 787 579 488 601 1210 949 434 53 509 100	0,0769 0,1367 0,2222 0,2021 0,6144 1,0491 0,2122 0,2510 0,2164 0,8464 10,8617 0,4376 4,4546	0,704596 0,704629 0,704512 0,704527 0,704637 0,704648 0,704322 0,703851 0,704152 0,704662 0,706159 0,705089 0,705490	0,704586 0,704611 0,704483 0,704501 0,704564 0,704523 0,704297 0,703798 0,704107 0,704624 0,705166 0,705049 0,705083
	g: SLP= San Lorenzo pluton (andesite)		I N
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Table 6 . Whole rock Sr and Nd isotopic data of pluton samples from the southern area.

 6

	Sample	Unit	Age (Ma)	Sm (ppm)	Nd (ppm) 147Sm/144Nd 143Nd/144Nd (143Nd/144Nd)t	eps(Nd)	Rb (ppm)	Sr (ppm)	87Rb/86Sr	87Sr/86Sr	(87Sr/86Sr)t
	07BA25	a	15	7,1	30,54	0,1406	0,512892	0,512878	5,1	41,5	528	0,2273	0,703304	0,703254
	07BA3	BMC	15	9,4	41,8	0,1360	0,512886	0,512872	5,0	191,3	493	1,1222	0,703511	0,703265
	07BA4	BMC	15	9,75	45,4	0,1298	0,512891	0,512878	5,1	179	445	1,1633	0,703574	0,703319
	07BA6	BLG b	15	4,7	21,2	0,1340	0,512737	0,512723	2,1	222	37,9	16,9499	0,709278	0,705557
	07BA8	BLG	15	4,1	19,4	0,1278	0,512765	0,512752	2,6	404	22	53,1989	0,720833	0,709153
	07BA22	BLG	15	8,4	38,9	0,1306	0,512854	0,512841	4,3	141,7	8	51,3382	0,725927	0,714655
	07BA26	BLG	15	10,1	47,8	0,1278	0,512866	0,512853	4,6	130	9,1	41,3782	0,719066	0,709981
	07BA27	BLG	15	8,2	38	0,1305	0,512854	0,512841	4,3	131	7,28	52,1313	0,721179	0,709733
	07DN2	basaltic dike	27	4,9	20,1	0,1474	0,512929	0,512903	5,8	0,89	635	0,0041	0,704406	0,704404
	07DN4	CDP c	27	5,42	26,8	0,1223	0,512606	0,512584	-0,4	92	669	0,3978	0,705092	0,704938
	07DN5	CDP	27	5,246	27	0,1175	0,512638	0,512617	0,3	90,6	658	0,3983	0,704868	0,704713
	07DN6	CDP	27	7,3	35,5	0,1243	0,512636	0,512614	0,2	122,8	636	0,5585	0,704901	0,704684
	07DN7	CDP	27	3,8	22	0,1044	0,512633	0,512614	0,2	154	689	0,6465	0,704857	0,704606
	07DN9	CDP	27	4,98	28,5	0,1056	0,512629	0,512610	0,1	88,8	793	0,3239	0,704910	0,704784
	07DN11	rhyolitic dike	27	3,2	17,9	0,1081	0,512557	0,512538	-1,3	119,8	231	1,5002	0,705739	0,705157
	TP6	PMC d	13	7,3	36,0	0,1230	0,512680	0,512670	0,9	96,1	570,5	0,4871	0,704480	0,704393
	TP7A	PG e	13	3,5	19,4					121,6	206,9
	TP7B	PMC	13	7,2	37,4	0,1159	0,512767	0,512757	2,6	195,2	741,3	0,7618	0,704488	0,704352
	TP8	PG	13	5,8	34,0	0,1038	0,512581	0,512572	-1,0	171,2	306,9	1,6136	0,704893	0,704604
	TP9	PMC	13	6,6	35,7	0,1122	0,512706	0,512697	1,5	124,5	814,2	0,4421	0,704019	0,703940
	TP11	PG	13	5,6	30,2	0,1129	0,512576	0,512567	-1,1	172,7	273,3	1,8281	0,704933	0,704606
	TP12	PG	13	5,0	26,9	0,1113	0,512616	0,512607	-0,3	155,0	312,3	1,4355	0,705025	0,704768
	TP13	PG	13	-	-	0,0000	0,512606			-	-		0,707890
	TP14	PG	13	4,1	22,1	0,1113	0,512623	0,512614	-0,2	169,8	240	2,0463	0,705179	0,704813
	TP16	PG	13	4,4	19,8	0,1342	0,512594	0,512583	-0,8	202,2	17,3	33,8965	0,710579	0,704514
	italics represent anomalous values

Acknowledgements

This work was possible thanks to "Becas de Doctorado" Conicyt (A.Sánchez), and to ECOS/Conicyt C05U02 grant. Field assistance of M.Gerbault (IRD), N.Croissant (U.Chile), B.Scalabrino (U.Montpellier) is very appreciated. FONDECYT projects 1010413 and 1095099 financed the geochemical analyses conducted at U. de Chile. We also thank Conaf staff for field support and permission to study in protected areas. Estancia Sol de Mayo owner allowed us to work in his property.

Río Arriba and 21 de Mayo enterprises also cooperated for a successful field work in these inhospitable regions. Constructive reviews by Andrés Echaurren, Cristobal Ramirez de Arellano and AG editor contributed to the improvement of this manuscript. Last but not least, we appreciate "El ermitaño" for his guidance in the difficult ways of Monte Balmaceda.