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Graphite

Graphite is a crystalline form of the element carbon. It consists of stacked layers of graphene. Graphite occurs naturally and is the most stable form of carbon under standard conditions. Synthetic and natural graphite are consumed on a large scale (1.3 million metric tons per year in 2022) for uses in pencils, lubricants, and electrodes. Under high pressures and temperatures it converts to diamond. It is a good (but not excellent) conductor of both heat and electricity.

Natural graphite
The principal types of natural graphite, each occurring in different types of ore deposits, are

 * Crystalline small flakes of graphite (or flake graphite) occurs as isolated, flat, plate-like particles with hexagonal edges if unbroken. When broken, the edges can be irregular or angular;
 * Amorphous graphite: very fine flake graphite is sometimes called amorphous;
 * Lump graphite (or vein graphite) occurs in fissure veins or fractures and appears as massive platy intergrowths of fibrous or acicular crystalline aggregates, and is probably hydrothermal in origin.
 * Highly ordered pyrolytic graphite refers to graphite with an angular spread between the graphite sheets of less than 1°.
 * The name "graphite fiber" is sometimes used to refer to carbon fibers or carbon fiber-reinforced polymer.

Synthetic graphite
Synthetic graphite (or artificial graphite) is a material consisting of graphitic carbon which has been obtained by graphitizing of non-graphitic carbon, by chemical vapor deposition from hydrocarbons at temperatures above 2500 K, by decomposition of thermally unstable carbides or by crystallizing from metal melts supersaturated with carbon.

Biographite
Biographite is a commercial product proposal for reducing the carbon footprint of lithium iron phosphate (LFP) batteries. It is produced from forestry waste and similar byproducts by a company in New Zealand using a novel process called thermo-catalytic graphitisation which project is supported by grants from interested parties including a forestry company in Finland and a battery maker in Hong Kong

Occurrence
Graphite occurs in metamorphic rocks as a result of the reduction of sedimentary carbon compounds during metamorphism. It also occurs in igneous rocks and in meteorites. Minerals associated with graphite include quartz, calcite, micas and tourmaline. The principal export sources of mined graphite are in order of tonnage: China, Mexico, Canada, Brazil, and Madagascar. Significant unexploited graphite resources also exists in Colombia's Cordillera Central in the form of graphite-bearing schists.

In meteorites, graphite occurs with troilite and silicate minerals. Small graphitic crystals in meteoritic iron are called cliftonite. Some microscopic grains have distinctive isotopic compositions, indicating that they were formed before the Solar System. They are one of about 12 known types of minerals that predate the Solar System and have also been detected in molecular clouds. These minerals were formed in the ejecta when supernovae exploded or low to intermediate-sized stars expelled their outer envelopes late in their lives. Graphite may be the second or third oldest mineral in the Universe.

Structure
Graphite consists of sheets of trigonal planar carbon. The individual layers are called graphene. In each layer, the carbon atoms are arranged in a honeycomb lattice with a bond length of 0.142 nm, and the distance between planes is 0.335 nm. Bonding between layers is relatively weak van der Waals bonds, which allows the graphene-like layers to be easily separated and to glide past each other. Electrical conductivity perpendicular to the layers is consequently about 1000 times lower.

There are two allotropic forms called alpha (hexagonal) and beta (rhombohedral), differing in terms of the stacking of the graphene layers: stacking in alpha graphite is ABA, as opposed to ABC stacking in the energetically less stable beta graphite. Rhombohedral graphite cannot occur in pure form. Natural graphite, or commercial natural graphite, contains 5 to 15% rhombohedral graphite and this may be due to intensive milling. The alpha form can be converted to the beta form through shear forces, and the beta form reverts to the alpha form when it is heated to 1300 °C for four hours.

Thermodynamics
The equilibrium pressure and temperature conditions for a transition between graphite and diamond is well established theoretically and experimentally. The pressure changes linearly between $1.7 GPa$ at $0 K$ and $12 GPa$ at $5,000 K$ (the diamond/graphite/liquid triple point). However, the phases have a wide region about this line where they can coexist. At normal temperature and pressure, 20 C and 1 atm, the stable phase of carbon is graphite, but diamond is metastable and its rate of conversion to graphite is negligible. However, at temperatures above about $4,500 K$, diamond rapidly converts to graphite. Rapid conversion of graphite to diamond requires pressures well above the equilibrium line: at $2,000 K$, a pressure of $35 GPa$ is needed.

