Nikolaus Hansen
email: nikolaus.hansen@inria.fr

Benchmarking a BI-Population CMA-ES on the BBOB-2009 Function Testbed

Keywords: G.1.6 [Numerical Analysis]: Optimization-global optimization, unconstrained optimization; F.2.1 [Analysis of Algorithms and Problem Complexity]: Numerical Algorithms and Problems Benchmarking, Black-box optimization, Evolutionary computation, CMA-ES

We propose a multistart CMA-ES with equal budgets for two interlaced restart strategies, one with an increasing population size and one with varying small population sizes. This BI-population CMA-ES is benchmarked on the BBOB-2009 noiseless function testbed and could solve 23, 22 and 20 functions out of 24 in search space dimensions 10, 20 and 40, respectively, within a budget of less than 10 6 D function evaluations per trial.

INTRODUCTION

The covariance matrix adaptation evolution strategy (CMA-ES) is a stochastic, population-based search method in continuous search spaces, aiming at minimizing an objective function f : R D → R in a black-box scenario. In this paper, the (µ/µw, λ)-CMA-ES [START_REF] Hansen | The CMA evolution strategy: a comparing review[END_REF] is applied in a multistart strategy and benchmarked on 24 functions. Comprehensive results for the number of function evaluations to reach a target function value are given.

THE (µ/µw, λ)-CMA-ES

In the standard (µ/µw, λ)-CMA-ES [START_REF] Hansen | The CMA evolution strategy: a comparing review[END_REF][START_REF] Hansen | Evaluating the CMA evolution strategy on multimodal test functions[END_REF][START_REF] Hansen | A method for handling uncertainty in evolutionary optimization with an application to feedback control of combustion[END_REF], in each iteration step t, λ new solutions xi ∈ R D are generated by sam-pling a multi-variate normal distribution, N `0, C t ´, with mean 0 and n × n covariance matrix C t , see Eq. [START_REF] Auger | A restart CMA evolution strategy with increasing population size[END_REF]. The µ best solutions are selected to update the distribution parameters for the next iteration t + 1. The complete algorithm is depicted in Table 1. We set µ = ¨λ 2 ˝, wi = ln(µ+1)-ln i P µ j=1 (ln(µ+1)-ln j) , µ -1 w = P µ i=1 w 2 i , and dσ = 1 + cσ + 2 max " 0,

q µw-1 D+1 -1
" usually close to one, C t -1 2 is symmetric and satisfies C t -1 2 C t -1 2 = `Ct ´-1 . The remaining learning parameters have been slightly modified, without connection to the BBOB-2009 testbed, and are chosen as cσ = µw+2

D+µw+5 , cc = 4+µw/D D+4+2µw/D , c1 = 2 (D+1.3) 2 +µw and cµ = min " 1 -c1, 2 µw-2+1/µw (D+2) 2 +µw " .

BI-Population Multistart Scheme

The (µ/µw, λ)-CMA-ES with the default population size λ def = 4 + ⌊3 ln D⌋ is a robust and fast local search method [START_REF] Hansen | Completely derandomized self-adaptation in evolution strategies[END_REF]. With a large(r) population size a more global search can be accomplished successfully [START_REF] Hansen | Evaluating the CMA evolution strategy on multimodal test functions[END_REF][START_REF] Hansen | Reducing the time complexity of the derandomized evolution strategy with covariance matrix adaptation (CMA-ES)[END_REF]. After a first single run with default population size, we apply two interlaced multistart regimes, each equipped with a function evaluation budget accounting for the so far conducted function evaluations. Depending on which budget value is smaller, a complete run of either one or the other strategy is launched. The first and last restart are conducted under the first regime.

Under the first regime, we restart with increasing population size, where before each restart the population size λ is increased by a factor of two [START_REF] Auger | A restart CMA evolution strategy with increasing population size[END_REF]. At most nine restarts are conducted, i.e., the largest population size is λ = 2 9 λ def = 512 λ def . The initial σ 0 = 2 (i.e., 1/5 of the domain width). The budget is loaded from the first restart, i.e., the first single run with population size λ def is disregarded.

Second, a multistart regime with small population size is applied, where the population size λ is set to

λs = $ λ def " 1 2
λ ℓ λ def « U [0,1] 2 % ,
where λ ℓ is the latest population size from the first regime with increasing (large) λ. Here U[0, 1] denote independent uniformly distributed numbers in [0, 1] and λs 1] . A maximum number of function evaluations of half of the recent large budget is enforced, but probably of minor relevance.

∈ [λ def , λ/2]. The initial step-size is set to σ 0 = 2 × 10 -2 U [0,
The second multistart regime is launched, if and only if its recent budget is smaller than the one for the first regime with increasing populations.

t+1 σ < p 1 -(1 -cσ) 2(t+1) " 1.4 + 2

D+1

" E N (0, I) and zero otherwise. Further symbols and constants and m t=0 and σ t=0 are given in the text. The chosen ordering of equations allows to remove the time index in all variables but m t

Given t ∈ N, m t ∈ R D , σ t ∈ R+, C t ∈ R D×D positive definite, p t σ ∈ R D , and p t c ∈ R D xi ∼ m t + σ t × Ni `0, C t ´is
normally distributed for i = 1, . . . , λ and evaluated on f

(1)

m t+1 = µ X i=1 wi x i:λ where f (x 1:λ ) ≤ • • • ≤ f (x µ:λ ) ≤ f (x µ+1:λ ) . . . (2)
p t+1 σ = (1 -cσ) p t σ + p cσ(2 -cσ)µw C t -1 2 m t+1 -m t σ t (3)
p t+1 c = (1 -cc) p t c + hσ p cc(2 -cc)µw m t+1 -m t σ t (4)
C t+1 = (1 -c1 -cµ + (1 -hσ) c1cc(2 -cc)) C t + c1 p t+1 c p t+1 c T + cµ µ X i=1 wi x i:λ -m t σ t × `xi:λ -m t ´T σ t (5)
σ t+1 = σ t × exp " cσ dσ " p t+1 σ E N (0, I) -1 «« (6)

Initial and Termination Criteria

The initial mean m 0 is sampled uniformly distributed in [-4, 4] D . A single run of the (µ/µw, λ)-CMA-ES is terminated, when the final target function value is reached or one of the following termination conditions is satisfied.

MaxIter = 100 + 50(D + 3) 2 /
√ λ is the maximal number of iterations in each run of CMA-ES TolHistFun = 10 -12 : the range of the best function values during the last 10 + ⌈30D/λ⌉ iterations is smaller than TolHistFun.

EqualFunVals: in more than 1/3 rd of the last D iterations the objective function value of the best and the k-th best solution are identical, that is f (x

1:λ ) = f (x k:λ ),
where k = 1 + ⌈0.1 + λ/4⌉. TolX = 10 -12 : all components of p t c and all square roots of diagonal components of C t , multiplied by σ t /σ 0 , are smaller than TolX. TolUpSigma = 10 20 : σ t /σ 0 > TolUpSigma √ l t , where l t is the largest eigenvalue of C t , indicates a mismatch between σ increase and decrease of all eigenvalues in C. In this, rather untypical, case the progression of the strategy is usually very low and a restart is indicated.

Stagnation: the median of the 20 newest values is not smaller than the median of the 20 oldest values, respectively, in the two arrays containg the best function values and the median function values of the last ⌈0.2 t + 120 + 30D/λ⌉ iterations.

ConditionCov: the condition number of C t exceeds 10 14 .

NoEffectAxis: m t remains numerically constant when adding 0.1σ t √ l t v t , where l t is the 1+(t mod D)-largest eigenvalue of C t and v t is the corresponding normalized eigenvector.

NoEffectCoor: any element of m t remains numerically constant when adding 0.2σ t l t , where elements of l t are the square root of the diagonal elements of C t . Condition NoEffectCoor was never satisfied.

Most criteria are standard part of our production codes of (µ/µw, λ)-CMA-ES (see also next section). Restarts are launched until the final target function value or the largest, final population size is reached (see above). In neither case more than 10 6 D function evaluations were conducted.

PARAMETER TUNING

No thorough parameter study has been done. We have experimented with restarts from a so-far best found solution point but had comparatively little success. The parameters for the first multistart scheme are taken from [START_REF] Auger | A restart CMA evolution strategy with increasing population size[END_REF], those for the second are ad-hoc settings. We reckon that even smaller population sizes λs could be useful. The maximum number of iterations MaxIter has been set to prevent excessive long runs and is chosen such that most functions should be solvable within this limit. Most other termination criteria are standard, while TolUpSigma and Stagnation have been only recently added to the set of standard termination criteria. The former indicates a problem in acquiring the functions topography and seems only effective up to D = 10. The latter is of major relevance for noisy functions. The same D-dependent parameter setting is used on all functions and therefore the crafting effort [START_REF] Hansen | Real-parameter black-box optimization benchmarking[END_REF] computes to CrE = 0.

CPU TIMING EXPERIMENT

For the timing experiment the complete algorithm was run on f8 and restarted until at least 30 seconds had passed (according to Figure 2 in [START_REF] Hansen | Real-parameter black-box optimization benchmarking[END_REF]). These experiments have been conducted with an Intel dual core T5600 processor with 1.8 GHz under Linux 2.6.27-11 using Matlab R2008a. The results are shown in the following table. Up to 10-D, the necessary CPU time even reduces with increasing dimension, presumbably due to a larger number of initialization procedures for the restarts until 30 seconds have passed.

Equations ( 1) and ( 3) require a decomposition of C t . An eigendecomposition with time complexity ∝ D 3 is applied and for computational efficiency reasons only conducted until after

(c1 + cµ) -1 10D (7)
iterations have passed. Therefore, a slightly outdated decomposition is used in case. This policy results in a quadratic scaling of the internal time complexity with the dimension.

