Paul Frossard
email: paul.frossard@uca.fr

Zhiguo Guo

Mary Spencer

Maud Boyet

Audrey Bouvier

Evidence from achondrites for a temporal change in Nd nucleosynthetic anomalies within the first 1.5 million years of the inner solar system formation

Keywords: Nd nucleosynthetic anomalies, achondrites, planetesimals, chondrule formation, thermal processing

Heterogeneity in isotopic compositions within the protoplanetary disc has been demonstrated for a number of elements measured in extra-terrestrial materials, mostly based on chondrite meteorite analyses. However, precise 182 Hf-182 W and 26 Al-26 Mg ages of iron meteorites, achondrites, and chondrules show that chondrites accreted later than achondrites and therefore do not strictly represent the early (< 2 Ma) solar system composition. Here we present the Nd mass-independent stable isotopic compositions of a suite of diverse achondrites to better constrain the Nd isotope evolution of the early solar system. Carbonaceous (C) achondrites are indistinguishable from their chondritic counterpart. However, early formed planetesimals as sampled by silicate-rich non-carbonaceous (NC) achondrite meteorites have higher 145 Nd/ 144 Nd and 148 Nd/ 144 Nd ratios (3.9 < µ 145 Nd < 11.0 and 9.1 < µ 148 Nd < 17.9 in part per million deviation, or µ i Nd) compared to NC chondrites (2.7 < µ 145 Nd < 3.3 and 2.2 < µ 148 Nd < 8.1). Moreover, the three terrestrial planets for which we have samples available (Earth, Mars, and the Moon) as well as the silicate inclusions from the non-magmatic IIE iron meteorite Miles present a systematic deficit in µ 145 Nd and µ 148 Nd compared to early-formed NC achondrites. Unlike chondrites, the Nd anomalies in achondrites are not correlated to the heliocentric distance of accretion of their respective parent bodies as inferred from redox conditions. Chronological constraints on planetesimal accretion suggests that Nd (and other elements such as Mo and Zr) nucleosynthetic compositions of the inner part of the protoplanetary disc significantly changed around 1.5 Ma after Solar System formation due to thermal processing of dust in the protoplanetary disc. This relatively late event coincides with the beginning of chondrule formation or at least their preservation. Terrestrial planets formed subsequently by a complex accretion regime during several million years. Therefore, two scenarios are envisioned considering the reported Nd isotope composition of early planetesimals: 1) Terrestrial planets accreted mostly chondritic material similar in composition to enstatite chondrites, or 2) early planetesimals constitute substantial parts of terrestrial planets building blocks mixed with highly thermally processed material enriched in s-process, still unsampled by meteorites.

Introduction

The location and timing of planetesimal formation within the protoplanetary disc are two critical parameters that influenced the formation of the terrestrial planets (Earth, Mars, Venus, and Mercury) and the precursor of the Moon. Recent studies have found evidence for the coexistence of two isotopically distinct reservoirs: the non-carbonaceous (NC), and carbonaceous reservoirs (C) [START_REF] Trinquier | Widespread 54 Cr heterogeneity in the inner solar system[END_REF][START_REF] Leya | Titanium isotopes and the radial heterogeneity of the solar system[END_REF]Kruijer et al., 2017). Molybdenum and Hf-W systematics bear evidence for an early formation of non-carbonaceous and carbonaceous reservoirs before the accretion of differentiated (iron and achondrite meteorites) and undifferentiated (chondrites) planetesimals (Kruijer et al., 2017). The formation of Jupiter was proposed to have taken place within 1 million years after CAIs to explain the separation of these two isotopically distinct reservoirs (Kruijer et al., 2017). The parent bodies of the carbonaceous chondrites and achondrites may have formed within a distinct reservoir further out in the disc before being transferred with the NC parent bodies to form together the asteroid belt (Kruijer et al., 2020). Based on mass-independent isotopic anomalies of refractory (e.g., 50 Ti, 48 Ca) and non-refractory (e.g., 54 Cr, 58 Ni) elements, Earth appears systematically as an end-member for the Solar System inner nebular reservoir; the so-called NC reservoir [START_REF] Mezger | Accretion of the Earth-Missing Components?[END_REF].

The formation timescales of differentiated planetesimals are constrained by the 182 Hf-182 W, 53 Mn- 53 Cr and 26 Al-26 Mg radiometric ages and isotopic evolution models of achondrite meteorites [START_REF] Sugiura | Correlated accretion ages and ε 54 Cr of meteorite parent bodies and the evolution of the solar nebula[END_REF]. Achondrites can be samples of planetary cores (irons) and mantle and crust silicate layers (primitive achondrites and basaltic achondrites). We use the term achondrites hereafter to encompass silicate-rich meteorites from planetesimals. The crystallisation ages and geochemical compositions of achondrite meteorites together provide minimum ages for differentiation as well as model ages for the accretion of their respective parent bodies after CAIs. The parent bodies of most achondrites formed within the first 2 Ma after CAIs (based on 182 Hf-182 W, 26 Al-26 Mg model ages; e.g., Kruijer et al., 2017;[START_REF] Sugiura | Correlated accretion ages and ε 54 Cr of meteorite parent bodies and the evolution of the solar nebula[END_REF]. In contrast, most chondrules from ordinary (LL, L) and carbonaceous chondrites (CV, CO, CM, CR), the main constituents of chondrites, formed from around 1.5 to 5 Ma after CAI based on 26 Al-26 Mg systematics (e.g., [START_REF] Pape | Time and duration of chondrule formation: Constraints from 26 Al-26 Mg ages of individual chondrules[END_REF]. Consequently, the parent bodies of these chondrites must have accreted even later. Chondrites are generally used to define the building blocks of the Earth. However, achondrites formed earlier, owing to the higher abundance of 26 Al at the time of formation of their parent body and may also contribute significantly to Earth's building blocks.

Several studies have hinted at a possible temporal evolution of the inner protoplanetary disc composition and explained the latter by the incorporation of material of presolar [START_REF] Sugiura | Correlated accretion ages and ε 54 Cr of meteorite parent bodies and the evolution of the solar nebula[END_REF] or CI chondrite nature [START_REF] Schiller | Isotopic evolution of the protoplanetary disk and the building blocks of Earth and the Moon[END_REF] into the accreting planetesimals.

The comparison of different systematics is complicated by the various carriers and behaviour of the elements. Therefore, cosmochemical interpretation of the protoplanetary disc evolution requires different processes to account for the variability of all systematics rather than a single process.

Neodymium is interesting in this respect as it has six isotopes that are produced during stellar nucleosynthesis by s-, rand p-processes in different proportions (Figure S1). Two isotopes, 142 Nd and 143 Nd, are produced in part by the radioactive decay of extinct 146 Sm and live 147 Sm for which the radiogenic contribution can blur the nucleosynthetic anomalies. Most notably, the difference between the 142 Nd/ 144 Nd ratio of chondrites and the Earth was originally attributed to an early differentiation event on Earth [START_REF] Boyet | 142 Nd evidence for early (> 4.53 Ga) global differentiation of the silicate Earth[END_REF] before several studies show that nucleosynthetic anomalies are likely responsible for this offset (Bouvier and Boyet, 2016;Burkhardt et al., 2016). Nd nucleosynthetic anomalies, similarly to most heavy elements, are increasing from enstatite chondrites, through ordinary chondrites and finally carbonaceous chondrites. The distribution of Nd nucleosynthetic anomalies has been related to the heliocentric distance to account for the covariation of Nd and Mo in chondrites with Earth as an end-member, enriched in s-process as observed for many elements [START_REF] Render | The cosmic molybdenum-neodymium isotope correlation and the building material of the Earth[END_REF]. This led to the hypothesis that Earth formed from materials that are not present in our meteorite collections, although the closest match for the isotopic compositions of many elements are the enstatite chondrites (e.g. [START_REF] Akram | Zirconium isotope evidence for the heterogeneous distribution of s-process materials in the solar system[END_REF]Burkhardt et al., 2016;[START_REF] Dauphas | The isotopic nature of the Earth's accreting material through time[END_REF]Boyet et al., 2018). So far, very little high precision data is available on achondrites from the early planetesimals that probe the solar system composition before chondrule formation and terrestrial planets accretion.

In this study, we provide new Nd mass-independent isotope composition of achondrites from various groups from the NC and C reservoirs to assess the distribution of Nd nucleosynthetic anomalies within the protoplanetary disc over the first few million years of its existence. The 142 Nd/ 144 Nd and 143 Nd/ 144 Nd are not discussed because of the uncertainties on corrections to make from radiogenic contributions owing to complex Sm/Nd fractionation histories for achondrites.

Methods

Samples

Fragments of one to three grams of 11 primitive and differentiated achondrite meteorites were obtained from national and private collections (see details in Supplementary Information). Achondrites from the newly defined non-carbonaceous and carbonaceous groups were selected for this study. Noncarbonaceous achondrites include two eucrites Tirhert and NWA 11001, ureilite Catalina 037; aubrite Khor Temiki; enstatite achondrite Itqiy (EH7); two ungrouped achondrites NWA 12338 (eucrite-like) and NWA 11119, as well as an individual silicate inclusion extracted from the IIE iron Miles. Two different fractions were analysed for NWA 11119, a whole-rock powder and a mixed fraction of mineral separates (pyroxene, plagioclase and silica). The two ungrouped carbonaceous achondrites analysed in this study are NWA 6704 and Tafassasset. In addition, the martian polymict breccia NWA 7034 was analysed.

Preparation and chemical procedure

Sample preparation, dissolution, and first stages of chemistry were carried out in cleanroom conditions in the GEOMETRIC laboratory at University of Western Ontario. The Sm and Nd final purification procedures were carried out at Laboratoire Magmas et Volcans (LMV). All chemicals were distilled in Savillex Teflon stills (HNO3 and HCl) or purchased (HF, H2O2, HClO4) at ppt levels or better for trace metals. Water was deionized using filtration systems to reach 18.2 MΩ resistivity.

All meteorite fragments were first cleaned with acetone and leached with mild acids where surficial carbonates (caliche) were still observed. A large individual silicate inclusion (~130 mg) in Miles was isolated from the metal using aqua regia on a hot plate (80°C) for 48 h. Sample powders were dissolved in high pressure Teflon vessels (Parr bombs) following methods described in Bouvier et al. (2008).

An aliquot of about 1-5% was used for trace element analysis, a 10 % aliquot for isotope dilution, and the remainder was used for unspiked Nd and Sm isotopic analyses (see section 2 of the Supplementary Information).

Two methods of REE separation were used for unspiked samples of this study: (1) cation exchange separation with 2-methylactic acid (2MLA) for Itqiy, Tirhert (1), NWA 7034 and Khor Temiki (see Bouvier and Boyet, 2016 for details); and (2) Ln-Spec-based method for the other samples. This last method is fully described by [START_REF] Garçon | Factors influencing the precision and accuracy of Nd isotope measurements by thermal ionization mass spectrometry[END_REF] and uses NaBrO3 to oxidise and remove Ce. Samples were processed twice on that column and a final purification step of Nd is made on a fine-grained 20-50 µm Ln-Spec resin. Samarium was separated from the other REE using 2 mL Biorad Polyprep® columns filled with the cation resin AG 50W-X8 in 2-methylactic acid medium.