For larger dimension, a computational burden between 10 -8 and 10 -7 × D 2 seconds per function evaluation is the typical outcome of timing experiments (for D = 80 the table reveals 9 × 10 -8 D 2 seconds).

RESULTS AND DISCUSSION

Results from experiments according to [START_REF] Hansen | Real-parameter black-box optimization benchmarking[END_REF] on the benchmark functions given in [START_REF] Finck | Real-parameter black-box optimization benchmarking 2009[END_REF][START_REF] Hansen | Real-parameter black-box optimization benchmarking 2009: Noiseless functions definitions[END_REF] are presented in Figures 1 and2 and in Table 2.

The number of solved functions amounts to 24, 24, 24, 23, 22, 20 out of 24 for dimension 2, 3, 5, 10, 20, 40. Two functions, f3 and f4, seem to become practically unsolvable with increasing dimension. The scaling of the running time (expected number of function evaluations, ERT) with the problem dimension is linear for f1, f5 and f12 and clearly sub-quadratic for most unimodal functions. For the multimodal functions the scaling is typically quadratic, in some cases worse, but never better. Running times to reach the final target function value in 20-D range between D and somewhat above 3 × 10 5 D. They are typically above 300D and below 30 000D.

The failure on f3 for larger dimensions is unexpected and caused by the introduced deformation of the Rastrigin function (see [START_REF] Finck | Real-parameter black-box optimization benchmarking 2009[END_REF][START_REF] Hansen | Real-parameter black-box optimization benchmarking 2009: Noiseless functions definitions[END_REF]). We suspect that a local minimum with a larger attraction basin has been generated, while this seems not to be the case for f15.

Functions f4 and f24 had been designed to be deceptive for evolution strategies. Nevertheless, f24 can be solved, but only with a very large budget of 3 × 10 5 D 2 function evaluations, also due to a small success probability.

SUCCESSFUL POPULATION SIZE

We investigate the population sizes of the final successful runs whenever at least one restart was executed. In Table 3 minimal, median (the larger in case of even data) and maximal population size are given. For the functions not listed, no restarts were necessary in 20-D (with one exception with a single restart in one trial on f9). On all multi-modal functions f15-24 restarts are applied. Functions 20 and 24 require a population size above 1000. Functions 19, 21 and 23 are solved with the largest range of different population sizes.

Table 4 tabulates minimal, median (the larger in case of even data) and maximal initial step-size σ 0 of the final successful runs, whenever σ 0 < 2 in at least one case. Only for functions 23 and 24, the smaller initial step-size appears to be beneficial, while for f22 the data are not conclusive. The multi-modal functions f17, f18 and f20 were never solved with an initially small step-size.

CONCLUSION

The BI-population CMA-ES performs satisfactorily on many functions of the BBOB-2009 testbed and exhibits a reasonable scaling behavior: between linear and quadratic on unimodal functions, between quadratic and cubic on multimodal functions. Yet, it can be considerably outperformed at least (a) on functions that are smooth, "regular" and only moderately ill-conditioned (f1, f5, f8, f9), (b) on separable functions (in particular f3 and f4) and (c) on the multimodal functions f21 and f22. The former two cases are intrinsic and connected to invariance properties of the algorithm, namely (a) invariance to order-preserving transformations of the function value and (b) rotational invariance. Case (c) might be successfully addressed by an improved restart schedule. 1.4 e3 1e-5 15 4.9 e2 4.8 e2 5.0 e2 4.9 e2 15 1.9 e3 1.9 e3 2.0 e3 2.8 e4 1e-1 15 6.9 e3 3.7 e3 1.0 e4 6.9 e3 15 9.0 e4 7.5 e4 1.0 e5 9.0 e4 1e-3 15 1.4 e4 9.6 e3 1.9 e4

1.4 e4 15 1.9 e5 1.5 e5 2.3 e5 1.9 e5 1e-5 15 1.6 e4 1.1 e4 2.

8 Figure 1 :

 81 Figure1: Expected Running Time (ERT, •) to reach fopt + ∆f and median number of function evaluations of successful trials (+), shown for ∆f = 10, 1, 10 -1 , 10 -2 , 10 -3 , 10 -5 , 10 -8 (the exponent is given in the legend of f1 and f24) versus dimension in log-log presentation. The ERT(∆f ) equals to #FEs(∆f ) divided by the number of successful trials, where a trial is successful if fopt + ∆f was surpassed during the trial. The #FEs(∆f ) are the total number of function evaluations while fopt + ∆f was not surpassed during the trial from all respective trials (successful and unsuccessful), and fopt denotes the optimal function value. Crosses (×) indicate the total number of function evaluations #FEs(-∞). Numbers above ERT-symbols indicate the number of successful trials. Annotated numbers on the ordinate are decimal logarithms. Additional grid lines show linear and quadratic scaling.

Figure 2 :

 2 Figure 2: Empirical cumulative distribution functions (ECDFs), plotting the fraction of trials versus running time (left subplots) or versus ∆f (right subplots). The thick red line represents the best achieved results. Left subplots: ECDF of the running time (number of function evaluations), divided by search space dimension D, to fall below fopt + ∆f with ∆f = 10 k , where k is the first value in the legend. Right subplots: ECDF of the best achieved ∆f divided by 10 k (upper left lines in continuation of the left subplot), and best achieved ∆f divided by 10 -8 for running times of D, 10 D, 100 D . . . function evaluations (from right to left cycling blackcyan-magenta). Top row: all results from all functions; second row: separable functions; third row: misc. moderate functions; fourth row: ill-conditioned functions; fifth row: multi-modal functions with adequate structure; last row: multi-modal functions with weak structure. The legends indicate the number of functions that were solved in at least one trial. FEvals denotes number of function evaluations, D and DIM denote search space dimension, and ∆f and Df denote the difference to the optimal function value.

Table 1 :

 1 Update equations for the state variables in the (µ/µw, λ)-CMA-ES with iteration index t = 0, 1, 2, . . . ,

	where p t=0 σ	= p t=0

c

= 0 and C t=0 = I. Here, x i:λ is the i-th best of the solutions x1, . . . , x λ and hσ = 1 if p

Table 3 :

 3 Final population sizes in 20-D, where λ def = 12, when at least one restart was executed

	f	min med max
	7	96	96	96
	13	24	48	96
	15	200	384	768
	16	56	115	384
	17	48	96	192
	18	96	192	192
	19	236 6144 6144
	20 3072 6144 6144
	21	12	101 1678
	22	14	45	202
	23	114	381 1441
	24 2137 4456 4675

Table 4 :

 4 Initial step-size σ 0 of successful restarts in 20-D for functions, where σ 0 < 2 was successful at

	least once	f min	med	max
		15 0.04	2	2
		16 0.066 2	2
		17 1.06	2	2
		19 0.054 2	2
		21 0.044 1.66	2
		22 0.024 0.4	0.6
		23 0.02	0.032 0.1
		24 0.036 0.068 0.166

Table 2 :

 2 Shown are, for a given target difference to the optimal function value ∆f : the number of successful

	D = 5

trials (#); the expected running time to surpass fopt + ∆f (ERT, see Figure

1

); the 10%-tile and 90%-tile of the bootstrap distribution of ERT; the average number of function evaluations in successful trials or, if none was successful, as last entry the median number of function evaluations to reach the best function value (RTsucc). If fopt + ∆f was never reached, figures in italics denote the best achieved ∆f -value of the median trial and the 10% and 90%-tile trial. Furthermore, N denotes the number of trials, and mFE denotes the maximum of number of function evaluations executed in one trial. See Figure

1

for the names of functions.

Acknowledgments

The author would like to acknowledge the great and hard work of the BBOB team with particular kudos to Raymond Ros, Steffen Finck and Anne Auger, and Anne Auger and Marc Schoenauer for their kind and persistent support.


A Diack-Rasselio

O Rouleau

L Coulomb

L Georgeton

M Beaudhuin

J.-C Crivello

E Alleno

Influence of self-substitution on the thermoelectric Fe2VAl Heusler alloy

The microstructure and the thermoelectric properties were systematically determined in the Fe2V1+xAl1-x, Fe2+xVAl1-x, Fe2-xV1+xAl series to investigate the influence of self-substitution on the Fe2VAl Heusler alloy. In the explored range of compositions (-0.1 < x < 0.1), all these series are solid solutions, which form anti-site defects to accommodate the off stoichiometry. They all crystallize in the cubic L21 structure, but their lattice parameter unusually increases with |𝑥|. A Bader analysis based on Density Functional Theory calculations indicates that these uncommon lattice parameter changes arise from variations in the interatomic electron transfer. The antisite defects behave like dopants that control the conduction type and charge carrier concentration. This leads to large thermoelectric power factor (PF) in the Fe2V1+xAl1-x series, which displays the largest electronic mobility. PF = 6.7 mW m -1 K -2 at 250 K and PF = 3.2 mW m -1 K -2 at 325 K are reached in n-type Fe2V1.03Al0.97 and p-type Fe2V0.985Al1.015 respectively. The lattice thermal conductivity systematically decreases upon self-substitution, but with differences among the series which can be traced back to the interatomic electron transfer unveiled by the Bader analysis. Finally, the figure of merit is improved to ZT = 0.06 at 500 K in p-type

1.-Introduction

The increasing need of energy to power devices, factories, homes, and the dwindling of natural resources lead to the search of alternative sources, both reliable and renewable. Among those research paths, the conversion of heat to electricity is interesting. Indeed, heat is ubiquitous in manufacturing plants, cars and is primarily wasted in daily activities. One way to convert this wasted heat to electricity is the use of thermoelectric devices. Thermoelectric devices are used primarily for cooling applications (Peltier effect) [START_REF] Leblanc | Material and manufacturing cost considerations for thermoelectrics[END_REF] and power generation (Seebeck effect) [START_REF] Leblanc | Material and manufacturing cost considerations for thermoelectrics[END_REF][START_REF] Jaziri | A comprehensive review of Thermoelectric Generators: Technologies and common applications[END_REF] but due to their low efficiency, current applications are limited to niche applications, such as powering deep-space missions [START_REF] Yang | High Performance Thermoelectric Materials: Progress and Their Applications[END_REF]. However, their indisputable reliability (free of moving parts) and their compacity compensate their performances. They are envisaged for powering autonomous sensors and actuators [START_REF] Bell | Cooling, Heating, Generating Power, and Recovering Waste Heat with Thermoelectric Systems[END_REF]. To compare and evaluate thermoelectric materials, one uses the dimensionless figure of merit ZT defined by the relation:

𝑍𝑇 =
𝛼 2 𝑇 𝜌 (𝜆 𝑒 + 𝜆 𝐿 ) with ⍺ the Seebeck coefficient, T the temperature, ρ the electrical resistivity, λe and L the electronic and lattice contributions to the total thermal conductivity (𝜆 = 𝜆 𝑒 + 𝜆 𝐿 ). The stateof-the-art thermoelectric material at 300 K is Bi2Te3 with ZT = 1. However, the cost and the toxicity of its constituents prevent its widespread. Fe2VAl is conversely constituted of earthabundant chemical elements and when properly doped [START_REF] Nishino | Thermal and transport properties of the Heusler-type Fe2VAl1-xGex (0 < x < 0.20) alloys: Effect of doping on lattice thermal conductivity, electrical resistivity, and Seebeck coefficient[END_REF], displays a power factor 𝑃𝐹 = 𝛼 2 𝜌 > 5 mW m -1 K -2 , a value larger than that of Bi2Te3. Nonetheless, the thermal conductivity is λ = 29 W m -1 K -1 in pristine Fe2VAl [START_REF] Nishino | Thermal and transport properties of the Heusler-type Fe2VAl1-xGex (0 < x < 0.20) alloys: Effect of doping on lattice thermal conductivity, electrical resistivity, and Seebeck coefficient[END_REF], one order of magnitude larger than in Bi2Te3. Substituting V atom by a heavy element such as Ta introduces mass fluctuations in the crystal, which scatter the heat carrying phonons, decreases the thermal conductivity to λ = 10 W m -1 K - 1 and leads to ZT = 0.2 at 400 K [START_REF] Renard | Thermoelectric properties of the Heusler-type Fe2VTaxAl1-x alloys[END_REF]. This ZT value is still too low for Fe2VAl to be considered in applications. Nanostructuring can provide the additional decrease of thermal conductivity required to improve performances in Fe2VAl [START_REF] Alleno | Review of the Thermoelectric Properties in Nanostructured Fe2VAl[END_REF]. To fully benefit from this effect and avoid spurious decrease of the power factor upon nanostructuring, a prior and detailed knowledge of the dependence of PF on dopant(s) and on charge carrier(s) concentration is a prerequisite.

Several references in the literature have experimentally [START_REF] Matsushita | Pseudogap and transport properties in Fe3-xVxAly x = 0.5-1.05; y = 0.95,1.05[END_REF] [START_REF] Nishino | Transport and magnetic properties of the Heusler-type Fe2-xV1+xAl system (-0.01<=x<=0.08)[END_REF] [10] [START_REF] Sugiura | Doping Effects of Transition Metals on Thermoelectric Properties of Off-Stoichiometric Fe2VAl Alloys[END_REF] and theoretically [START_REF] Bilc | Electronic and thermoelectric properties of Fe2VAl: The role of defects and disorder[END_REF] [13] [START_REF] Berche | Unexpected band gap increase in the Fe2VAl Heusler compound[END_REF] shown the occurrence of VAl (V instead of Al) and AlV (Al instead of V) as "native" antisites defects in stoichiometric Fe2VAl as well as the occurrence of FeV, VFe, FeAl, AlFe antisites defects in off-stoichiometric Fe2VAl. When compared to antisite defects, the vacancies and interstitials defects indeed display too high enthalpies of formation to exist in these alloys [START_REF] Bandaru | Electronic structure of the Heusler compound Fe2VAl and its point defects by ab initio calculations[END_REF]. Depending on their nature, the antisite defects are either electron donors or acceptors and hence strongly influence the electronic transport properties and power factor. Moreover Miyazaki et al. [START_REF] Miyazaki | Thermoelectric properties of Heusler-type off-stoichiometric Fe2V1+ xAl1-x alloys[END_REF] reported a large maximum power factor PFmax = 6.8 mW m -1 K -2 at 300 K in n-type Fe2V1+xAl1-x. We thus decided to re-examine the previous series, both n-and p-type doped and to extend this work to the unknown or nearly unknown Fe2-xV1+xAl and Fe2+xVAl1-x (-0.1 ≤ x ≤ 0.1) series, by comprehensively investigating their microstructural and thermoelectric properties. A theoretical Bader analysis completes this experimental study and provides deep insights on the influence of interatomic electron transfer on the crystal structure and transport properties.

2.-Experimental and theoretical methods

Synthesis

Fe2V1+xAl1-x, Fe2-xV1+xAl and Fe2+xVAl1-x samples (-0.1 < x < 0.1) were prepared by melting adequate quantities of high purity elemental iron (99.97%), vanadium (99.99%) and aluminum (99.98%) in an arc-furnace. To ensure homogeneity, the samples were remelted and flipped over at least four times. Weight losses after melting were less than 0.3%. These samples were subsequently annealed for 72 h at 1173 K in a vacuum-sealed quartz tube and furnace cooled. Disk-shaped samples with 10 mm diameter and ~ 1 mm thickness were cut with a c-BN wheel saw for electrical resistivity and thermal diffusivity measurements. Ten-millimeterlong bar-shaped samples were subsequently cut for Seebeck coefficient measurements, the remaining part was kept for 3ω thermal conductivity measurement. To remove the microstrains that occur upon cutting, polishing, or grinding [START_REF] Maier | Order-disorder transitions in the Fe2VAl Heusler alloy[END_REF], each sample was subsequently annealed under secondary vacuum at 1173 K for 2 h, followed by furnace cooling. For X-ray powder diffraction (XRD), the ground powders were similarly annealed before the measurements.

Microstructural characterization

The samples were structurally characterized by performing powder X-ray diffraction (XRD) on a Bruker D8 diffractometer (Cu-Kα radiation). The lattice parameter of the cubic unit-cell, the line width parameters, the isotropic atomic displacement parameters of these Heusler alloys were refined by the Rietveld method, with the help of the Fullprof program [17].

Microstructural and chemical analyses were carried out by scanning electron microscopy (SEM, Zeiss Merlin) and electron probe micro-analyses (EPMA, Cameca SX100) respectively. The atomic compositions were converted to formula unit by normalizing the total number of atoms to 4. This assumes that no vacancy is considered in these compounds, in agreement with their very large enthalpies of formation (several eV/vacancy) derived from first-principle calculations [START_REF] Bandaru | Electronic structure of the Heusler compound Fe2VAl and its point defects by ab initio calculations[END_REF].

Transport measurements

The Seebeck coefficient and the electrical resistivity were both measured in an argon atmosphere from 150 K to 300 K and from 300 K to 600 K using two home-made apparatus, described in detail in ref. [18] [19]. Thermal diffusivity (a) was measured by the laser flash method using a Netzsch LFA 457 equipment from 300 K to 600 K in an argon atmosphere. The thermal conductivity (λ) was derived using the relationship 𝜆 = 𝑎 × 𝐶 𝑝 × 𝑑 with Cp the heat capacity obtained using the Dulong and Petit's law and d the density measured by Archimedes' method. From 150 K to 300 K, the thermal conductivity was measured by the 3 method [START_REF] Cahill | Thermal-Conductivity Measurement from 30-K to 750-K -the 3-Omega Method[END_REF][START_REF] Beaudhuin | Mesure de la conductivité thermique par la méthode 3-oméga[END_REF] using a cold finger cryostat and an acquisition setup as described in ref. [START_REF] Sinnarasa | Microstructural and transport properties of Mg doped CuFeO2 thin films: A promising material for high accuracy miniaturized temperature sensors based on the Seebeck effect[END_REF]. The uncertainty values on the Seebeck coefficient, the electrical resistivity, and the thermal conductivity are respectively 6%, 8% and 11% [START_REF] Alleno | Invited Article: A round robin test of the uncertainty on the measurement of the thermoelectric dimensionless figure of merit of Co0.97Ni0.03Sb3[END_REF]. In some cases, a discrepancy between the laser-flash and the 3 data smaller than the uncertainty was observed. The latter data were corrected by nullifying the difference at 300 K, with the former data considered as more reliable. The lattice part of the thermal conductivity λL was obtained by subtracting the electronic part λe, related to the electrical resistivity by the Wiedemann-franz law λe = LT/ ρ, with the Lorentz number L = 2.45 × 10 -8 V 2 K -2 .

Calculations details

To model the substitutional chemical disorder in Fe2V1+xAl1-x, large supercell units have been designed based on N = 160 atoms, including nFe = 80, nV = 40 + n and nAl = 40n, with n{0, 1, 2, 3} to describe the 5 compositions from Fe2V0.925Al1.075 to Fe2V1.075Al0.925 with a step of x = 0.025. A special attention was required in the choice of atoms distribution for n = 2 and 3 where several cases were tested and the most stable one (displaying the lowest energy) was considered.