Nd isotopic compositions

Thermo Scientific TM Triton and Triton Plus thermal ionisation mass spectrometer (TIMS) were used at LMV for the Nd and Sm isotopic analyses of unspiked samples.

For Nd, samples from 150 ng to 1000 ng were loaded in 2 M HCl on outgassed zone-refined Re filament using H3PO4. The analysis was made in different modes according to the amount of Nd available.

Standard isotopic measurements for each method are given in Table S2 and data with analytical methods used for each sample are reported in Table 1. All Nd compositions were normalised to 146 Nd/ 144 Nd = 0.7219 using an exponential law to correct mass fractionation.

Samples with low Nd content (< 200 ng) were run in static mode on Faraday cup detectors which were less than 6 months old. Other samples were analysed dynamically using either the 2-lines dynamic method described in Bouvier and Boyet (2016) or the 4-lines dynamic method developed by Garçon et al. (2018) when a larger mass of Nd was available, typically above ~ 250 ng. The 4-line dynamic method developed by [START_REF] Garçon | Factors influencing the precision and accuracy of Nd isotope measurements by thermal ionization mass spectrometry[END_REF] provides better precision on Nd stable isotope ratios and long-term reproducibility. This method requires large amounts of samples, typically 500-700 ng Nd, but a reasonable precision can be achieved with 250 ng Nd as demonstrated here with NWA 11119 and Miles samples. Intensities measured for the samples ranged from 0.6 to 8×10 -11 A for 142 Nd in the samples. The ratios were calculated for each sample as an average of all dynamic ratios of every cycle.

All ratios are corrected for mass fractionation using the exponential law and 146 Nd/ 144 Nd = 0.7219. Errors reported for individual measurements correspond to 2 × standard error (SE). The external reproducibility is assessed using the JNdi-1 standard reference for each session because of the long-term drift observed in static methods of measurement [START_REF] Garçon | Factors influencing the precision and accuracy of Nd isotope measurements by thermal ionization mass spectrometry[END_REF] and is reported as 2 × standard deviation (SD).

The reproducibility ranges from 4-13 ppm for 142 Nd/ 144 Nd, 2-9 ppm for 143 Nd/ 144 Nd, 1-13 ppm for 145 Nd/ 144 Nd, 4-15 ppm for 148 Nd/ 144 Nd and 11-34 ppm for 150 Nd/ 144 Nd for all series irrespective of the load and method used. All µ values are calculated with the standard measured in the same session with a similar load to avoid drifting related to the cup ageing, following this equation:

µ " = $ ! ! ! " " #$%&'( ! ! ! " " #)$"*$+* -1' × 10 # $
where i X/ n X stands for the isotope ratio for an element X with isotopes i and n for the normalising isotope.

Mass-independent stable Nd isotope composition of achondrites and planetary bodies

The Nd isotope compositions of the samples measured in this study are reported in Table 1. Several isotopic ratios are not discussed in the main text (see section 6 of the Supplementary Information): 1) S3, S4, S5 and S6. The grey areas represent the external uncertainty of JNdi-1 standards using the 4 lines-dynamic method (Table S2). The s-process composition is from Bisterzo et al. (2014). The leachates regression is calculated using data from Qin et al. (2011a) and Boyet and Gannoun (2013). See text for more details.

Eucrites

Eucrite samples analysed in this study consist of Tirhert and NWA 11001. In addition, five eucrites analysed by [START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF] are included in the eucrite mean composition. Data from [START_REF] Boyet | 142 Nd evidence for early (> 4.53 Ga) global differentiation of the silicate Earth[END_REF], the only other study that reports stable Nd isotope composition for eucrites, is not included here because precision on stable isotopes is significantly lower than our current dataset.

Incorporating that data gives a very similar average value but with larger errors. Average compositions of Tirhert and NWA 11001 are determined from the individual measurements reported in this study.

The mean Nd isotope composition of eucrite is calculated from the seven meteorites reported so far and yield a µ 145 Nd = 7.1 ± 0.9 and µ 148 Nd = 12.6 ± 1.6 (2 standard errors, SE, n=7). reported by [START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF]. Carbonaceous achondrites along with NWA 11119 have the most positive µ 148 Nd, similar to the value of NC NWA 5363 ungrouped achondrite (paired with NWA 5400) reported by Burkhardt et al. (2016).

Ungrouped achondrites

3.3 Enstatite achondrite, ureilite, iron silicate inclusion, and angrite meteorites Catalina 037 is a pigeonite and augite-bearing ureilite. It had just enough Nd (in over 3 g dissolved) to be analysed in static mode yielding µ 145 Nd = 3.9 ± 2.2 and µ 148 Nd = 12.6 ± 3.9 (2 SD).

Miles is a IIE non-magmatic iron meteorite with silicate inclusions composed of plagioclase, augite and orthopyroxene. The individual silicate inclusion analysed in this study has a composition indistinguishable within errors from the standard with µ 145 Nd = 4.4 ± 2.3 and µ 148 Nd = 2.3 ± 6.8 (2 SD).

Neodymium isotope compositions of angrites have been reported by Saji et al. (2020) and [START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF]. The average composition of angrites, excluding NWA 4801 (see [START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF], is µ 145 Nd = 7.3 ± 1.6 and µ 148 Nd = 13.9 ± 3.8 (2 SE, n=5).

Martian meteorites and the Moon

The martian polymict breccia NWA 7034 (n=3) was analysed with a 2-line dynamic method in this study and yields a composition indistinguishable from the standard within errors for µ 145 Nd and µ 148 Nd.

Several literature studies have reported Nd isotope compositions for martian meteorites with various levels of precision as most studies focused on 142 Nd (Table S4). The weighted mean composition of Mars obtained is µ 145 Nd = 3.3 ± 1.5 and µ 148 Nd = 4.3 ± 2.1 (2 SE, n = 51 and 39 respectively).

Lunar samples were not analysed in this study but literature data is relatively abundant (Table S5). As lunar samples are more commonly affected by neutron capture effects, only samples with ε 149 Sm < 6 were included in this compilation and all corresponding Nd compositions were corrected for neutron capture effects. We find a weighted mean composition for the Moon of µ 145 Nd = 0.4 ± 2.3 and µ 148 Nd = -1.3 ± 2.5 (2 SE, n = 42).

0 Not all publications on martian meteorites report all isotope ratios. We included 51 measurements for µ 145 Nd and 32 for µ 148 Nd.

b The mean composition of carbonaceous chondrites used here does not include the highly variable CV chondrites because of the varying content in CAI that greatly affects their Nd isotope composition as well as CI chondrites and Tagish Lake that have a distinct composition from other CC groups.

Discussion

Gap in the Nd isotope composition between NC achondrites and chondrites

The C-NC isotope dichotomy divides both chondrites and achondrites into two distinct groups that coexisted separately in the protoplanetary disc [START_REF] Trinquier | Widespread 54 Cr heterogeneity in the inner solar system[END_REF][START_REF] Leya | Titanium isotopes and the radial heterogeneity of the solar system[END_REF]. Compared to other heavy elements such as Mo, Nd isotope ratios normalised to 146 Nd/ 144 Nd lack resolution on pand rnucleosynthetic processes to identify this dichotomy which consists primarily in an excess of rprocess and depletion in p-process or variable s-process compositions [START_REF] Stephan | Molybdenum Isotopes in Presolar Silicon Carbide Grains: Details of s-process Nucleosynthesis in Parent Stars and Implications for r-and p-processes[END_REF]Bouvier and Boyet, 2016;Kruijer et al., 2020). Indeed, excess or depletion in r-process coincides with the s- NC achondrites display stronger anomalies in comparison to their chondritic counterparts (ordinary and enstatite chondrites). These achondrites are intermediate in composition between ordinary and carbonaceous chondrites. This observation is corroborated by a recent study on eucrites and angrites [START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF]. The difference between NC achondrites and chondrites is also observed for other elements such as Zr, Mo and Cr (Figure 2). The distinction between achondrites and ordinary chondrites is not clear with ε 96 Zr when including compositions from different studies, but [START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF] suggest that ordinary chondrites display resolved anomalies from angrites. However, concerning Mo and Cr, achondrites are clearly resolved from ordinary and enstatite chondrites.

Chromium isotope composition reflects many nucleosynthetic processes and the anomalies cannot be strictly compared to those of heavy elements. The Nd and Cr isotope compositions of achondrites are not well correlated (Figure 2). In fact, the spread in ε 54 Cr of planetesimal achondrites is not observed in µ 148 Nd, which is rather homogeneous. Nd and Cr are hosted in different carriers, SiC and oxides, respectively, and are not produced in the same stellar environment. Chromium-54 is predominantly produced in type Ia or II supernova [START_REF] Dauphas | Neutron-rich chromium isotope anomalies in supernova nanoparticles[END_REF]Qin et al., 2011) and Nd s-process in asymptotic giant branch (AGB) stars (Hoppe and Ott, 1997). About 40% of Nd nuclides are produced by r-process but are not hosted in a presolar carrier (Qin et al., 2011;Boyet and Gannoun, 2013;Bisterzo et al., 2014). Thus, it is difficult to interpret this general trend as a true correlation.

A correlation between Nd, Zr and Mo nucleosynthetic anomalies has been suggested by [START_REF] Render | The cosmic molybdenum-neodymium isotope correlation and the building material of the Earth[END_REF] and [START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF]. Even if the carriers of the anomalies for these elements are different, the observed trends appear to reflect s-process variations. The advantage of Mo lies in its moderately siderophile nature that allows for the comparison of iron meteorites with stony achondrites.

Most iron and stony NC achondrites display more positive Mo isotopes anomalies compared to ordinary chondrites. The IAB-MG, -sLL, -SLM, IIICD and IIE irons, aubrites and some ungrouped achondrites are exceptions and display lower or similar Mo anomalies than ordinary chondrites [START_REF] Budde | Molybdenum isotopic evidence for the late accretion of outer Solar System material to Earth[END_REF][START_REF] Hilton | New implications for the origin of the IAB main group iron meteorites and the isotopic evolution of the noncarbonaceous (NC) reservoir[END_REF]. The distinction between achondrites and chondrites is therefore not restricted to Nd and is a significant feature that is observed particularly for heavy elements. This feature may transcribe: (1) a spatial heterogeneity, or (2) a temporal variation in the protoplanetary disc, or both. 4.2 Variation of the Nd nucleosynthetic anomalies within the inner regions of the protoplanetary disc

Oxygen fugacity gradient within the protoplanetary disc as a proxy for heliocentric distance

Previous studies have proposed that the Nd isotope composition of chondrites is related to the heliocentric distance of accretion of their respective parent bodies (Bouvier and Boyet, 2016;Burkhardt et al., 2016;[START_REF] Render | The cosmic molybdenum-neodymium isotope correlation and the building material of the Earth[END_REF][START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF]. Defining the location of formation of a meteorite parent body is challenging and some authors have proposed that the volatile elements content and oxygen fugacity in meteorites could provide clues in this regard (e.g. [START_REF] Grossman | Redox Conditions in the Solar Nebula: Observational, Experimental, and Theoretical Constraints[END_REF][START_REF] Morbidelli | Building terrestrial planets[END_REF]. Concerning chondrites, this distinction seems plausible as the gradient in the Nd isotope composition matches a general trend of volatile depletion and oxidation in chondrites from enstatite to carbonaceous chondrites. Enstatite chondrites are extremely reduced, possibly even more reduced than the solar nebula conditions [START_REF] Grossman | Redox Conditions in the Solar Nebula: Observational, Experimental, and Theoretical Constraints[END_REF]. Ordinary chondrites display a range of oxidation from H to LL subgroups and carbonaceous chondrites are generally more oxidized with barely no metal in aqueously altered groups. The distribution of asteroids in the main belt highlights the original zonation in the Solar System with the prevalence in the inner parts of the asteroid belt of E-and S-type asteroids, possible parent bodies of enstatite and ordinary chondrites respectively, whereas Ctype (carbonaceous) asteroid populate the outer parts (DeMeo and Carry, 2014). Consequently, the oxygen fugacity is considered as a proxy of the heliocentric distance of accretion of the parent body of a given meteorite group.