After the supercell generation, a post-calculation was made to estimate volume, heat of formation and electronic charge transfer in the frame of the Density Functional Theory (DFT) [START_REF] Kohn | Self-Consistent Equations Including Exchange and Correlation Effects[END_REF]. The DFT calculations were done using pseudopotential and projector augmented wave (PAW) methods [START_REF] Blöchl | Projector augmented-wave method[END_REF] as implemented in the VASP code [START_REF] Kresse | Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set[END_REF] [START_REF] Kresse | From ultrasoft pseudopotentials to the projector augmented-wave method[END_REF]. The Perdew-Burke-Ernzerhof (PBE) functional [START_REF] Perdew | Generalized Gradient Approximation Made Simple[END_REF] was considered for the exchange-correlation contribution, whereas spin-orbit coupling was left aside. A plane wave basis set with 600 eV as cutoff energy was used in all calculations converging within 0.1 meV in the total energy under a high-density k-meshing (ku  0.05 2/u, with u = a, b or c). For all the compounds, relaxations were performed so that the convergence of Hellmann-Feynman forces was better than 1 meV Å -1 by carefully using separated volume and ionic relaxations in a repetitive steps procedure.

The electronic charge distribution on the atoms was investigated using Bader's topological analysis [START_REF] Bader | Atoms in Molecules: A Quantum Theory[END_REF]. In this approach developed initially for molecules, atomic charges are calculated using the decomposition of electronic charge density into atomic contributions by dividing the space into atomic regions with surfaces at a minimum in the charge density. We have used the "Bader" code developed by Henkelman et al. [START_REF] Henkelman | A fast and robust algorithm for Bader decomposition of charge density[END_REF].

3.-Results and discussions

Microstructure

Fig. 1a-c display back-scattered electron (BSE) images of one sample in each alloy series. The variation of contrast observed across each image is related to differing grain orientations.

The mean grain size, determined by averaging Feret's diameters [START_REF] Hofmann | Chapter 2.5 Stromatoid Morphometrics[END_REF], is 500 ± 100 μm in Fe2V0.95Al1.05 and Fe1.96V1.04Al (Fig. 1a-b), and 250 ± 50 μm in Fe1.92VAl1.08. (Fig. 1c). The smaller grain size in this last sample is most likely related to the position of the polished chunk taken from the melted button, relative to the sole of the arc furnace: the grains are smaller in the button part closer to the water-cooled sole due to a faster cooling rate in this area. Anyway, these grain sizes are large enough to avoid effects on the transport properties. The dark spots can be ascribed to pores and from these images, no secondary phases could be detected. Fig. 1d shows the atomic concentrations measured on 86 randomly selected points on the Fe1.92VAl1.08 sample (nominal composition). The average measured composition is Fe1.90(1)V1.03(3)Al1.07 [START_REF] Jaziri | A comprehensive review of Thermoelectric Generators: Technologies and common applications[END_REF] with a standard deviation from point to point of 0.01 -0.03 mol / f.u.. The complete list of samples, their nominal and EPMA compositions are compiled in Table I. Each sample displays a microprobe composition equal, within uncertainty, to its nominal composition. Fig. 2 presents the XRD patterns of all the samples in the Fe2V1+xAl1-x, Fe2+xVAl1-x, Fe2-xV1+xAl series. Every line could be indexed within the L21 structure type (space group Fm-3m) and no extra line that could have arisen from a secondary phase could be detected. The 111 and 200 lines are well defined on every pattern and characteristic of the L21 order [START_REF] Maier | Order-disorder transitions in the Fe2VAl Heusler alloy[END_REF]. In shows the good quality of the fit (Rwp = 1.9% and RB = 14.1%) and confirms that these compositions crystallize in the L21 structure.

The evolution of the refined lattice parameter as a function of composition (-0.1 < x < 0.1) for all three series is displayed in Fig. 3. In Fe2V1+xAl1-x (Fig. 3a), the lattice parameter increases linearly with the absolute value of x, and two Vegard's laws are thus observed, one for each sign of x, with a minimum value amin = 5.7622 ± 6 × 10 -4 Å at x = -0.01. This shift from x = 0.00 does not indicate that Fe2V1.01Al0.99 rather than Fe2VAl displays the minimum lattice parameter in the series. It probably rather arises from a systematic deficit of aluminum in these samples due to partial oxidation, which remained undetected by EPMA because it is of the order of its uncertainty (~ 0.01). The linear evolutions of the lattice parameter indicate that Fe2V1+xAl1-x with -0.1 < x < 0.1 is a solid solution where the deviation from stoichiometry is accommodated by the formation of AlV or VAl antisites defects. This is in good agreement with the literature on this series [START_REF] Miyazaki | Thermoelectric properties of Heusler-type off-stoichiometric Fe2V1+ xAl1-x alloys[END_REF] and moreover a(x) can be linearly extrapolated to the binary alloys FeAl (x = -1) [START_REF] Mondal | Electronic structure of FeAl alloy studied by resonant photoemission spectroscopy and Ab initio calculations[END_REF] and quenched FeV (x = +1) [START_REF] Seki | Metastable order-disorder transition and sigma phase formation in Fe-V binary alloys[END_REF], both crystallizing in the disordered B2 structure.

Nonetheless, this non-monotonous variation with x cannot be straightforwardly explained by simple arguments: for instance, the difference of atomic radii between V (135 pm) and Al (125 pm) [34] or the valence electron count both evolve monotonously with x. Although the volume increase for x > 0 could be easily understood by the geometric criterion, the increase for the Al-richer composition, x < 0, is not. To better understand this counter intuitive behavior, we carried out first principles calculations and a Bader analysis, as described in the 2.4 methodology section [START_REF] Henkelman | A fast and robust algorithm for Bader decomposition of charge density[END_REF]. This approach partitions the space into volumes to weigh the contribution of each atom to the bonding. Each Bader volume contains a single charge density maximum and is separated from other volumes by surfaces on which the charge density is a minimum normal to these surfaces [START_REF] Tang | A grid-based Bader analysis algorithm without lattice bias[END_REF][START_REF] Lepetit | Topological analysis of the metalmetal bond: A tutorial review[END_REF]. The Bader volumes and charges arising from the present analysis are centered on the atomic nuclei. Figure 4.a compares the cell parameter from theoretical results with the experiments in Fe2V1+xAl1-x. The absolute theoretical and experimental values do not agree due to the underestimation of the actual unit-cell volume using GGA-PBE approximation. However, the relative experimental variation rate of a(x) for x < 0 is nearly quantitatively represented by the theory, whereas a(x) for x > 0 is not described quantitatively but qualitatively, the experimental slope being underestimated for x > 0. Theory also confirms that the x = 0 composition displays the minimum lattice parameter, in agreement with the experiment. These increases of a with |𝑥| can be related to the variations of the atomic Bader volumes (Fig. 4 b). For x < 0, it can be noticed that both the Fe and Al volumes increase with |𝑥|, while for x > 0, only the Al volume increases. These variations of the Bader atomic volumes can be related to the variations with x of the Bader charge displayed in Fig. 4b. Before commenting the variations with x, it is necessary to interpret the value and sign of the Bader charge (q) for each atom at x = 0. Both Al and V display a positive charge (+1.8 and +0.8 respectively) while Fe displays a negative charge (-1.3). Since 2𝑞 𝐹𝑒 + 𝑞 𝑉 + 𝑞 𝐴𝑙 = 0 for any x, this means that a "net transfer" of part of the Al and V electron towards Fe occurs. This net transfer is only partial because 𝑞 𝐴𝑙 ≠ +3, 𝑞 𝑉 ≠ +5 and 𝑞 𝐹𝑒 ≠ -4, the valence of Al and V and the number of empty 3d states in Fe, respectively. Fe2VAl can thus be understood as a partially ionic or "charge transfer" compound with the effective formula 𝐹𝑒 2 1.3-𝑉 0.8+ 𝐴𝑙 1.8+ , where V and Al behave like cations and Fe like an anion. This electron transfer is explained by the progressive 3d-Fe bands filling from the electrons of cations, leading to a more stable electronic structure for the compound. This scheme disagrees with the scheme 𝐹𝑒 2 1-𝑉 1-𝐴𝑙 3+

proposed in ref. [START_REF] Anand | Thermoelectric transport of semiconductor full-Heusler VFe2Al[END_REF], which was based on simpler electronegativity considerations. It agrees with the Bader analysis [START_REF] Bende | Covalence and Ionicity in MgAgAs-Type Compounds[END_REF] performed in the half-Heusler Li 1+ Al 1+ Si 2-or Li 1+ Al 1+ Ge 2- compounds, where both most electropositive atoms transfer part of their electrons to the most electronegative one. More importantly, it agrees well with the interatomic charge transfers reported in ref. [START_REF] Hinterleitner | The electronic pseudo band gap states and electronic transport of the full-Heusler compound Fe2VAl[END_REF] for Fe2VAl, where 𝐹𝑒 2 0.75-𝑉 0.5+ 𝐴𝑙 1.0+ was derived from a similar Bader analysis. For x < 0 and upon increasing |𝑥|, the Bader charge of Fe and Al decreases or becomes more negative, while the charge of V increases or becomes more positive, indicating a stronger electron transfer from the latter atom towards the two former atoms. This leads to the expansion of the Bader volume of Fe and Al due to their larger electron population. For increasing x > 0, as already mentioned, these calculations only capture the decrease of the Al charge and misses the decrease of the charge of either the Fe or V atom. We can nonetheless surmise that the electron transfer from the Al atom to either Fe, V or both atoms, leads to their volume expansion and to the increase of a(x). To summarize, these variations of the lattice parameter in Fe2V1+xAl1-x can be explained by varying electron transfers with x, between the constituting atoms.

Figures 3c and3b display the lattice parameters for the alloy series Fe2-xV1+xAl and Fe2+xVAl1-x respectively. In the case of Fe2-xV1+xAl, a Vegard's law is obvious for x ≥ 0. It becomes apparent for x ≤ 0 when considering values of |𝑥| up to 0.4 (see inset of Fig. 3c).

Nishino et al. presented a similar report on the evolution of the lattice parameter in Fe2-xV1+xAl

for -1 ≤ x ≤ 0.2 [START_REF] Nishino | Phase stability of Fe3Al with addition of 3d transition elements[END_REF]. For Fe2+xVAl1-x, two Vegard's laws are also observed for x ≥ 0 and x ≤ 0.

These two series hence follow a solid solution behavior, at least for -0.1 < x < 0.1. Again, the deviation from stoichiometry is accommodated in these series by the formation of antisite defects such as AlFe, FeAl, FeV or VFe. Similarly, to the first series, a minimum value is also observed close to x = 0 in Fe2-xV1+xAl and Fe2+xVAl1-x. Nonetheless, it is difficult to determine accurately its x-position due an insufficient number of data points in this neighborhood.

Currently, the best estimation is amin = 5.7633 ± 6 × 10 -4 Å at x = 0 for both series, in good agreement with the minimum value derived from the Fe2V1+xAl1-x series. Nonetheless, a systematic elemental deficit cannot currently be detected from the a(x) data in Fe2+xVAl1-x.

Following the Bader analysis of Fe2V1+xAl1-x, the evolutions of the lattice parameters in Fe2+xVAl1-x and Fe2-xV1+xAl for each sign of x can most probably be ascribed to variations in the charge transfers between the constituting atoms. As will be further discussed, the antisite defects formed in these three series can modify the electronic transport properties of these alloys.

3.2 Electronic transport properties

Electrical properties at room temperature

The values of carrier concentrations, carrier mobilities, Seebeck coefficient, resistivity and power factor measured at 300 K in Fe2V1+xAl1-x, Fe2+xVAl1-x and Fe2-xV1+xAl are presented in Table I and II, respectively. In agreement with the literature [START_REF] Nishino | Effect of off stoichiometry on the transport properties of the Heusler type Fe2VAl compound[END_REF] [10] [START_REF] Garmroudi | Boosting the thermoelectric performance of Fe2VAl Heusler compounds by band engineering[END_REF], pristine Fe2VAl displays a p-type conduction with a concentration of 3.9 × 10 20 holes cm -3 as majority charge carriers. Upon self-substitution in Fe2V1+xAl1-x, as expected [START_REF] Miyazaki | Thermoelectric properties of Heusler-type off-stoichiometric Fe2V1+ xAl1-x alloys[END_REF], the formation of AlV defects in Al-rich compositions (x < 0) leads to p-type conduction whereas the formation of VAl counterpart defects in V-rich compositions (x > 0) leads to n-type conduction. We previously discussed that in pristine Fe2VAl, the formation of few percent of combined AlV -VAl antisite defects ("inversions") leads to the observed hole concentration at 300 K [START_REF] Noutack | Numerical and experimental determination of the thermal conductivity of pristine and substituted Fe2VAl[END_REF]. Similarly, FeV, AlFe antisite defects and VFe, FeAl as their counterparts are presently shown to give rise to pand n-type conduction in Fe2-xV1+xAl and Fe2+xVAl1-x, respectively. The antisite defects formed in these three series hence behave either as electron acceptors or electron donors and control the electronic transport properties. As previously discussed in the Bader analysis, a stronger electron transfer from the V atom towards the Al atom occurs in Fe2V1+xAl1-x for x < 0 and it thus accompanies the electron acceptor character of the AlV defects. Similarly, a stronger electron transfer towards the V atom occurs for x > 0, when VAl defects behave as electron donor. This is in line with atom-projected density of states (p-DOS) calculations in Fe2VAl [START_REF] Maier | Order-disorder transitions in the Fe2VAl Heusler alloy[END_REF] [37] that shows that V and Fe eg states contribute strongly to the conduction band.

In Table II It can also be noticed in Table I that for every series, the electronic mobility is three-to four-time larger in p-type compositions than in their n-type counterpart. For instance, it is in the range 25 -40 cm 2 V -1 s -1 for p-type Fe2V1+xAl1-x while it is in the range 7 -12 cm 2 V -1 s -1

for n-type Fe2V1+xAl1-x. When comparing compositions with similar electron and hole concentration, a ratio 𝜇 𝑝 𝜇 𝑛 = 3.6 can be derived. Since this feature is also effective at least in the other Fe2+xVAl1-x series, it is independent on the nature of the dopant and is very likely to arise from the band structure of Fe2VAl e.g., a smaller effective mass for the holes than the electrons.

When comparing the 3 series between each other, for a given type of conduction, the electronic mobility is many-fold larger in Fe2V1+xAl1-x than in Fe2-xV1+xAl and Fe2+xVAl1-x. The reduced mobility in the last two series is related to the occurrence of FeV, AlFe, VFe, FeAl defects, which either modify the electronic structure or scatter more strongly the charge carriers than the AlV or VAl defects. Based on DFT calculations [START_REF] Bilc | Electronic and thermoelectric properties of Fe2VAl: The role of defects and disorder[END_REF][START_REF] Bandaru | Electronic structure of the Heusler compound Fe2VAl and its point defects by ab initio calculations[END_REF], FeV FeAl and VFe have been reported to be magnetic defects, whereas VAl has been reported to be non-magnetic. The magnetic character of the former defects may enhance their scattering cross-section of the charge carriers, leading to a reduced mobility. The VFe and FeAl defects have also been predicted [START_REF] Bilc | Electronic and thermoelectric properties of Fe2VAl: The role of defects and disorder[END_REF] to modify the electronic structure by inducing new in-gap states close to the conduction and valence bands.

These states could act as charge carrier scatterers of the holes or electrons transported in the main valence and conduction bands states. Magnetic defects and / or new in-gap states are the two scenarios that could explain the reduced electronic mobility in Fe2-xV1+xAl and Fe2+xVAl1-x.

It is easily noticeable that the larger observed values of mobility in the Fe2V1+xAl1-x series than in the Fe2-xV1+xAl and Fe2+xVAl1-x series (Table I) lead systematically to smaller values of resistivity in the former series than in the latter (Table II). Remarkably, in Fe2V1+xAl1-x,  is always smaller than 2.5  m and 5  m in p-and n-type compounds respectively. This leads to large values of PF in (Table II) in Fe2V1+xAl1-x. For Fe2-xV1+xAl and Fe2+xVAl1-x, irrespective of their conduction type, values of PF do not exceed 1.6 mW m -1 K -2 whereas a value as large as PF = 5.8 mW m -1 K -2 is observed in n-type Fe2V1+xAl1-x. Measurements as a function of temperature will confirm that the latter series presents better thermoelectric properties than the others. When comparing n-type with p-type Fe2V1+xAl1-x, the previously unveiled correlation between  and PF does not apply anymore: despite larger mobility values in p-type Fe2V1+xAl1-x, only a smaller value of PF = 3.2 mW m -1 K -2 is obtained in p-type Fe2V0.985Al1.015.

Since the power factor is not optimized for any conduction type, it is difficult to draw a definitive conclusion on this difference, but it is likely to be related to electrons displaying a larger effective mass than holes.

Evolution of the electrical properties with temperature

The Seebeck coefficient, resistivity and power factor measured between 100 K and 600 K are displayed as a function of temperature in Fig. 5, 6, 7 and 8 for Fe2V1+xAl1-x, Fe2-xV1+xAl and Fe2+xVAl1-x respectively. In the Fe2V1+xAl1-x series, the electrical resistivity (Fig. 5b,6b) goes through a maximum in the temperature range 300 K -600 K in both p-type or n-type compounds. This behavior is characteristic of degenerate semi-conductors: at temperatures smaller than the maximum their metal-like electrical transport is dominated by the electrons (holes) with their chemical potential in the conduction (valence) band(s) and at temperature larger than the maximum, their semiconducting-like behavior is dominated by the minority carriers excited across the gap. Similarly, the Seebeck coefficient (Fig. 5a, 6a) displays a maximum or a minimum in p-type or n-type Fe2V1+xAl1-x compositions respectively. These extrema fall in the range [270 K -520 K] and are shifted by roughly -100 K when compared to the corresponding electrical resistivity maximum. This point has been discussed in Co1-xNixSb3

by Kajikawa [START_REF] Kajikawa | Multi-band analysis of thermoelectric properties of n-type Co1-xNixSb3 (0<x<0.01) over a wide temperature range of 10-773 K[END_REF] who ascribed it to the occurrence of several bands for the minority carriers, all contributing to the electrical conductivity and the Seebeck coefficient, but at different temperatures due to differing mobilities in the bands. Again, these variations are typical of degenerate semiconductors entering the intrinsic regime at high temperature. Consequently, depending on composition, the power factor (Fig. 5c,6c) shows a maximum between 250 K and 500 K. It reaches PFmax = 6.7 mW m -1 K -2 and PFmax = 3.2 mW m -1 K -2 in n-type Fe2V1.03Al0.97 at 250 K and in p-type Fe2V0.985Al1.015 at 325 K respectively. The present n-type maximum power factor is as large as the one reported in ref. [START_REF] Miyazaki | Thermoelectric properties of Heusler-type off-stoichiometric Fe2V1+ xAl1-x alloys[END_REF] for Fe2V1+xAl1-x, whereas the maximum p-type power factor is slightly smaller. This confirms anyway that PFmax is larger in Fe2VAl than in Bi2Te3.