However, the heliocentric distance of achondrite parent bodies when they formed is much more difficult to assess due to the loss of volatile elements during degassing of the magma ocean and the oxygen fugacity variation during the differentiation events on planetesimals. [START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF] recently suggested that the correlation between Nd and Zr nucleosynthetic anomalies and water content of chondrites implies that nucleosynthetic anomalies are a proxy for the heliocentric distance of accretion. Our dataset that includes various types of achondrites suggests otherwise. In the search for a proxy of the heliocentric distance, the oxygen fugacity could provide significant information. Despite its variation during magmatic processes, the oxygen fugacity gives a broad estimation of the nebular reservoirs of achondrites.

The oxidation degree, or oxygen fugacity (fO2), of the meteorites can be quantified with various methods including XANES (X-Ray Absorption Near Edge Structure) studies and thermodynamical calculations based on the chemical composition of various phases. The oxygen fugacity is expressed relative to the Iron-Wüstite buffer (∆IW) in the following sections. Crustal rocks generally display higher fO2 than their primary melt, as exemplified on Earth with the primitive mantle of about ∆IW -2 and andesites up to ∆IW +6 [START_REF] Righter | Redox variations in the inner solar system with new constraints from vanadium XANES in spinels[END_REF]. Therefore, the oxygen fugacity of achondrites reported here corresponds to the higher end of the fO2 conditions of their respective parent bodies.

The distribution of Nd nucleosynthetic anomalies relative to fO2 differs when considering achondrites and chondrites (Figure 3). The µ 148 Nd of chondrite groups increase with heliocentric distance, whereas the planetesimal-derived achondrites, excluding Miles, display a similar µ 148 Nd while spanning over a large range of fO2 (-6.5 < ∆IW < 1). Mars, the Earth and the Moon formed in fO2 conditions similar to that of achondrites but display much lower µ 148 Nd anomalies. This observation conflicts with the interpretation of a heliocentric distribution of the nucleosynthetic anomalies of many elements in achondrites and chondrites alike. In addition, the comparison of Nd and Mo nucleosynthetic anomalies of parent bodies with their formation locations within the solar system inferred by the model of Desch et al. ( 2018) yields a similar interpretation (Figure 4).

Spatial distribution has also been invoked to explain the distribution of the nucleosynthetic anomalies in meteorites (e.g. Burkhardt et al., 2016;[START_REF] Fischer-Gödde | Ruthenium isotopic evidence for an inner Solar System origin of the late veneer[END_REF][START_REF] Render | The cosmic molybdenum-neodymium isotope correlation and the building material of the Earth[END_REF][START_REF] Ek | The origin of s-process isotope heterogeneity in the solar protoplanetary disk[END_REF][START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF]. This interpretation is based on three types of chondrites (enstatite, ordinary and carbonaceous) and the correlation between nucleosynthetic anomalies and H2O content, the latter inferred to increase with heliocentric distance due to the thermal gradient in the protoplanetary disc. Most chondrites formed coevally and their heterogeneous nucleosynthetic composition needs to be spatially-distributed. When Rumuruti chondrites are considered, this relationship breaks down for Cr and Mo for instance. Indeed, these chondrites are relatively oxidised and contain more water than other non-carbonaceous chondrites [START_REF] Krot | 1.1 -Classification of Meteorites and Their Genetic Relationships[END_REF], whereas their nucleosynthetic composition is close to enstatite chondrites for Cr (Figure 2). Nucleosynthetic anomalies for Mo are variable and are either lower or higher in magnitude than ordinary chondrites considering [START_REF] Budde | Molybdenum isotopic evidence for the late accretion of outer Solar System material to Earth[END_REF] or [START_REF] Yokoyama | Origin and Evolution of Distinct Molybdenum Isotopic Variabilities within Carbonaceous and Noncarbonaceous Reservoirs[END_REF] data, respectively. As demonstrated above, achondrite nucleosynthetic anomalies are not distributed following the heliocentric distance (Figures 3 and4).

Temporal distribution of the Nd nucleosynthetic anomalies

Increasingly precise Hf-W and Al-Mg short-lived radiometric ages show that accretion ages of iron meteorites are older than chondrules, which start to form around 2 Ma after CAI based on Al-Mg systematics (e.g. Kruijer et al., 2017;[START_REF] Pape | Time and duration of chondrule formation: Constraints from 26 Al-26 Mg ages of individual chondrules[END_REF]. Older ages of chondrules obtained by Pb-Pb [START_REF] Bollard | Early formation of planetary building blocks inferred from Pb isotopic ages of chondrules[END_REF] or Mn-Cr chronometry [START_REF] Zhu | Chromium Isotopic Evidence for an Early Formation of Chondrules from the Ornans CO Chondrite[END_REF]) may be caused by several processes. For instance, precursor compositions not fully resetting during chondrule melting events, as suggested by the abundance of volatile elements in chondrules [START_REF] Mahan | Volatile element evolution of chondrules through time[END_REF]; and Th/U ratio variability in chondrules [START_REF] Blichert-Toft | Th/U variability in Allende chondrules[END_REF] may result in erroneous ages. The Al-Mg systematics are not exempt from debate, as the homogeneity of the initial abundance of 26 Al is still contested but involve refractory elements and agree with the Hf-W system chronology [START_REF] Nagashima | 26 Al-26 Mg Systematics of Chondrules[END_REF].

The accretion ages of differentiated achondrites are more difficult to constrain owing to thermal and geochemical models. [START_REF] Sugiura | Correlated accretion ages and ε 54 Cr of meteorite parent bodies and the evolution of the solar nebula[END_REF] suggested that most achondrite parent bodies accreted before chondrules and have similar or younger accretion ages to that of iron meteorite parent bodies.

NWA 5363/5400 formed around 2.2 ± 0.8 Ma after CAI based on I-Xe age and Hf-W modelling (Burkhardt et al., 2017) and NWA 11119 accretion age has not been reported in the literature. However, the rock crystallised at 4564.8 ± 0.3 Ma, thus within 2-3 Ma of CAIs according to Al-Mg dating [START_REF] Srinivasan | Silica-rich volcanism in the early solar system dated at 4.565 Ga[END_REF], and therefore its parent body must have accreted in the period deduced for other basaltic achondrites (e.g., angrites, eucrites, ureilites, ungrouped such as NWA 6704 or Tafassasset). Thus, the parent bodies of achondrites accreted before chondrules even formed or were at least preserved and accreted to form the chondrites.

In contrast, planetary bodies accreted over a longer period of time, spanning several millions of years after chondrule formation. Some achondrites also formed later, notably the IAB and IIE parent bodies according to the Hf-W systematics. The Hf-W ages of the IAB and IIE irons are possibly reset due to impact melting and re-equilibration, nevertheless, the oldest model ages agree with a rather late accretion around 1.5 Ma, thus significantly later than other iron groups [START_REF] Hunt | Late metal-silicate separation on the IAB parent asteroid: constraints from combined W and Pt isotopes and thermal modelling[END_REF][START_REF] Hilton | New implications for the origin of the IAB main group iron meteorites and the isotopic evolution of the noncarbonaceous (NC) reservoir[END_REF][START_REF] Kruijer | Age and origin of IIE iron meteorites inferred from Hf-W chronology[END_REF]. Despite the rather unprecise accretion ages, Nd and Mo nucleosynthetic anomalies in achondrites and chondrites of the non-carbonaceous group appear to roughly decrease with the age of accretion of the parent bodies, particularly around 1.5 Ma (Figure 4). This trend is not observed in carbonaceous achondrites that are thought to originate from CR-related reservoirs (Gardner-Vandy et al., 2012;[START_REF] Sanborn | Carbonaceous achondrites Northwest Africa 6704/6693: Milestones for early Solar System chronology and genealogy[END_REF] and display the same Nd isotope composition with CR chondrites. Three groups can be distinguished in non-carbonaceous meteorites based on chronological constraints: 1) early planetesimal achondrites; 2) chondrites; 3) late planetesimal achondrites and planetary bodies.

Several studies have suggested a temporal distribution of the nucleosynthetic anomalies (e.g. [START_REF] Sugiura | Correlated accretion ages and ε 54 Cr of meteorite parent bodies and the evolution of the solar nebula[END_REF][START_REF] Sugiura | Correlated accretion ages and ε 54 Cr of meteorite parent bodies and the evolution of the solar nebula[END_REF][START_REF] Schiller | Isotopic evolution of the protoplanetary disk and the building blocks of Earth and the Moon[END_REF]. Using the Cr isotope systematics, [START_REF] Sugiura | Correlated accretion ages and ε 54 Cr of meteorite parent bodies and the evolution of the solar nebula[END_REF] evidenced a correlation between time of accretion and ε 54 Cr anomalies. [START_REF] Hilton | New implications for the origin of the IAB main group iron meteorites and the isotopic evolution of the noncarbonaceous (NC) reservoir[END_REF] also identified a correlation between µ 182 W and µ 97 Mo indicating a possible temporal evolution of the Mo nucleosynthetic anomalies of non-carbonaceous iron meteorites. Our Nd data corroborate these findings and highlight the gap between the nucleosynthetic signatures of achondrites, chondrites, and planetary bodies.

We argue that the temporal distribution of Nd and Mo nucleosynthetic anomalies are likely, but nevertheless do not rule out a spatial heterogeneity of the anomalies. The range of nucleosynthetic anomalies observed in early planetesimal achondrites cannot be related to a temporal evolution and may reflect spatial heterogeneities in different parts of the inner solar system in which radial mixing is significant as exemplified in accretion models (e.g. Raymond and Morbidelli, 2020). Nonetheless, the large change in Nd and Mo nucleosynthetic composition between early planetesimals and planetary bodies appears temporally related and occurred relatively late. This is also demonstrated with the lower intensity of the anomalies of the two late-formed iron meteorite groups: the IIE that display comparable Nd and Mo nucleosynthetic anomalies with OC, and the IAB that are undistinguishable from Earth's Mo composition (Figure 4). (Table S8) and references therein for iron meteorites. All meteorite groups are not plotted for all graphs, as heliocentric distances and ages of accretion are not estimated for all. The age of accretion reported for NWA 5363 represents a maximum, whereas the age of crystallisation is reported for NWA 11119, both are likely older (Burkhardt et al., 2017;[START_REF] Srinivasan | Silica-rich volcanism in the early solar system dated at 4.565 Ga[END_REF]. [START_REF] Sugiura | Correlated accretion ages and ε 54 Cr of meteorite parent bodies and the evolution of the solar nebula[END_REF] report an age of 1.8 ± 0.1 Ma based on thermal evolution models for EL6 chondrites, but there is no precise age for enstatite chondrite accretion or chondrule formation.