In the Fe2-xV1+xAl series, the electrical resistivity (Fig. 7b) shows an activated behavior for both types of conduction in the entire measured temperature range. When compared to the Fe2V1+xAl1-x series which is degenerate for the present x values, the activated behavior most likely arises from a deeper donor (acceptor) level(s) in the n-type (p-type) compounds of the Fe2-xV1+xAl series. This scenario is supported by electron concentration versus temperature data derived from Hall effect and presented in Fig. S2. The electron concentration shows an activated behavior in Fe1.92V1.08Al whereas it is weakly temperature dependent in Fe2V1.03Al0.97 as expected in a degenerate semi-conductor. The larger values of electrical resistivity for the ntype compositions than the p-type ones could be ascribed to a donor level deeper than the acceptor level. At temperatures larger than 400 K, the electrical resistivity values for all the samples converge on a common curve, a feature characteristic of a common regime e.g., the intrinsic regime. The variations of the Seebeck coefficient with temperature (Fig. 7a) are also consistent for both types of conduction with this picture of extrinsic semi-conductors at "low" temperature, entering the intrinsic regime at "high" temperature. The Seebeck coefficient indeed displays a maximum or a minimum in the range [250 K-350 K] in p-type or n-type Fe2-xV1+xAl compositions respectively. Again, at temperature smaller than the extremum, transport is dominated by the majority carriers whereas at temperatures larger than the extremum, the minority carriers excited across the gap dominate transport. The power factor varies with temperature in accordance with the Seebeck coefficient: it displays a maximum between 250 K and 350 K. The best maximum power factor value is observed in p-type Fe2.04V0.96Al where it reaches PFmax = 1.7 mW m -1 K -2 . The better p-type than n-type power factor can this time be related to the larger electronic mobility for the former type of conduction than for the latter.

Finally, in the Fe2+xVAl1-x series, the electronic transport (Fig. 8) shows great similarity with the Fe2-xV1+xAl series. The electrical resistivity (Fig. 8.b) is also activated in both n-and p-type samples in the entire temperature range 120 K -600 K, it converges towards common values above 400 K and the Seebeck coefficient (Fig. 8.a) exhibits an extremum between 250 K and 300 K. Again, these variations of the electrical resistivity and the Seebeck coefficient are characteristic of extrinsic semi-conductors at temperature below 250 K -300 K, entering the intrinsic regime at higher temperatures. The best power factor value is obtained in n-type Fe2.08VAl0.92 at 300 K where PFmax = 1.56 mW m -1 K -2 is reached. This value is significantly smaller than those reached in n-type Fe2V1+xAl1-x. due to an overall larger electronic mobility in the latter series.

Thermal conductivity and ZT

The lattice thermal conductivity (L) for all three series is plotted in Fig. 9. In each sample, this quantity decreases monotonously with temperature, due to the increasing phononphonon interaction. Among all the sample, Fe2VAl displays the largest values with L = 26 W m -1 K -1 at 300 K, in agreement with previous studies [START_REF] Nishino | Thermal and transport properties of the Heusler-type Fe2VAl1-xGex (0 < x < 0.20) alloys: Effect of doping on lattice thermal conductivity, electrical resistivity, and Seebeck coefficient[END_REF]. The off-stoichiometric compositions systematically display smaller values than in Fe2VAl, and for a given sign of x, in all three series, L decreases with increasing |𝑥|. This arises from the scattering of phonons by the masses and interatomic force constants (IFCs) fluctuations introduced by the self-substitutions.

Theory [START_REF] Katcho | Effect of nitrogen and vacancy defects on the thermal conductivity of diamond: An ab initio Green's function approach[END_REF] allows to formulate explicitly both contributions: the perturbation term to the dynamic Hamiltonian can be written as 𝑉 = -

∆𝑚 𝑖 𝑚 𝑖 𝜔 2 + ∆𝑘 𝑖𝑗 √ 𝑚 𝑖 𝑚 𝑗
where mi and kij refers to the unperturbed mass of atom in site i and the IFCs between site i and j respectively. mi and kij refer to the difference between the perturbed and the unperturbed mass and IFCs respectively.

On the one hand, in the Fe2V1+xAl1-x series, L varies from sample to sample in accordance with their departure from stoichiometry (|𝑥|), regardless of the sign of x: the x = ±0.03 and the x = ±0.07 display very close values of L on broad ranges of temperature. This means that the inequivalent modifications of the IFCs arising from excess Al or excess V weakly affect the lattice thermal conductivity and the mass term, which is symmetric with both Al or V excesses, dominates the perturbation Hamiltonian for this series. In a recent article [START_REF] Noutack | Numerical and experimental determination of the thermal conductivity of pristine and substituted Fe2VAl[END_REF], it has also been shown theoretically and experimentally that in Fe2V1-xTaxAl1-xSnx where similarly to Fe2V1+xAl1-x only the V and Al sites are substituted, the mass term dominates over the IFCs contribution to the perturbation. On the other hand, in the Fe2-xV1+xAl and Fe2+xVAl1-x series, L depends on the sign of x and is smaller when Fe is in excess, rather than V or Al. This implies that the IFCs or "chemical bonding strength" are more perturbed when Fe substitutes V or Al than the opposite situations. It can be surmised that this specific effect of Fe on L could be related to the effective formula 𝐹𝑒 2 1.3-𝑉 0.8+ 𝐴𝑙 1.8+ derived from the present Bader analysis.

Indeed, Fe behaves in Fe2VAl like an anion, whereas V and Al behave like cations. Exchanging

V and Al e.g. two cations most likely affects less strongly the chemical bonds or IFCs than exchanging an anion with a cation. Despite these differing behaviors with x among the three series, the smallest values of L reached for x = ±0.08 in every series are very close to 13 W m -1 K -1 at 300 K, regardless of the series. This value is too large to ensure large figures of merit in these compositions, as will be discussed in the next part.

The dimensionless figure of merit (ZT) is plotted as a function of temperature in Fig. 10 for Fe2V1+xAl1-x and in Fig. 11

Fig. S1 (

 S1 Fig. S1 (Supplementary Material), a typical example of Rietveld refinement in nominal Fe2VAl

  figures of merit ZTmax = 0.06 at 500 K in p-type Fe2V0.93Al1.07 and ZTmax = 0.15 at 450 K in n-

Figure 1 .

 1 Figure 1. Back-scattered electron images of 3 samples: (a) Fe2V0.95Al1.05, (b) Fe1.96V1.04Al, (c) Fe1.92VAl1.08 (nominal composition); (d) Fe, V, Al atomic percentage as a function of electronic microprobe (EPMA) position for Fe1.92VAl1.08.

Figure 3 .

 3 Figure 3. Evolution of lattice parameters as a function of x in (a) Fe2V1+xAl1-x, (b) Fe2+xVAl1-x and (c) Fe2-xV1+xAl alloy series. The lines are linear fits to the data.

Figure 4 .

 4 Figure 4. Evolution as a function of x in Fe2V1+xAl1-x of (a) the experimental and calculated lattice parameters, (b) Bader volumes of Fe, V and Al and (c) electronic charge of Fe, V and Al. For a given graph, there is no change of scale across the vertical axis.

Figure 5 .

 5 Figure 5. Seebeck coefficient (a), resistivity (b) and power factor (c) in n-type Fe2V1+xAl1-x alloys between 120 K -600 K.

Figure 6 .

 6 Figure 6. Seebeck coefficient (a), resistivity (b) and power factor (c) in p-type Fe2V1+xAl1-x alloys between 120 K -600 K.

Figure 7 :

 7 Figure 7: Seebeck coefficient (a), resistivity (b) and power factor (c) in p-type and n-type Fe2+xVAl1-x alloys between 120 K -600 K.

Figure 8 .

 8 Figure 8. Seebeck coefficient (a), resistivity (b) and power factor (c) in p-type and n-type Fe2-xV1+xAl alloys between 120 K -600 K.

Figure 9 .

 9 Figure 9. Lattice thermal conductivity versus temperature between 120 K -600 K in Fe2V1+xAl1-x (a), Fe2-xV1+xAl (b) and Fe2+xVAl1-x (c) alloys.

Figure 10 .

 10 Figure 10. Dimensionless figure of merit versus temperature in Fe2V1+xAl1-x (a) p-type and (b) n-type alloys between 120 K -600 K.

Figure 11 .

 11 Figure 11. Dimensionless figure of merit versus temperature in (a) Fe2-xVAl1+x and (b) Fe2+xV1+xAl alloys between 120 K -600 K.

  V K -1 in n-type samples. For both types,  and  vary according to x and p or n: except Fe2VAl, the samples with the compositions the closest to the stoichiometry display the largest absolute value of the Seebeck coefficient and resistivity and the smallest charge carrier

	, when comparing the Fe2V1+xAl1-x, Fe2-xV1+xAl and Fe2+xVAl1-x series, the
	Seebeck coefficient reaches the remarkable values of +93.2 V K -1 in p-type samples
	and -151.6

concentration, whereas the most off-stoichiometric samples display the smallest values of  and  and the largest values of p or n.

Table I :

 I Nominal compositions, EPMA compositions, charge carrier concentrations, Hall mobilities in the alloy series Fe2V1+xAl1-x, Fe2+xVAl1-x, Fe2-xV1+xAl at 300 K. Negative carrier concentrations correspond to electron as majority carriers.