4.3 Thermal processing event coinciding with chondrule formation

Processes to produce heterogeneous isotopic reservoirs

The variation observed in Nd and Mo isotope compositions from achondrites to chondrites and later formed planetary bodies can be explained by two main processes: (1) addition of compositionally different matter, and (2) thermal processing. For instance, both processes have been invoked to explain the NC-CC dichotomy (e.g., Trinquier et al., 2009;[START_REF] Nanne | Origin of the non-carbonaceouscarbonaceous meteorite dichotomy[END_REF]. In the light of the new Nd stable isotopic data acquired on achondrites, we propose a new model. This model may also apply to other elements for which the carriers of the anomalies are similar such as Zr and Ba, or different such as Mo.

Following the collapse of the solar nebula, the protoplanetary disc accreted progressively and grew by viscous spreading. While expanding, the protoplanetary disc was continuously fed by the infalling nebular cloud [START_REF] Boss | Presolar cloud collapse and the formation and early evolution of the solar nebula[END_REF]. Timescales of infall depend on the initial temperature of the molecular cloud and are generally short, around 100-500 ka [START_REF] Yang | The effects of disk building on the distributions of refractory materials in the solar nebula: Refractory objects transport in the solar nebula[END_REF]. Infall of material into the protoplanetary disc is therefore unlikely to have produced the difference between the Nd isotope compositions of achondrites and chondrites which appeared relatively late, 1.5 Ma after CAIs. Infall of anomalous material creating the variation in nucleosynthetic anomalies in meteorites is principally proposed for light elements such as Cr and Ni for which the anomalies originate from supernovae products (e.g. [START_REF] Dauphas | Neutron-rich chromium isotope anomalies in supernova nanoparticles[END_REF]Qin et al., 2011b;[START_REF] Nanne | Origin of the non-carbonaceouscarbonaceous meteorite dichotomy[END_REF]. Altogether, the infall scenario does not explain the anomalies in heavier elements produced by s-, rand p-processes (e.g. [START_REF] Akram | Zirconium isotope evidence for the heterogeneous distribution of s-process materials in the solar system[END_REF][START_REF] Worsham | Distinct evolution of the carbonaceous and non-carbonaceous reservoirs: Insights from Ru, Mo, and W isotopes[END_REF][START_REF] Yokoyama | Origin and Evolution of Distinct Molybdenum Isotopic Variabilities within Carbonaceous and Noncarbonaceous Reservoirs[END_REF][START_REF] Ek | The origin of s-process isotope heterogeneity in the solar protoplanetary disk[END_REF].

Astronomical observations and astrophysical models show that protoplanetary discs are thermally zoned from the inside out and cool in a few million years [START_REF] Boss | Temperatures in protoplanetary disks[END_REF]. Thermal processing of material in the protoplanetary disc is likely to have occurred in the hot and early inner solar system. Several lines of evidence support the importance of thermal processing to produce variable nucleosynthetic anomalies in meteorites in particular for heavy elements regarding the refractory nature of anomaly carriers (e.g. [START_REF] Worsham | Distinct evolution of the carbonaceous and non-carbonaceous reservoirs: Insights from Ru, Mo, and W isotopes[END_REF][START_REF] Ek | The origin of s-process isotope heterogeneity in the solar protoplanetary disk[END_REF].

Thermal processing as the main process to produce the temporal dichotomy

Thermal processing involves a selective destruction of phases in a reservoir containing compositionally different materials. Leaching experiments evidenced that anomalous Nd is solely hosted in presolar SiC, similarly to other elements such as Ba (Boyet and Gannoun, 2013;Qin et al., 2011) and highlighted the absence of pure rand p-process Nd anomaly carriers observed in chondrites. It is very unlikely that such carriers were partially destroyed during thermal processing in the protoplanetary disc. Heavy elements anomalies measured in NC meteorites correspond to a binary mixing between s-process (sometimes multiple) refractory carriers and another component devoid of extremely anomalous material. The latter is considered to be composed of dust in the protoplanetary disc and representative of the original composition of the protoplanetary disc material excluding s-process carriers, hereafter referred to as "solar reservoir," equivalent to the ISM dust defined by [START_REF] Ek | The origin of s-process isotope heterogeneity in the solar protoplanetary disk[END_REF]. The temporal variation of Nd isotope compositions between achondrites and planetary materials suggests that the solar reservoir material that was destroyed was somewhat homogeneous in composition. In general, anomalous isotope compositions are hosted in minute grains of refractory nature, carbides, refractory metals, and oxides as evidenced by leaching experiments and presolar grains studies (e.g. [START_REF] Zinner | Presolar Grains[END_REF].

Because presolar grains are mostly refractory [START_REF] Zinner | Presolar Grains[END_REF], thermal processing is more prone to affect the solar reservoir dust rather than highly anomalous presolar grains. The nature of dust in the protoplanetary disc is diverse. However, matrix mineralogy in primitive chondrites as well as astronomical observations of the interstellar medium and protoplanetary discs reveal the predominance of amorphous silicates that would be easily altered during thermal processing (Le [START_REF] Guillou | Widespread oxidized and hydrated amorphous silicates in CR chondrites matrices: Implications for alteration conditions and H2 degassing of asteroids[END_REF][START_REF] Scott | Thermal Processing of Silicate Dust in the Solar Nebula: Clues from Primitive Chondrite Matrices[END_REF][START_REF] Tielens | Origin and evolution of dust in circumstellar and interstellar environments[END_REF].

As bulk meteorite composition is influenced by a binary mixing, one can estimate the solar reservoir composition with a mass balance using CI chondrites, considering that they contain an unaltered presolar SiC content (Huss, 1997). Depending on the SiC content and Nd concentrations in SiC, the solar reservoir µ 148 Nd ranges from +113 to +2171 ppm (see section 8 of the Supplementary Information).

Then, considering two stages in the protoplanetary disc evolution, the early achondrite and terrestrial planet formation stages, the same binary mixing can be formulated. Considering that SiC grains are not affected by this thermal processing event, the only variable is the amount of presolar SiC in the two stages as the destruction of solar reservoir material results in an increase of the SiC content in the bulk material [START_REF] Yokoyama | Origin and Evolution of Distinct Molybdenum Isotopic Variabilities within Carbonaceous and Noncarbonaceous Reservoirs[END_REF][START_REF] Ek | The origin of s-process isotope heterogeneity in the solar protoplanetary disk[END_REF]. The mass of Nd of the solar reservoir lost between the two stages to account for the composition of achondrites and planetary bodies is derived from the SiC content calculated from the two mixing stages. Because SiC are particularly rich in Ba, we apply the same mixing equations to µ 135 Ba in order to compare with µ 148 Nd. The achondrite Ba composition obtained from Juvinas eucrite (Andreasen and Sharma, 2007) is not resolved from the terrestrial standard (µ 135 Ba = 5 ± 4). Nevertheless, calculations were carried out to see if the results were consistent or totally nonsensical owing to the high Ba concentrations in SiC. The results using µ 148 Nd and µ 135 Ba in function of the concentration of SiC are reported in Figure 5 and are very similar. Neodymium and Ba content in SiC significantly influence the lost fraction of the solar reservoir. According to the presolar SiC contents in Orgueil reported by Huss and Lewis (1995), and considering Nd and Ba contents in SiC of 10 ppm to 39 ppm and 50 ppm to 400 ppm respectively, the fraction of the solar reservoir lost with thermal processing ranges from 0.2 to 2.3 % to account for the difference between achondrites and Earth's Nd and Ba isotope compositions. [START_REF] Ek | The origin of s-process isotope heterogeneity in the solar protoplanetary disk[END_REF] proposed an estimated 0.37 % of the fraction of the ISM dust destroyed, based on the 0.02% s-process enrichment of the Earth relative to carbonaceous chondrites. Our approach is different than [START_REF] Ek | The origin of s-process isotope heterogeneity in the solar protoplanetary disk[END_REF] as we consider only the inner solar system materials. Nevertheless, the two interpretations are not mutually exclusive. The difference between inner (NC) and outer (C) meteorites may reflect thermal processing in the early phases of the solar system evolution. Different dynamical scenarios have been proposed to explain the separation of planetary formation reservoirs with different compositions (e.g. Kruijer et al., 2017;[START_REF] Yokoyama | Origin and Evolution of Distinct Molybdenum Isotopic Variabilities within Carbonaceous and Noncarbonaceous Reservoirs[END_REF][START_REF] Ek | The origin of s-process isotope heterogeneity in the solar protoplanetary disk[END_REF].

The effect of thermal processing on Mo isotope compositions is more difficult to constrain as s-process

Mo is hosted in various presolar grains in addition to SiC, for which the abundance is not known.

Interestingly, in contrast to the relative homogeneity of Nd isotope compositions, the early planetesimals display variable Mo isotope compositions (e.g. [START_REF] Yokoyama | Origin and Evolution of Distinct Molybdenum Isotopic Variabilities within Carbonaceous and Noncarbonaceous Reservoirs[END_REF][START_REF] Spitzer | Isotopic evolution of the inner solar system inferred from molybdenum isotopes in meteorites[END_REF]. This heterogeneity can be interpreted as sampling a temporally and spatially heterogeneous early protoplanetary disc. [START_REF] Yokoyama | Origin and Evolution of Distinct Molybdenum Isotopic Variabilities within Carbonaceous and Noncarbonaceous Reservoirs[END_REF] suggest that the mixing trend identified in NC meteorites is due to two endmembers produced by thermal processing under different conditions, while [START_REF] Spitzer | Isotopic evolution of the inner solar system inferred from molybdenum isotopes in meteorites[END_REF] invoke the incorporation of an "inclusion-like" reservoir enriched in s-process to the NC reservoir. The two models are possible and not mutually exclusive, but a thermal processing origin appears more likely [START_REF] Yokoyama | Origin and Evolution of Distinct Molybdenum Isotopic Variabilities within Carbonaceous and Noncarbonaceous Reservoirs[END_REF]. In conclusion, the temporal distribution of Nd, Zr, Ba and Mo isotope compositions is associated with a significant thermal processing event that destroyed up to 2 % of the material in the inner protoplanetary disc, based on refractory lithophile elements systematics. Orgueil (Huss and Lewis, 1995). The most accepted content of presolar SiC is 14.2 ± 0.8 ppm.

4.4

Major change in the inner solar system reservoir Nd isotope composition around 1.5 Ma

The shift in Nd isotope composition explained by thermal processing appears to have occurred around 1.5 Ma. The lack of trend between ages of accretion and nucleosynthetic anomalies suggests that thermal processing was not protracted (Figure 4). This event may coincide with the main recorded period of chondrule formation starting at ~1.6 Ma after CAI formation, and lasted about 2 million years [START_REF] Pape | Time and duration of chondrule formation: Constraints from 26 Al-26 Mg ages of individual chondrules[END_REF]. Chondrules were ubiquitous within an inner portion of the protoplanetary disc as evidenced by their presence in different chondrite groups and with different chemical and isotopic compositions.

They formed from diverse precursors during brief heating events in the protoplanetary disc while it was still rich in gas [START_REF] Galy | The formation of chondrules at high gas pressures in the solar nebula[END_REF]. Chondrule formation involved temperatures up to 1850°C and cooling rates from 100 to 1000°C/h [START_REF] Hewins | Experimental constraints on chondrule formation[END_REF]. Chondrule formation mechanisms are still debated (Russell et al. 2018 for a recent review) but their formation conditions were likely to result in the destruction of ISM dust in the surrounding medium. Escape of the gas from the system is needed to explain the loss of Nd which is possible by the decoupling of gas and dust in the protoplanetary disc.

Whereas it is possible that chondrules formed before the chondrule-forming event recorded in chondrites, it is likely that their ubiquity in chondrites reflects a large-scale transformation in the protoplanetary disc. The change in nucleosynthetic anomalies in Nd and other systematics of the NC reservoir is coincidental to chondrule formation recorded in chondrites (Figure 6). Although it may not be strictly related to the thermal processing event, their contemporaneity is striking. Moreover, the similar Nd nucleosynthetic composition of CC achondrites (Tafassasset and NWA 6704) and chondrites could arise from the lower chondrule formation efficiency in the carbonaceous reservoir suggested by the lower chondrule to matrix ratio in these meteorites [START_REF] Krot | 1.1 -Classification of Meteorites and Their Genetic Relationships[END_REF].

Implications for terrestrial planets building blocks

Planets accreted over a long time period and likely incorporated large planetesimals during the process as well as chondrites (Raymond and Morbidelli, 2020 for a review). In the light of the reported Nd isotope composition of achondrites, the building blocks of terrestrial planets are reassessed qualitatively for refractory elements.

Earth's composition is an endmember for many isotopic systematics [START_REF] Mezger | Accretion of the Earth-Missing Components?[END_REF]. Mars' Nd isotope composition is identical to Earth's within errors, but is distinguishable for other elements such as O, Cr or Ti [START_REF] Dauphas | The isotopic nature of the Earth's accreting material through time[END_REF]. Terrestrial planets accreted differently. For instance, Mars formed more rapidly than the Earth, as inferred from its size and formation age [START_REF] Dauphas | Hf-W-Th evidence for rapid growth of Mars and its status as a planetary embryo[END_REF]Kruijer et al., 2020a). Mars may have thus incorporated different or less chondrite-like material than

Earth and/or its building blocks may have been less affected by thermal processing, such as early planetesimals.

Earth's building blocks have been deduced from the isotope composition of chondrites and generally agree with a major contribution of enstatite chondrites [START_REF] Dauphas | The isotopic nature of the Earth's accreting material through time[END_REF]. The Nd isotope composition of the Earth has been matched by only one meteorite sub-type so far: the EL3 enstatite chondrites (Boyet et al., 2018). [START_REF] Schiller | Iron isotope evidence for very rapid accretion and differentiation of the proto-Earth[END_REF] propose that a large proportion of Earth's building blocks (~40 %) is made of CI-like material, arguing that the µ 48 Ca and µ 54 Fe composition of meteorites are best explained by mixing of an inner solar system component and a CI-like component. Despite having no nucleosynthetic anomalies compared to Earth's composition on the stable isotopes of Nd, CI chondrites display a deficit between -12 to -21 ppm in µ 142 Nd. If this signature reflects a p-process deficit, it should be recorded in the terrestrial µ 144 Sm (pure p-process isotope), which is not the case (Bouvier et Boyet, 2016;Burkhardt et al., 2016). Concerning refractory lithophile elements, Earth's building blocks are therefore potentially chiefly related to enstatite chondrites and most likely to EL3 chondrites (Boyet et al., 2018).

The incorporation of early planetesimals in Earth's building blocks is another possibility. This scenario has been suggested by [START_REF] Morbidelli | Subsolar Al/Si and Mg/Si ratios of non-carbonaceous chondrites reveal planetesimal formation during early condensation in the protoplanetary disk[END_REF] to explain Earth's Al/Si and Mg/Si ratios. More thermally processed material is, however, necessary to balance Earth's composition considering a significant contribution of early planetesimals with elevated µ 145,148 Nd in Earth's building blocks. Burkhardt et al. (2016) proposed the existence of such an endmember, distinct from any kind of meteoritic material in our collections. Recently reported isotope composition of highly siderophile Ru of ancient terrestrial rocks formed before 3.8 Ga indicate that early Earth composition was distinct from all known meteorites analysed so far [START_REF] Fischer-Gödde | Ruthenium isotope vestige of Earth's pre-late-veneer mantle preserved in Archaean rocks[END_REF]. Assuming a similar distribution of the Nd and Ru anomalies, these results favour the second scenario, namely that Earth's composition is an endmember different from any chondritic (or known) material. Nucleosynthetic anomalies are however significantly related to the behaviour of the carriers of the anomalies in different environments (e.g. [START_REF] Worsham | Distinct evolution of the carbonaceous and non-carbonaceous reservoirs: Insights from Ru, Mo, and W isotopes[END_REF]. In this scenario, Earth would have accreted a large proportion of early planetesimals mixed with material more thermally processed than chondrites and more enriched in s-process.

Conclusions

Various carbonaceous and non-carbonaceous achondrites samples were analysed for mass-independent Nd isotope composition. Tafassasset and NWA 6704 carbonaceous achondrites have a similar Nd composition to the CR chondrites group from which they are possibly spatially related. The NC achondrites including aubrites, eucrites, ureilites, ungrouped meteorites, as well as angrites from this study and the literature display anomalies µ 145 Nd and µ 148 Nd between + 3.9 and + 11.0 ppm and + 9.1 and + 17.9 ppm respectively. The NC achondrites are distinct from NC chondrites and lie between ordinary and carbonaceous chondrite compositions. Planetary bodies (Earth, Mars and the Moon) as well as IIE irons display smaller anomalies µ 145 Nd and µ 148 Nd between + 0.4 and + 4.4 ppm and -1.8 and 4.3 ppm respectively, undistinguishable within errors.

The redox conditions of achondrites used as a proxy for the heliocentric distance shows that NC achondrites sample parent bodies formed in different location of the solar system have a similar Nd isotope composition. This suggests that the difference in composition observed between NC achondrites and chondrites is not related to the heliocentric distance. Early planetesimals achondrites accreted earlier than chondrites, most likely before 1.5 Ma as inferred from the IIE irons accretion age. Altogether, this suggests a time-related origin of the Nd nucleosynthetic anomalies distribution in the inner solar system.

This trend is also identified in other isotopic systematics such as those of Mo and Zr.

Thermal processing is the more likely process to produce the variations in Nd isotope composition within 1.5 Myr after the formation of CAI. The dust in the protoplanetary disc is more prone to be destroyed than the carriers of s-process isotopes such highly refractory SiC. Moreover, mass balance calculations show that up to 2 % of the Nd mass needs to be destroyed between the accretion of early achondrite parent bodies and terrestrial planets. The timing of this event coincides with chondrule formation. Achondrite compositions show that a thermal processing event within 1.5 Myr was a landmark of the inner solar system evolution and influenced the terrestrial planet composition.

Nd and Sm isotope dilution analyses

For isotopic dilution, enriched mixed 149 Sm-150 Nd spikes were added and homogenised overnight with the sample solutions prior to evaporation. Rare-Earth Elements (REE) were separated from the matrix using cation resin AG 50W-X8 200-400 mesh on separate columns dedicated for spiked and non-spiked samples respectively (see further details in Bouvier and Boyet, 2016). The Nd and Sm cuts from spiked samples were further separated on Ln-Spec 50-100 µm Eichrom® resin.

Spiked Nd and Sm fractions were analysed using a Thermo Scientific TM Neptune Plus multi-collector ICP-MS at LMV. Samples were uptaken in 0.05 M HNO3 solution which was introduced using a desolvator CETAC Aridus system with Ar and N2 gases added to control the oxide production in the plasma (see Bouvier and Boyet, 2016;Boyet et al., 2018 for more details). Neodymium and Sm samples were analysed in one block of 60 or 30 cycles respectively, each with an integration time of 8 seconds.

All Nd compositions were normalised to 146 Nd/ 144 Nd=0.7219 using an exponential law to correct mass fractionation. JNdi-1 standards were analysed every 3 samples.

For Sm, there is no standard normalisation required for isotopic dilutions. Nevertheless, a Sm standard was analyzed at the beginning of the session to control the instrumental mass bias.

A USGS BCR-2 basalt rock standard was analysed to assess the external reproducibility and accuracy of our measurements and isotope dilution deconvolution, and yielded a composition within 0.2% of reported values (Boyet et al., 2018).

Sm isotope analyses

Samarium was separated from the other REE the cation resin AG 50W-X8 in 2-methylactic acid medium.

Samples were loaded in 2 M HNO3 on outgassed zone-refined Re filaments and were analysed following the method described in Bouvier and Boyet (2016). The axial cup is centred on mass 149, while Nd and Gd interferences were monitored on masses 146 (L3) and 155 or 156 (H4), respectively. The external ( [START_REF] Busfield | Testing an integrated chronology: I-Xe analysis of enstatite meteorites and a eucrite[END_REF][START_REF] Gilmour | The I-Xe chronometer and its constraints on the accretion and evolution of planetesimals[END_REF]). An early event of differentiation and subsequent evolution could produce such a radiogenic composition with this Sm/Nd.

Nd nucleosynthetic anomalies

The deviation of the µ 142 NdB from pure s-process nucleosynthetic anomalies in carbonaceous achondrites may be related to either a multi-stage evolution or p-process contribution. The former is unlikely as these rocks have been interpreted as melting products of a chondritic source (e.g. Gardner-Vandy et al., 2012;Hibiya et al., 2019). The contribution of the p-process will drag µ 142 Nd down to more negative values, as observed in carbonaceous chondrites that contain p-depleted CAI (Bouvier and Boyet, 2016). This suggests that the reservoir from which carbonaceous achondrites formed was depleted in p-process and possibly contained CAI in order to produce this nucleosynthetic composition.

References used for Nd isotope composition of achondrites and planetary bodies in Table 2

Angrites: Saji et al. (2020), [START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF].

Eucrites: This study, [START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF].

Bunburra Rockhole: [START_REF] Render | Isotopic signatures as tools to reconstruct the primordial architecture of the Solar System[END_REF].

NWA 5363: Burkhardt et al. (2016). Moon: [START_REF] Boyet | A highly depleted moon or a non-magma ocean origin for the lunar crust?[END_REF], [START_REF] Brandon | Re-evaluating 142Nd/144Nd in lunar mare basalts with implications for the early evolution and bulk Sm/Nd of the Moon[END_REF][START_REF] Mcleod | Constraints on the formation age and evolution of the Moon from 142 Nd-143 Nd systematics of Apollo 12 basalts[END_REF], Boyet et al. (2015) and [START_REF] Borg | Isotopic evidence for a young lunar magma ocean[END_REF].

Enstatite chondrites: Burkhardt et al. (2016) and Saji et al. (2020).

Ordinary chondrites: Burkhardt et al. (2016), Fukai and Yokoyama (2017) and Saji et al. (2020).

Carbonaceous chondrites: Burkhardt et al. (2016), Fukai andYokoyama (2017, 2019) and Saji et al. (2020).

CAI: Brennecka et al. ( 2013), Bouvier and Boyet (2016) and Burkhardt et al. (2016). Only "nonterrestrial" CAI were included, Bouvier and Boyet (2016) reported CAI (Allende 322 and 323, NWA 6991 B4) with a Nd nucleosynthetic composition similar to terrestrial standards.