	Nom. Comp.	EPMA Comp.	n / p (10 20 cm -3 )  (cm 2 .V -1 .s -1 )
	Fe2V0.93Al1.07	Fe2.00(1)V0.93(1)Al1.07(1)	22.4	25.3
	Fe2V0.95Al1.05	Fe2.00(1)V0.96(1)Al1.04(1)	16.9	30.6
	Fe2V0.97Al1.03	Fe1.99(1)V0.98(1)Al1.03(1)	11.7	40.2
	Fe2V0.985Al1.015	Fe1.99(1)V1.00(1)Al1.01(1)	6.97	35.8
	Fe2VAl	Fe2.00(1)V1.01(1)Al0.99(1)	3.90	25.8
	Fe2V1.02Al0.98	Fe1.97(1)V1.04(2)Al0.99(1)	-11.4	11.5
	Fe2V1.03Al0.97	Fe2.00(1)V1.04(1)Al0.96(1)	-15.3	10.4
	Fe2V1.08Al0.92	Fe1.99(1)V1.08(1)Al0.93(1)	-37.4	7.7
	Fe1.92V1.08Al	Fe1.92(1)V1.09(1)Al0.99(1)	-41.5	1.0
	Fe1.95V1.05Al	Fe1.93(2)V1.07(2)Al1.00(1)	-39.9	1.1
	Fe1.96V1.04Al	Fe1.95(1)V1.05(1)Al1.00(1)	-34.8	1.5
	Fe2.04V0.96Al	Fe2.05(1)V0.95(2)Al1.00(2)	5.40	22.0
	Fe2.08V0.92Al	Fe2.08(1)V0.92(1)Al1.00(1)	7.35	13.4
	Fe1.92VAl1.08	Fe1.90(1)V1.03(3)Al1.07(2)	11.3	5.6
	Fe1.95VAl1.05	Fe1.92(3)V1.02(5)Al1.05(5)	-	-
	Fe2.04VAl0.96	Fe2.03(2)V1.01(2)Al0.96(1)	12.2	6.3
	Fe2.08VAl0.92	Fe2.07(1)V1.01(1)Al0.92(1)	-34.6	2.4

Table II :

 II Seebeck coefficients, electrical resistivities and power factors (PF) in the alloy series Fe2+xVAl1-x, Fe2V1+xAl1-x, Fe2-xV1+xAl at 300 K.

	Nom. composition	 (V/K)	 (.m)	PF (mW.m -1 .K -2 )
	Fe2V0.93Al1.07	38.4	1.1	1.33
	Fe2V0.95Al1.05	49.8	1.21	2.05
	Fe2V0.97Al1.03	60.77	1.33	2.78
	Fe2V0.985Al1.015	89.5	2.5	3.20
	Fe2VAl	84.7	5.8	1.24
	Fe2V1.02Al0.98	-146.6	4.76	4.52
	Fe2V1.03Al0.97	-151.6	3.94	5.84
	Fe2V1.08Al0.92	-110.1	2.18	5.57
	Fe1.92V1.08Al	-101.1	15.42	0.66
	Fe1.95V1.05Al		13.79
	Fe1.96V1.04Al	-4.2	12.26	0.09
	Fe2.04V0.96Al	92.3	5.26	1.61
	Fe2.08V0.92Al	79.0	6.33	0.98
	Fe1.92VAl1.08	93.2	9.87	0.88
	Fe1.95VAl1.05		13.17
	Fe2.04VAl0.96	2.9	8.06	0.001
	Fe2.08VAl0.92	-108.7	7.59	1.56

Acknowledgments

ICGM would like to thank C. Riebel, A. Viera e Silva, F. Pichot and J.-M. Peyris for their technical support. Funding of this work by the "Agence Nationale de la Recherche" through the contract ''LoCoThermH'' (Project ANR-18-CE05-0013-01) is also acknowledged.


Nikolaus Hansen
email: nikolaus.hansen@inria.fr

Benchmarking the Nelder-Mead Downhill Simplex Algorithm With Many Local Restarts

Keywords: G.1.6 [Numerical Analysis]: Optimization-global optimization, unconstrained optimization; F.2.1 [Analysis of Algorithms and Problem Complexity]: Numerical Algorithms and Problems Benchmarking, Black-box optimization, Evolutionary computation, Simplex downhill

We benchmark the Nelder-Mead downhill simplex method on the noisefree BBOB-2009 testbed. A multistart strategy is applied on two levels. On a local level, at least ten restarts are conducted with a small number of iterations and reshaped simplex. On the global level independent restarts are launched until 10 5 D function evaluations are exceeded, for dimension D ≥ 20 ten times less. For low search space dimensions the algorithm shows very good results on many functions. It solves 24, 18, 11 and 7 of 24 functions in 2, 5, 10 and 40-D.

INTRODUCTION

The Nelder-Mead method [START_REF] Nelder | The downhill simplex method[END_REF] is a real-parameter blackbox optimization method that operates, similar to many evolutionary algorithms, on a set of solution points using only the ranking of solution. The latter implies that the algorithm is invariant under order-preserving transformations of the objective function values. The Nelder-Mead algorithm is independent of the choice of coordinate system and therefore exhibits more attractive invariance properties. In contrast to most evolutionary algorithms, the Nelder-Mead algorithm does not solely resort to selection for improving

THE ALGORITHM

The Nelder-Mead method [START_REF] Nelder | The downhill simplex method[END_REF] operates on a set of D + 1 solution points, a simplex, where D is the search space dimension. Generally, a new solution is constructed by reflecting the worst solution on the center of the remaining D solutions. Depending on the quality of the new solution additional operations are performed, but details are omitted here. For solving global optimization problems sophisticated restart procedures have been proposed for example in [START_REF] Luersen | Globalized Nelder-Mead method for engineering optimization[END_REF]. In this paper, a few different restart mechanism are used.

1. local restarts, where the recent best solution is used as initial solution for the restart and the projection of the range of the recent simplex is used for initialization of the new simplex. The default initialization procedure is applied, which places new simplex points by changing one coordinate at a time. At least ten restarts are conducted and the maximum number of iterations is 200 × √ D for all but the last. This number is as small that even on the sphere function f1 usually some local restarts are conducted.

2. local restarts as above, where some additional perturbation is added to the simplex.

3. global restarts, which are completely independent of previous results.

The applied reshaping exploits the given coordinate system and improves the local search abitities for D ≥ 10 on functions with comparatively low parameter dependencies. It is also effective on the Rosenbrock function in moderate dimension. All details are given in Figure 1 and in the next sections.

PARAMETER TUNING

Exemplary online experiments on f2 and f8 have been conducted to verify reasonable constants for the maximum iteration number of local restarts (constant 200 in Figure 1) and the number of local restarts (constants 10 and 0.1). The chosen dependencies on D have not been verified. We added add-hoc termination criteria, where TolX turned out to be useful. At most between 10 5 D and 2 × 10 5 D function evaluations are conducted (input parameter maxfunevals was set to 10 5 D), for D ≥ 20 ten times less. The final parameter setting were identical on all functions and therefore the crafting effort [START_REF] Hansen | Real-parameter black-box optimization benchmarking[END_REF] is CrE = 0.

METHODS

We have used the matlab function fminsearch, Revision 1.21.4.7, and made the variable usual_delta an additional input parameter. Onto this algorithm we have applied a multistart strategy as given in Figure 1. This procedure has been benchmarked on the noiseless BBOB-2009 testbed [START_REF] Finck | Real-parameter black-box optimization benchmarking 2009[END_REF][START_REF] Hansen | Real-parameter black-box optimization benchmarking 2009: Noiseless functions definitions[END_REF] according to the experimental design from [START_REF] Hansen | Real-parameter black-box optimization benchmarking[END_REF].

The initial solution from which the first simplex is constructed was chosen uniformely distributed in [START_REF] Luersen | Globalized Nelder-Mead method for engineering optimization[END_REF][START_REF] Luersen | Globalized Nelder-Mead method for engineering optimization[END_REF] D or as the former best solution.

CPU TIMING EXPERIMENT

For the timing experiment the same multistart algorithm was run on f8 and restarted until at least 30 seconds had passed (according to Figure 2 in [START_REF] Hansen | Real-parameter black-box optimization benchmarking[END_REF]). These experiments have been conducted with an Intel dual core T5600 processor with 1.8 GHz under Linux 2.6.27-11 using Matlab R2008a. The results were 6.2; 5.8; 5.6; 5.7; 5.8; 5.9 and 6.3 × 10 -4 seconds per function evaluation in dimension 2; 3; 5; 10; 20; 40 and 80, respectively. Up to 80-D a dependency of CPU time on the search space dimensionality is hardly visible.

RESULTS AND DISCUSSION

The results are presented in Table 1 and Figures 2 and3. The method solves 24, 23, 18, 11, 8 and 7 out of 24 functions in 2, 3, 5, 10, 20 and 40-D (Figure 2). The expected number of function evaluations to reach a given target function value scales often quadratically with the dimension on unimodal functions and on functions 21 and 22 (Figure 2). The scaling is remarably better only on f2 in larger dimension, presumably due to the used simplex reshaping. The scaling is often worse than quadratical, not only but in particular on multi-modal functions, and the algorithm fails within the given budget for larger dimension.

Figure 3 reveals the algorithms main weaknesses on the multimodal functions 15-19. These multimodal functions have a large number of optima and an independent multistart algorithm cannot discover the overall function structure. The performance is also poor in larger dimension in particular on the ill-conditioned functions 10-14. In contrast, the performance is very good on the low dimensional ill-conditioned functions.

CONCLUSION

The Nelder-Mead algorithm, as implemented in Matlab, equipped with an additional input vector and applied in a multistart fashion, is a fast and reliable black-box search algorithm for low dimensional search spaces. The applied reshaping of the simplex extends its efficiency to larger dimension only for unimodal functions with little dependencies between variables. The multiple independent restarts allow to searching unstructured multi-modal landscapes comparatively effective, while a global topography within a multimodal or rugged landscape is not well exploited. 15 2.9 e2 2.7 e1 5.5 e2 2.9 e2 15 1.5 e4 5.5 e3 2.5 e4 1.5 e4 1 15 3.7 e4 2.5 e4 4.9 e4 3.7 e4 0 62e-1 45e-1 77e-1 1.0 e5 1e-1 13 2.6 e5 1.9 e5

Figure 1 :

 1 Figure 1: Multistart procedure of Nelder-Mead in Matlab

Figure 2 :

 2 Figure2: Expected Running Time (ERT, •) to reach fopt + ∆f and median number of function evaluations of successful trials (+), shown for ∆f = 10, 1, 10 -1 , 10 -2 , 10 -3 , 10 -5 , 10 -8 (the exponent is given in the legend of f1 and f24) versus dimension in log-log presentation. The ERT(∆f ) equals to #FEs(∆f ) divided by the number of successful trials, where a trial is successful if fopt + ∆f was surpassed during the trial. The #FEs(∆f ) are the total number of function evaluations while fopt + ∆f was not surpassed during the trial from all respective trials (successful and unsuccessful), and fopt denotes the optimal function value. Crosses (×) indicate the total number of function evaluations #FEs(-∞). Numbers above ERT-symbols indicate the number of successful trials. Annotated numbers on the ordinate are decimal logarithms. Additional grid lines show linear and quadratic scaling.