Concerning chondrites, Adrian (H4) and NWA 2090 (CO3) are discarded because they appear highly fractionated and deviate from chondrites from their respective groups; see Fukai and Yokoyama (2017) for discussion. The mean composition of carbonaceous chondrites does not include CV chondrites because of the varying content in CAI that greatly affects their Nd isotope composition as well as CI chondrites and Tagish Lake that have a distinct composition from other CC groups.

Data for chondrites from the literature includes only those obtained using dynamic mass spectrometric measurements for the stable isotopes of Nd.

Mixing equations used to estimate the lost fraction of the solar reservoir

The original composition of the solar reservoir can be estimated by mass balance (Eq. 1) using CI chondrites. We consider that CI chondrites contain an unaltered presolar SiC content (Huss, 1997).

µ "# !"# $% = % &'$ × ["#] &'$ × µ "# !"# &'$ + (1 -% &'$ ) × ["#] ⨀ × µ "# !"# ⨀ % &'$ × ["#] &'$ + (1 -% &'$ ) × ["#] ⨀
In this equation, XSiC corresponds to the concentration of SiC in CI chondrites, which is equal to 14.2 ± 0.8 ppm or 28.5 ±3.3 ppm using two methods of calculation (Huss and Lewis, 1995).

[Nd]SiC corresponds to the Nd content in presolar SiC that ranges from 0.5 to 11 ppm (average of 4 ppm) on large individual SiC grains [START_REF] Schulz | on Miles silicate inclusions and therefore negligible neutron capture effects on 142,145,148,150 Nd isotopes are expected. From the measured Nd isotope composition of Miles, we do not detect any neutron capture effects[END_REF] to 25 to 39 ppm in bulk SiC separates [START_REF] Zinner | S-process Ba, Nd, and Sm in presolar SiC from the Murchison meteorite[END_REF].

[Nd]⨀ is the Nd content in the solar reservoir as defined in the main text and calculated with mass balance using CI chondrites Nd concentration, 0.464 ppm [START_REF] Barrat | Geochemistry of CI chondrites: Major and trace elements, and Cu and Zn Isotopes[END_REF]. Similarly µ 148 NdCI, µ 148 NdSiC and µ 148 Nd⨀ correspond to the Nd isotope composition of CI chondrites [START_REF] Fukai | Nucleosynthetic Sr-Nd Isotope Correlations in Chondrites: Evidence for Nebular Thermal Processing and Dust Transportation in the Early Solar System[END_REF], SiC (Hoppe and Ott, 1997) and the solar reservoir, respectively.

The isotope composition of the solar reservoir is derived from Eq. 1.

µ "#

!"# ⨀ = % &'$ × ["#] &'$ × /µ "# !"# $% -µ "# !"# &'$ 0 + ["#] ⨀ /µ "# !"# $% -% &'$ 0 ["#] ⨀ -% &'$
In the light of the temporal shift reported here, and considering thermal processing of the solar r-/pprocess enriched reservoir, we can calculate how much of the later has to be destroyed to explain the composition of the terrestrial planets.

One can describe this system with two equations:

µ "# !"# )*+ = % &'$ !"# × ["#] &'$ × µ "# !"# &'$ + (1 -% &'$ !"# ) × ["#] ⨀ × µ "# !"# ⨀ % &'$ !"# × ["#] &'$ + (1 -% &'$ !"# ) × ["#] ⨀ µ "# !"# ,-./+ = % &'$ $%&'# × ["#] &'$ × µ "# !"# &'$ + (1 -% &'$ $%&'# ) × ["#] ⨀ × µ "# !"# ⨀ % &'$ $%&'# × ["#] &'$ + (1 -% &'$ $%&'# ) × ["#] ⨀
With XSiC Ach and XSiC Earth corresponding to the concentration of SiC in the achondrite and Earth accreted material. This proportion differs because of the thermal processing of the solar reservoir. They correspond to the mass of the SiC endmember MSiC, that remains unchanged, over the total mass, Mtot Ach and Mtot Earth , which decreases with increasing thermal processing in the disk.

% &'$ !"# = 1 &'$ 1 /0/ !"# and % &'$ $%&'# = 1 &'$ 1 /0/ $%&'# Hence, 1 - % &'$ !"# % &'$ $%&'# = 1 /0/ !"# -1 /0/ $%&'# 1 /0/ !"# = 5
L is the mass fraction of Nd in the solar reservoir that is lost during thermal processing between the early planetesimal stage to planets accretion.

The same equations can be used for Ba.

[Ba]CI is 2.46 ppm [START_REF] Barrat | Geochemistry of CI chondrites: Major and trace elements, and Cu and Zn Isotopes[END_REF]. Ba content in SiC is

  process mixing line and large anomalies in the p-process are only identified with µ 142 Nd.The mass-independent Nd isotope composition of achondrites and planetary bodies (Earth, Mars, and Moon) distinguishes two groups that reveal a new dichotomy related to the time of accretion. On the 1 one hand, differentiated NC and C achondrites originating from early-formed planetesimals display significant anomalies from the terrestrial JNdi-1 standard on the 148 Nd/ 144 Nd ratio with + 12 to +18 ppm excesses. On the other hand, planetary samples originating from the Moon and Mars have Nd isotope compositions indistinguishable from the terrestrial composition. A silicate inclusion from Miles (IIE iron) appears as an outlier among planetesimal achondrites as it displays composition similar to planetary samples. The two carbonaceous achondrites (NWA 6704 and Tafassasset) studied are related to CR chondrites(Gardner-Vandy et al., 2012;[START_REF] Sanborn | Carbonaceous achondrites Northwest Africa 6704/6693: Milestones for early Solar System chronology and genealogy[END_REF] and all share the same Nd isotope composition. Interpretation of the CC achondrites composition relative to CC chondrites therefore requires additional measurements of such meteorites.

Figure 2 :

 2 Figure 2: Non-carbonaceous achondrites and chondrites groups average compositions for µ 148 Nd, ε 97 Mo, ε 96 Zr and ε 54 Cr. Data sources for Mo, Zr and Cr isotope compositions are reported in TableS7, S8 and S9.A broad correlation is observed for all systems from an end-member represented by the Earth-Moon system to early planetesimal achondrites. Chromium isotope composition reflects different nucleosynthetic processes and the trend has another signification in µ 148 Nd-ε 54 Cr and ε 97 Mo-ε 54 Cr diagrams.

Figure 3 :

 3 Figure 3: µ 148 Nd (in ppm) shown against a proxy of the heliocentric distance using the redox conditions expressed relative to the IW (Fe-FeO) equilibrium, in (A) achondrites and (B) chondrites. The sources for achondrites and chondrites data are the same as those in Figure 1. Oxygen fugacities are all from Righter et al. (2016), except for ungrouped achondrites that are from Srinivasan et al. (2018) for NWA 11119, Burkhardt et al. (2017) for NWA 5363, Gardner-Vandy et al. (2012) for Tafassasset and Hibiya et al. (2019) for NWA 6704.

Figure 4 :

 4 Figure 4: Distribution of µ 148 Nd (A) and ε 97 Mo (C) with the putative heliocentric distance of accretion estimated by Desch et al. (2018) and actual position of planetary bodies, and with the estimated age of accretion determined by[START_REF] Sugiura | Correlated accretion ages and ε 54 Cr of meteorite parent bodies and the evolution of the solar nebula[END_REF] for achondrites and chondrites,[START_REF] Spitzer | Isotopic evolution of the inner solar system inferred from molybdenum isotopes in meteorites[END_REF]

Figure 5 :

 5 Figure 5: Nd and Ba fractions of the solar reservoir (in %) that is lost to account for the difference in µ 148 Nd and µ 135 Ba between achondrites and the Earth as a function of the presolar SiC content in the bulk initial solar reservoir (in ppm). Achondrite compositions used here are the mean achondrite composition for Nd and Juvinas eucrite measurement for Ba with µ 135 Ba = 5 ± 4. (Andreasen and Sharma, 2007). The various concentrations correspond to maximum concentrations measured in presolar SiC (black curve), intermediate (green and red) and minimum concentrations (blue) inferred

Figure 6 :

 6 Figure 6: Sketch of the temporal evolution of the µ 148 Nd composition of the planetesimals and planets and the ordinary chondrite (OC) chondrule Al-Mg age frequency (from Gregory et al., 2020). PB=parent body. During the first million year or so after CAI formation, the µ 148 Nd of the planetesimals is relatively homogeneous and starts to decrease around 1.5 Ma as evidenced by the silicate inclusion of a IIE iron meteorite composition. This change in the isotope composition of inner solar system materials coincides with the chondrule formation recorded in OC chondrites (light orange). As discussed in the text, chondrule formation for EC is poorly constrained and might have happened later that for OC. Planets formed later and accreted various material including chondrites. Mars accreted before 10 Ma after CAI (e.g.[START_REF] Dauphas | Hf-W-Th evidence for rapid growth of Mars and its status as a planetary embryo[END_REF] Kruijer et al., 2020) while Earth's accretion continued until the Moon-forming impact dated between 30-250 Ma after CAI[START_REF] Carlson | Rb-Sr, Sm-Nd and Lu-Hf isotope systematics of the lunar Mg-suite: the age of the lunar crust and its relation to the time of Moon formation[END_REF].

Figure S1 :

 S1 Figure S1: Theoretical deviations calculated relative to the terrestrial reference for excesses or deficits of nucleosynthetic processes with ratios normalised to 146 Nd/ 144 Nd ratio of 0.7219. Relative contributions of nucleosynthetic processes for each isotope are represented in sectors. Nucleosynthetic processes contributions are from Bisterzo et al. (2014).6. Initial 142 Nd/ 144 Nd composition of the achondrites

Figure S2 :

 S2 Figure S2: Comparison of theoretical µ 142 Nd (µ 142 Ndtheo.) according to nucleosynthetic s-process, calculated using acid leachates regression (see text) and the corrected µ 142 Nd calculated with method B (µ 142 NdB) of Boyet et al. (2018) using 143 Nd/ 144 Nd ratio. The grey areas represent the typical uncertainties on the standard measurements using the 4-lines dynamic method of Garçon et al. (2018).

Mars:

  [START_REF] Armytage | A complex history of silicate differentiation of Mars from Nd and Hf isotopes in crustal breccia NWA 7034[END_REF],[START_REF] Borg | Accretion timescale and impact history of Mars deduced from the isotopic systematics of martian meteorites[END_REF],[START_REF] Caro | Super-chondritic Sm/Nd ratios in Mars, the Earth and the Moon[END_REF],[START_REF] Debaille | Coupled 142 Nd-143 Nd evidence for a protracted magma ocean in Mars[END_REF] andKruijer et al. (2017) andSaji et al. (2020).

  highly variable.[START_REF] Schulz | on Miles silicate inclusions and therefore negligible neutron capture effects on 142,145,148,150 Nd isotopes are expected. From the measured Nd isotope composition of Miles, we do not detect any neutron capture effects[END_REF] report bulk separates of SiC Ba concentrations of 442-129 ppm (average of 215 ppm) and individual SiC concentrations of 0.6-509 ppm (average of 49 ppm), whereasÁvila et al. (2013) report 380 ppm on a bulk separate and 1.7-10.4 ppm (average of 5.9 ppm) in individual SiC grains. Barium isotope compositions are based on Orgueil for CI chondrites from[START_REF] Carlson | Chondrite barium, neodymium, and samarium isotopic heterogeneity and early earth differentiation[END_REF], on Juvinas for achondrites fromAndreasen and Sharma (2007) and on the mean of a single SiC composition from[START_REF] Liu | Ba isotopic composition of mainstream silicon carbides from Murchison: constraints for s-process nucleosynthesis in Asymptotic Giant Branch stars[END_REF].

  Figure 1: A) µ 145 Nd -µ 148 Nd compositions of NC achondrite meteorites measured in this study (green) and literature (light green) and planetary bodies. Non-carbonaceous achondrites are represented in green symbols while carbonaceous achondrites are in blue symbols. (Bun. Rock.=Bunburra Rockhole) B) µ 145 Nd -µ 148 Nd compositions of achondrites groups and planetary bodies compared with mean chondrite groups (EC=enstatite, OC=ordinary and CC=carbonaceous) compositions and CAI. Data sources are available in the Supplementary Information and Table

142 Nd/ 144 Nd and 143 Nd/ 144 Nd due to their radiogenic nature and 2) 150 Nd/ 144 Nd the because the current level of precision of about 20 ppm (2 SD) is too low to distinguish achondrites. Only 145 Nd/ 144 Nd and 148 Nd/ 144 Nd ratios are considered thereafter. The Nd isotope composition of the samples is presented for each group below. A summary of the Nd isotope composition of achondrites and chondrites groups as well as planetary bodies including results from the literature is reported in Tables 2, S3 and S6.

Achondrites and planetary samples Nd mass-independent stable isotope compositions are compared with chondrites and CAI in Figure

1

.

Table 1 :

 1 Neodymium isotope compositions of the samples and rock standards, and details for the acquisition method used for each. Elemental concentrations for Nd and Sm are also reported in 1 parts per million (ppm) from isotope dilution calculations. Errors are 2 standard errors or 2 standard deviations for averages and are reported in ppm. Numbers in brackets correspond to dissolutions 2 of different fragments of the same sample, whereas letters correspond to different runs of the same filament. µ 142 NdB corresponds to the µ 142 Nd corrected from the radiogenic contribution using

		Classification	Serie	Method	Nd (ppm)	Sm (ppm)	147 Sm/ 144 Nd	I 142 Nd (V)	µ 142 Nd	±	µ 142 NdB µ 143 Nd	±	µ 145 Nd	±	µ 148 Nd	±	µ 150 Nd	±	146 Nd/ 144 Nd	142 Ce/ 142 Nd ppm	144 Sm/ 144 Nd ppm	cycles
	Ungrouped achondrites
	NWA 6704	Achon-ung		Dyn 4L	0.30	0.10	0.1995	4.45	-12.0	1.9	-24.1	1515	1	8.9	1.7	18.3	1.2	34.4	8.6	0.7218	0.3	0.1	540
	Tafassasset	Achon-ung		Dyn 4L	0.28	0.09	0.2027	3.39	-28.0	2.4	-33.2	1241	1	10.6	2.1	17.1	1.4	12.8	11.9	0.7223	0.1	0.1	420
	NWA 11119 WR			Dyn 4L	1.19	0.51	0.2606	0.6	90.1	4.7	-5.8	4848	3	6.0	2.9	15.9	8.3	32.3	22.5	0.7211	304.5	0.0	220
		Achon-ung
	NWA 11119 MS1			Dyn 4L	1.51	0.64	0.2577	0.8	78.0	2.0	-15.4	4751	1	7.9	1.3	12.7	3.7	25.1	9.5	0.7220	0.0	0.0	250
	NWA 11119 ave.										-10.6			6.9	2.8	14.3	4.5	28.7	10.2
	NWA 12338 (1)a	Achon-ung		Dyn 4L	2.23	0.73	0.1972	5.57	-9.0	1.1	-9.4	1050	1	7.7	1.0	9.6	0.8	16.2	5.6	0.7219	1.2	9.3	1080
	NWA 12338 (1)b	Achon-ung		Dyn 4L	2.23	0.73	0.1972	5.89	-9.6	1.7	-10.0	1051	1	6.4	1.5	14.6	1.2	23.6	7.7	0.7238	0.0	0.0	510
	NWA 12338 ave.										-9.7			7.0	1.7	12.1	7.0	19.9	10.3
	Eucrites
	Tirhert (1)	Eucrite		Dyn 2L	2.77	0.91	0.1984	1.3	-19.8	3.9	-13.1	720	1	3.0	3.6	15.8	6.0	18.4	10.8	0.7222	27.9	0.1	440
	Tirhert (2)	Eucrite		Dyn 4L	-	-	-	5.14	-11.0	1.3	-11.8	1123	4	8.4	1.2	9.3	0.8	8.2	5.7	0.7206	0.1	0.1	1080
	Tirhert ave.									1.9	-12.5			5.7	7.7	12.5	9.1	13.3	14.4
	NWA 11001 (1)a	Eucrite		Dyn 4L	2.64	1.01	0.2313	7.5	42.4	1.4	-10.5	3120	1	7.3	1.3	13.7	0.9	25.5	6.4	0.7214	0.0	0.0	540
	NWA 11001 (1)b	Eucrite		Dyn 4L	2.64	1.01	0.2313	7.38	46.2	1.3	-6.8	3122	1	5.2	1.3	12.8	0.9	33.0	6.4	0.7235	0.0	0.0	540
	NWA 11001 (2)	Eucrite		Dyn 4L	2.67	1.08	0.2452	4.86	59.4	2.1	-13.5	3904	1	7.0	1.8	9.1	1.3	13.9	9.1	0.7219	0.1	0.2	540
	NWA 11001 (3)	Eucrite		Dyn 4L	-	-	-	2.84	73.5	2.4	-26.4	4968	1	5.9	2.1	17.3	1.5	16.7	11.7	0.7211	0.7	0.2	540
	NWA 11001 ave.									17.1	-14.3			6.3	2.0	13.2	6.8	22.3	17.4
	Mars
	NWA 7034 (1)	Martian		Stat	20.30	5.61	0.1668		-41.9	5.9	3.9	-717	6	-1.3	5.2	0.2	0.0	0.2	0.0		21.8	12.3
	NWA 7034 (2)	polymict		Dyn 2L	20.30	5.61	0.1668	2.3	-43.6	5.2	2.3	-724	5	-3.3	4.8	3.4	7.8	-12.4	9.7	0.7233	3141.7	0.1	240
	NWA7034 R	breccia		Dyn 2L	8.96	2.74	0.1852	1.3	-35.9	4.9	-34.2	973	5	-0.2	4.4	10.5	7.5	-3.4	10.5	0.7227	2404.8	0.2	300
	Enstatite achondrites
	Khor Temiki	Aubrite		Dyn 2L	0.43	0.16	0.2206	1.0	17.6	8.6	-19.1	2549	8	7.1	7.3	11.3	11.8	54.7	18.5	0.7235	164.8	0.0	200
	Itqiy (1)	EH7		Dyn 2L	0.07	0.06	0.5010	0.6	312.5	11.0	-21.2	14285	10	-2.7	9.0	2.8	16.7	34.3	23.7	0.7235	113.1	0.3	180
	Itqiy (2)	EH7		Stat	0.09	0.07	0.4438	0.7	435.9	11.0	-11.7	18807	10	9.2	8.0	0.8	15.7	-18.8	20.5	0.7223	235.3	0.2	200
	Itqiy ave.										-16.5			3.2	16.8	1.8	2.8	7.7	75.0
	Catalina 037	Ureilite		Stat	0.06	0.02	0.2468	7.5	72.9	3.0	-12.1	4412	2	3.9	2.2	12.6	3.9	29.9	5.3	0.7226	0.6	0.1	820
	Miles (sil. inclusion)	IIE		Dyn 4L	1.71	0.71	-	2.4	52.6	4.9	-22.7	4028	4	4.4	2.3	2.3	6.8	13.1	17.0	0.7220	84.6	198.7	250
	Rock standards
	BCR-2	Earth		Dyn 2L	28.19	6.45	0.1383	1.7	3.7	3.2		1014	3	-2.6	2.9	9.1	5.0	11.9	7.0	0.7227	128.3	0.2	440
	BCR-2	Earth		Dyn 4L				5.5	2.3	3.6		1019	5	-0.5	2.5	-4.0	5.6	-14.4	9.4	0.7213	0.0	0.0	540
	BHVO-2	Earth		Dyn 4L				4.2	5.9	3.6		1706	5	1.5	2.5	4.7	5.6	10.9	9.4	0.7216	0.1	0.0	540
	Average								4.0	3.6				-0.5	4.2	3.3	13.3	2.8	29.7

Table 2 :

 2 Nd isotope composition of achondrite and chondrite groups as well the Moon and Mars. References can be found in the section 7 of the Supplementary Information. Errors are 2 SE or 2 SD for n<4 and are reported in ppm.

	Meteorite group	µ 142 NdB	±	µ 145 Nd	±	µ 148 Nd	±	n
	Ung. CC achondrites
	NWA 6704	-24.1	1.9	8.9	1.7	18.3	1.2	1
	Tafassasset	-33.2	2.4	10.6	2.1	17.1	1.4	1
	NC achondrites
	NWA 11119	-10.6	13.7	6.9	6.0	14.3	7.3	1
	NWA 12338	-9.7	0.9	7.0	2.9	12.1	8.3	1
	Bunburra Rockhole	-6.3	4.4	7.6	3.6	11.9	5.7	1
	NWA 5363	-16.0	5.9	11.0	6.0	17.1	7.3	1
	Angrites	-13.8	3.2	7.3	1.6	13.9	3.8	5
	Ureilites	-12.1	3.0	3.9	2.2	12.6	3.9	1
	Eucrites	-14.8	2.3	7.1	0.9	12.6	1.6	7
	Aubrites	-19.1	8.6	7.1	7.3	11.3	11.8	1
	IIE (silicate inclusion)	-22.7	4.9	4.4	2.3	2.3	6.8	1
	Mars			3.3	1.5	4.3	2.1	51/32 a
	Moon			0.4	2.3	-1.3	2.5	42
	Enstatite chondrites	-11.4	2.7	3.3	1.7	2.2	1.4	21
	Ordinary chondrites	-13.0	3.0	2.7	3.1	8.1	1.6	14
	Carbonaceous
	chondrites b	-28.9	6.1	8.0	5.1	20.3	4.3	7
	CAI	-7.5	3.3	-23.4	2.3	-26.8	4.3	15
	a

Table S1 :

 S1 Sm isotope composition of achondrites

	Table of contents
	1.	Sample information	3
	2.	Nd and Sm isotope dilution analyses 3
	3.	Sm isotope analyses	3
	4.	Neutron capture effects 4
	5.	Nd nucleosynthetic anomalies 5
	6.	Initial 142 Nd/ 144 Nd composition of the achondrites	5
	7.	References used for Nd isotope composition of achondrites and planetary bodies in Table 2
		7
	8.	Mixing equations used to estimate the lost fraction of the solar reservoir 8
	List of supplementary figures
	Figure S1: Nd nucleosynthetic anomalies
	Figure S2: Comparison of decay-corrected and theoretical µ 142 Nd
	List of supplementary tables
	Included in this document

Table S2 :

 S2 Nd and Sm isotope composition of the standards

	Included in a spreadsheet

Table S3 :

 S3 Nd isotope composition of achondrites

Table S4 :

 S4 Nd isotope composition of martian meteorites

Table S5 :

 S5 Nd isotope composition of lunar samples

Table S6 :

 S6 Nd isotope composition of chondrites

Table S7 :

 S7 Zr isotope composition of meteorite groups

Table S8 :

 S8 Mo isotope composition of meteorite groups

Table S9 :

 S9 Cr isotope composition of meteorite groups 1. Sample information Sample sources: Khor Temiki (sample off BM.1934,778 from the National Museum Natural History, London), Tirhert (sample 1880_1 from the Center for Meteorite Studies, Arizona State University),

	NWA 11119 and NWA 7034 (Institute of Meteoritics, University of New Mexico) were loaned for this
	research study. Ureilite Catalina 037 (Eric Christensen), eucrite Tirhert (Adam Aaronson), and NWA
	11001 and NWA 12338 (Sean Tutorow) were kindly donated for research analyses. Meteorite slices of
	NWA 6704 (Greg Hupé), Tafassasset (Mary-Alix Kaczmarek), and Itqiy and Miles (Luc Labenne) were
	purchased from private dealers.