  4.2 e1 3.1 e1 5.3 e1 4.2 e1 15 3.7 e2 3.4 e2 4.0 e2 3.7 e2 1e-3 15 4.2 e1 3.3 e1 5.4 e1 4.2 e1 15 3.7 e2 3.5 e2 4.0 e2 3.7 e2 1e-5 15 4.2 e1 3.2 e1 5.4 e1 4.2 e1 15 3.7 e2 3.4 e2 4.0 e2 3.7 e2 1e-8 15 4.2 e1 3.2 e1 5.3 e1 4.2 e1 15 3.7 e2 3.4 e2 4.0 e2 3.7 e2 f 6 in 5-D, N=15, mFE=9819 f 6 in 20-D,

Figure 3 :

 3 Figure 3: Empirical cumulative distribution functions (ECDFs), plotting the fraction of trials versus running time (left subplots) or versus ∆f (right subplots). The thick red line represents the best achieved results. Left subplots: ECDF of the running time (number of function evaluations), divided by search space dimension D, to fall below fopt + ∆f with ∆f = 10 k , where k is the first value in the legend. Right subplots: ECDF of the best achieved ∆f divided by 10 k (upper left lines in continuation of the left subplot), and best achieved ∆f divided by 10 -8 for running times of D, 10 D, 100 D . . . function evaluations (from right to left cycling blackcyan-magenta). Top row: all results from all functions; second row: separable functions; third row: misc. moderate functions; fourth row: ill-conditioned functions; fifth row: multi-modal functions with adequate structure; last row: multi-modal functions with weak structure. The legends indicate the number of functions that were solved in at least one trial. FEvals denotes number of function evaluations, D and DIM denote search space dimension, and ∆f and Df denote the difference to the optimal function value.

Table 1 :

 1 Shown are, for a given target difference to the optimal function value ∆f : the number of successful trials (#); the expected running time to surpass fopt + ∆f (ERT, see Figure2); the 10%-tile and 90%-tile of the bootstrap distribution of ERT; the average number of function evaluations in successful trials or, if none was successful, as last entry the median number of function evaluations to reach the best function value (RTsucc). If fopt + ∆f was never reached, figures in italics denote the best achieved ∆f -value of the median trial and the 10% and 90%-tile trial. Furthermore, N denotes the number of trials, and mFE denotes the maximum of number of function evaluations executed in one trial. See Figure2for the names of functions.

													f 18 in 5-D, N=15, mFE=512528	f 18 in 20-D, N=15, mFE=221968
												∆f	# ERT 10%	90%	RTsucc	# ERT	10%	90%	RTsucc
												10	15 4.6 e3 2.9 e3 6.6 e3	4.6 e3	0 20e+0 14e+0 30e+0	7.9 e4
												1	15 8.6 e4 4.9 e4 1.2 e5	8.6 e4	.	.	.	.	.
					3.4 e5	2.3 e5	.	.	.	.	.	1e-1 5 1.3 e6 8.4 e5 2.3 e6	4.2 e5	.	.	.	.	.
	1e-3 0 54e-3 16e-3 11e-2	2.8 e5	.	.	.	.	.	1e-3 0 17e-2 50e-3 58e-2	2.2 e5	.	.	.	.	.
	1e-5 .	.	.	.	.	.	.	.	.	.	1e-5 .	.	.	.	.	.	.	.	.	.
	1e-8 .	.	.	.	.	.	.	.	.	.	1e-8 .	.	.	.	.	.	.	.	.	.
		f 19 in 5-D, N=15, mFE=503610	f 19 in 20-D, N=15, mFE=212448		f 20 in 5-D, N=15, mFE=500477	f 20 in 20-D, N=15, mFE=201399
	∆f	# ERT 10%	90%	RTsucc	# ERT 10%	90%	RTsucc	∆f	# ERT 10%	90%	RTsucc	# ERT 10%	90%	RTsucc
	10	15 1.2 e1 1.1 e1 1.4 e1	1.2 e1	15 1.6 e2 1.3 e2 2.0 e2	1.6 e2	10	15 2.4 e1 1.9 e1 2.9 e1	2.4 e1	15 2.9 e2 2.5 e2 3.3 e2	2.9 e2
	1	15 2.9 e3 1.7 e3 4.2 e3	2.9 e3	2 1.4 e6 7.5 e5 >3 e6	2.0 e5	1	15 2.1 e4 1.4 e4 2.8 e4	2.1 e4	0 13e-1 12e-1 14e-1	1.3 e5
	1e-1 15 1.4 e5 1.1 e5 1.8 e5	1.4 e5	0 19e-1 91e-2 23e-1	1.3 e5	1e-1 0 24e-2 24e-2 47e-2	2.5 e5	.	.	.	.	.
	1e-3 0 59e-3 24e-3 90e-3	1.6 e5	.	.	.	.	.	1e-3 .	.	.	.	.	.	.	.	.	.
	1e-5 .	.	.	.	.	.	.	.	.	.	1e-5 .	.	.	.	.	.	.	.	.	.
	1e-8 .	.	.	.	.	.	.	.	.	.	1e-8 .	.	.	.	.	.	.	.	.	.
			f 21 in 5-D, N=15, mFE=66367	f 21 in 20-D, N=15, mFE=201297		f 22 in 5-D, N=15, mFE=84189	f 22 in 20-D, N=15, mFE=201226
	∆f	# ERT 10%	90%	RTsucc	# ERT 10%	90%	RTsucc	∆f	# ERT 10%	90%	RTsucc	# ERT 10%	90%	RTsucc
	10	15 5.0 e2 2.3 e2 7.7 e2	5.0 e2	15 4.3 e3 1.8 e3 6.9 e3	4.3 e3	10	15 1.3 e3 6.9 e2 2.0 e3	1.3 e3	15 7.8 e3 3.3 e3 1.2 e4	7.8 e3
	1	15 9.7 e3 4.9 e3 1.5 e4	9.7 e3	12 1.3 e5 1.1 e5 1.6 e5	1.1 e5	1	15 5.2 e3 3.2 e3 7.4 e3	5.2 e3	13 9.8 e4 6.6 e4 1.4 e5	6.7 e4
	1e-1 15 1.7 e4 1.0 e4 2.5 e4	1.7 e4	7 3.4 e5 2.4 e5 5.5 e5	1.4 e5	1e-1 15 1.3 e4 6.5 e3 1.9 e4	1.3 e4	2 1.4 e6 7.3 e5 >3 e6	1.8 e5
	1e-3 15 1.7 e4 9.7 e3 2.5 e4	1.7 e4	7 3.4 e5 2.4 e5 5.5 e5	1.4 e5	1e-3 15 1.3 e4 6.5 e3 2.0 e4	1.3 e4	2 1.4 e6 7.4 e5 >3 e6	1.8 e5
	1e-5 15 1.7 e4 9.4 e3 2.5 e4	1.7 e4	7 3.4 e5 2.4 e5 5.5 e5	1.5 e5	1e-5 15 1.3 e4 6.6 e3 2.0 e4	1.3 e4	2 1.4 e6 7.4 e5 >3 e6	1.9 e5
	1e-8 15 1.7 e4 1.0 e4 2.5 e4	1.7 e4	7 3.4 e5 2.4 e5 5.6 e5	1.5 e5	1e-8 15 1.3 e4 6.6 e3 2.0 e4	1.3 e4	2 1.4 e6 7.3 e5 >3 e6	1.9 e5
		f 23 in 5-D, N=15, mFE=500023	f 23 in 20-D, N=15, mFE=202618		f 24 in 5-D, N=15, mFE=500713	f 24 in 20-D, N=15, mFE=201076
	∆f	# ERT 10%	90%	RTsucc	# ERT 10%	90%	RTsucc	∆f	# ERT 10%	90%	RTsucc	# ERT	10%	90%	RTsucc
	10	15 8.8 e0 6.5 e0 1.1 e1	8.8 e0	15 6.9 e0 4.3 e0 9.7 e0	6.9 e0	10	15 1.8 e4 1.1 e4 2.6 e4	1.8 e4	0 10e+1 65e+0 14e+1	1.1 e5
	1	15 1.8 e3 9.6 e2 2.8 e3	1.8 e3	15 5.4 e3 3.2 e3 7.7 e3	5.4 e3	1	5 1.2 e6 8.3 e5 2.2 e6	4.5 e5	.	.	.	.	.
	1e-1 15 3.9 e4 2.7 e4 5.2 e4	3.9 e4	1 2.9 e6 1.4 e6 >3 e6	2.0 e5	1e-1 0 12e-1 83e-2 30e-1	1.4 e5	.	.	.	.	.
	1e-3 15 1.3 e5 9.9 e4 1.6 e5	1.3 e5	0 20e-2 11e-2 27e-2	7.9 e4	1e-3 .	.	.	.	.	.	.	.	.	.
	1e-5 15 1.5 e5 1.1 e5 1.9 e5	1.5 e5	.	.	.	.	.	1e-5 .	.	.	.	.	.	.	.	.	.
	1e-8 14 2.1 e5 1.5 e5 2.8 e5	1.8 e5	.	.	.	.	.	1e-8 .	.	.	.	.	.	.	.	.	.

Acknowledgments

The author would like to acknowledge the great and hard work of the BBOB team with particular kudos to Raymond Ros, Steffen Finck and Anne Auger, and Anne Auger and Marc Schoenauer for their kind and persistent support.