  Therefore, the measured 142 Nd/ 144 Nd ratio has to be corrected for the decay of 146 Sm. Concerning chondrites, two methods, hereafter A and B, have been used (seeBoyet et al., 2018). Method A uses the precisely measured 147 Sm/ 144 Nd ratio of the samples to obtain the 142 Nd/ 144 Nd at the time of the Sm/Nd fractionation, considered as the formation of the solar system for chondrites, 4568 Ga ago[START_REF] Bouvier | The age of the Solar System redefined by the oldest Pb-Pb age of a meteoritic inclusion[END_REF] and recalculate the 142 Nd/ 144 Nd at present time using the 147 Sm/ 144 Nd of the chondritic uniform reservoir (CHUR) ofBouvier et al. (2008). The method B uses the 143 Nd/ 144 Nd of the sample to recalculate the 147 Sm/ 144 Nd ratio of the sample that may be affected by terrestrial contamination, weathering or other recent perturbations that affect less significantly 143 Nd/ 144 Nd ratios. Then the same procedure is used to calculate the corrected the 142 Nd/ 144 Nd at present time. For differentiated meteorites, the time of Sm/Nd fractionation is inferred from 147 Sm-143 Nd systematics internal isochrons on samples or relying on other chronometers. We used both methods to correct the 142 Nd/

144

Nd of achondrites samples and used Sm-Nd ages whenever available or Al-Mg and Pb-Pb ages instead. We note that other chronometers may be sensitive to different equilibration temperatures and therefore may not correspond well with the Sm/Nd fractionation event.

Table S1 :

 S1 Sm isotope compositions of the achondrite samples and rock standards. Sm 146 Nd/ 152 Sm 155 Gd/ 152 Sm cycles

	Classification Sm/ 152 Ungrouped achondrites Serie I 147 Sm (V) µ 144 Sm 2 SD µ 148 Sm 2 SD µ 149 Sm 2 SD µ 150 Sm 2 SD µ 154 Sm 2 SD 147
	NWA 6704	Achon-ung	0.34	-81.6	55.8	60.1	20.9	-66.0	16.6	391.6	23.4	-18.5	18.5		0.00506	0.00010	300
	Tafassasset	Achon-ung	0.08	-114.8	189.2	-12.4	59.2	-223.2	53.4	356.2	87.3	-49.3	52.7		0.00037	0.00056	360
	NWA 11119 NWA 11119 MS1	Achon-ung	0.19 0.8	0 219	72 89	-11 17	25 31	-150 -128	21 34	254 269	27 35	-90 -64	24 33	0.5621 0.5617	0.00027 0.00229	0.00013 0.00042	160 100
	NWA 12338 (1)a		0.83	32	15	0	7	-26	6	50	7	-21	7	0.5629	0.00089	0.00000	340
	Eucrites						0
	Tirhert (1)	Eucrite	1.97	26.3	14.5	-4.2	5.3	2.7	4.7	-6.2	6.6	-6.4	5.2	0.5639	0.00034	0.00002	500
	NWA 11001 (1)a	Eucrite	1.54	26.9	13.8	0.9	6.8	-53.8	5.9	101.7	7.2	-14.1	6.6		0.00028	0.00003	540
	NWA 11001 (1)b	Eucrite	0.96	6.8	10.6	-2.1	7.8	-54.2	6.4	106.1	8.8	12.8	8.2		0.00017	0.00000	540
	NWA 11001 (2)	Eucrite	0.62	12.9	27.9	5.4	12.9	-23.8	11.0	69.3	15.0	-6.2	12.7		0.00052	0.00004	360
	Enstatite achondrites						0
	Khor Temiki	Aubrite	0.47	808.9	1436.6	195.5	186.0	-194.0	166.5	447.7	95.0	-272.3	122.2	0.5627	0.00644	0.00161	320
	Itqiy (1)	EH7	0.57	-55.9	62.3	16.3	14.2	-28.4	12.1	83.0	17.1	-14.8	12.5	0.5632	0.00108	0.00001	300
	Itqiy (2)	EH7	0.76	-58.0	42.6	34.9	13.1	-25.8	10.3	112.1	15.0	13.3	10.5	0.5633	0.00631	0.00001	240
	Standards
	Sm ICP	n = 8		0.114976±4	31.2	0.420428±6 14.8 0.516847±2	4.1	0.275980±3	9.7	0.850792±9	10.4	0.5640
	Sm ICP	n = 5		0.114976±2	19.9	0.420443±4 10.3 0.516853±5	9.6	0.275995±7 27.1 0.850798±22 25.4
	Sm ICP	n = 12		0.114976±5	41.3	0.420442±5 12.5 0.516847±6 11.1 0.275995±4 15.8 0.850788±13 15.1	0.5663

Method B with 143 Nd/ 144 Nd ratios as described inBoyet et al. (2018).

Bayerisches Geoinstitut, Universität Bayreuth, 95447 Bayreuth, Germany *Corresponding author: paul.frossard@uca.fr

Nd/

Nd (143 < ε 143 Nd <188) and µ 142 Nd (313 < µ 142 Nd < 436). The age of the Sm/Nd fractionation is not well defined with only an I-Xe age of -2.6 ±2.6 Ma relative to the Shallowater aubrite standard

Acknowledgements:

We thank Laurence Garvie (ASU), Carl Agee (UNM), Caroline Smith (NMNH), Mary-Alix Kaczmarek (GET), Eric Christensen (LPL), Adam Aaronson, and Sean Tutorow for the generous sample donations which made this study possible. We also would like to thank Delphine Auclair (LMV) and Mouhcine Gannoun (LMV) for their assistance with TIMS and MC-ICP-MS, respectively, and Chantal Bosq (LMV) for clean lab facility management. We also thank Rajdeep Dasgupta for editorial handling and thorough reviews by Maria Schönbächler and Mario Fischer-Gödde are greatly appreciated and helped improving the clarity of the paper. This project has received funding from the European Research Council (ERC) under the European Union's Horizon 2020 research and innovation program (Grant Agreement No. 682778). AB thanks support from the Canada Foundation for Innovation (Grant Agreement No. 33353), Government of Ontario (ER-15-11-077), NSERC Discovery Grant (06310-2014) and Canada Research Chair programs (950-229061). This is Laboratory of Excellence ClerVolc contribution number 480.

Supplementary information

Evidence from achondrites for a temporal change in Nd nucleosynthetic anomalies within the first 1.5 million years of the inner solar system formation Paul Frossard 1* , Zhiguo Guo 2 , Mary Spencer 2 , Maud Boyet 1 , Audrey Bouvier 3, 2 1 Université Clermont Auvergne, CNRS, IRD, OPGC, Laboratoire Magmas et Volcans, F-63000 Clermont-Ferrand, France 2 Department of Earth Sciences, University of Western Ontario, N6A 5B7 London, Ontario, Canada Many achondrites may have experienced a complex magmatic and metamorphic history, for example with several stages of Sm/Nd fractionation. This may be the case for complex crustal formation or impact processes on some parent bodies. The timing and extent of Sm/Nd fractionation at each stage cannot be accurately constrained and therefore leading to an erroneous corrected 142 Nd/ 144 Nd. One way of assessing the accuracy of the corrected 142 Nd/ 144 Nd is the petrological study of the samples and trace element geochemistry of the minerals to assess whether they are at equilibrium with the adjacent minerals. Most meteorites included in this study were extensively studied (e.g. Tafassasset and NWA 6704 and pairs) and for most of them the systems seem undisturbed and reflect simple, one-stage evolution. Another way is to compare the corrected 142 Nd/ 144 Nd with a theoretical 142 Nd/ 144 Nd according to nucleosynthetic processes. 142-Neodymium is the only Nd isotope that was produced in part by the p-process. The proportion of the p-process contribution to 142-Nd is debated but ranges from 2 to 8 % in astrophysical calculations [START_REF] Arlandini | Neutron capture in low-mass asymptotic giant branch stars: cross sections and abundance signatures[END_REF]Bisterzo et al., 2014) whereas some sample-based isotopic studies hypothesised contribution up to 20 % [START_REF] Andreasen | Solar nebula heterogeneity in p-process samarium and neodymium isotopes[END_REF][START_REF] Gannoun | 146Sm-142Nd systematics measured in enstatite chondrites reveals a heterogeneous distribution of 142 Nd in the solar nebula[END_REF]. Such a large contribution of the p-process is however unlikely and may rather reflect s-process heterogeneity among chondrites as for other Nd isotopes (Bouvier and Boyet, 2016;Boyet et al., 2018;Burkhardt et al., 2016). One can calculate a theoretical 142 Nd/ 144 Nd using 145 Nd/ 144 Nd or 148 Nd/ 144 Nd ratios. The s-process mixing line can be defined using astrophysical models for nucleosynthesis, measuring the composition of the presolar SiC grains which are the main carrier of the s-process Nd in chondrites, and unequilibrated chondrite leachate regressions, but there is some discrepancy between these three estimates.

Nucleosynthetic processes contribution for each isotopes are variable in astrophysical models and deviate from the measurements, notably on 146 Nd used for internal normalisation [START_REF] Yin | Signatures of the s-process in presolar silicon carbide grains: Barium through hafnium[END_REF].

Neodymium isotopes measurements on SiC are very difficult to perform and are obtained without elemental separation other than in the mass spectrometer, leading to large errors. The caveat with the leachate method is that it does not discriminate minerals individually and contains very little information on the nature of the anomalous carrier. However, leachates are obtained in the same conditions as the samples and are likely to represent the general trend on which the meteorite samples are scattered. Based on the leachate data on chondrites (Boyet and Gannoun, 2013;Qin et al., 2011) the µ 142 Nd can be approximated to -1.60 ´ µ 145 Nd and -0.915 ´ µ 148 Nd. The use of µ 148 Nd is preferred because of the small range of variation in the µ 145 Nd compared to the uncertainties associated.

Theoretical and corrected µ 142 Nd using method B are compared in Figure S2. Most samples plot near the 1:1 line, but three samples are clearly offset. Miles silicate inclusion, martian meteorites and carbonaceous achondrites NWA 6704 and Tafassasset have initial µ 142 NdB significantly different from µ 142 Nd inferred from their µ 148 Nd composition. Itqiy displays large errors but is not offset despite a high 147 Sm/ 144 Nd ratio, that reflects its high content in enstatite, and an extremely radiogenic composition in