Other properties
The acoustic and thermal properties of graphite are highly anisotropic, since phonons propagate quickly along the tightly bound planes, but are slower to travel from one plane to another. Graphite's high thermal stability and electrical and thermal conductivity facilitate its widespread use as electrodes and refractories in high temperature material processing applications. However, in oxygen-containing atmospheres graphite readily oxidizes to form carbon dioxide at temperatures of 700 °C and above.

Graphite is an electrical conductor, hence useful in such applications as arc lamp electrodes. It can conduct electricity due to the vast electron delocalization within the carbon layers (a phenomenon called aromaticity). These valence electrons are free to move, so are able to conduct electricity. However, the electricity is primarily conducted within the plane of the layers. The conductive properties of powdered graphite allow its use as pressure sensor in carbon microphones.

Graphite and graphite powder are valued in industrial applications for their self-lubricating and dry lubricating properties. However, the use of graphite is limited by its tendency to facilitate pitting corrosion in some stainless steel, and to promote galvanic corrosion between dissimilar metals (due to its electrical conductivity). It is also corrosive to aluminium in the presence of moisture. For this reason, the US Air Force banned its use as a lubricant in aluminium aircraft, and discouraged its use in aluminium-containing automatic weapons. Even graphite pencil marks on aluminium parts may facilitate corrosion. Another high-temperature lubricant, hexagonal boron nitride, has the same molecular structure as graphite. It is sometimes called white graphite, due to its similar properties.

When a large number of crystallographic defects bind these planes together, graphite loses its lubrication properties and becomes what is known as pyrolytic graphite. It is also highly anisotropic, and diamagnetic, thus it will float in mid-air above a strong magnet. (If it is made in a fluidized bed at 1000–1300 °C then it is isotropic turbostratic, and is used in blood-contacting devices like mechanical heart valves and is called pyrolytic carbon, and is not diamagnetic. Pyrolytic graphite and pyrolytic carbon are often confused but are very different materials. )

Natural and crystalline graphites are not often used in pure form as structural materials, due to their shear-planes, brittleness, and inconsistent mechanical properties.

History of natural graphite use
In the 4th millennium BCE, during the Neolithic Age in southeastern Europe, the Marița culture used graphite in a ceramic paint for decorating pottery.

Sometime before 1565 (some sources say as early as 1500), an enormous deposit of graphite was discovered on the approach to Grey Knotts from the hamlet of Seathwaite in Borrowdale parish, Cumbria, England, which the locals found useful for marking sheep. During the reign of Elizabeth I (1558–1603), Borrowdale graphite was used as a refractory material to line molds for cannonballs, resulting in rounder, smoother balls that could be fired farther, contributing to the strength of the English navy. This particular deposit of graphite was extremely pure and soft, and could easily be cut into sticks. Because of its military importance, this unique mine and its production were strictly controlled by the Crown.

During the 19th century, graphite's uses greatly expanded to include stove polish, lubricants, paints, crucibles, foundry facings, and pencils, a major factor in the expansion of educational tools during the first great rise of education for the masses. The British Empire controlled most of the world's production (especially from Ceylon), but production from Austrian, German, and American deposits expanded by mid-century. For example, the Dixon Crucible Company of Jersey City, New Jersey, founded by Joseph Dixon and partner Orestes Cleveland in 1845, opened mines in the Lake Ticonderoga district of New York, built a processing plant there, and a factory to manufacture pencils, crucibles and other products in New Jersey, described in the Engineering & Mining Journal 21 December 1878. The Dixon pencil is still in production. The beginnings of the revolutionary froth flotation process are associated with graphite mining. Included in the E&MJ article on the Dixon Crucible Company is a sketch of the "floating tanks" used in the age-old process of extracting graphite. Because graphite is so light, the mix of graphite and waste was sent through a final series of water tanks where a cleaner graphite "floated" off, which left waste to drop out. In an 1877 patent, the two brothers Bessel (Adolph and August) of Dresden, Germany, took this "floating" process a step further and added a small amount of oil to the tanks and boiled the mix – an agitation or frothing step – to collect the graphite, the first steps toward the future flotation process. Adolph Bessel received the Wohler Medal for the patented process that upgraded the recovery of graphite to 90% from the German deposit. In 1977, the German Society of Mining Engineers and Metallurgists organized a special symposium dedicated to their discovery and, thus, the 100th anniversary of flotation.

In the United States, in 1885, Hezekiah Bradford of Philadelphia patented a similar process, but it is uncertain if his process was used successfully in the nearby graphite deposits of Chester County, Pennsylvania, a major producer by the 1890s. The Bessel process was limited in use, primarily because of the abundant cleaner deposits found around the globe, which needed not much more than hand-sorting to gather the pure graphite. The state of the art, c. 1900, is described in the Canadian Department of Mines report on graphite mines and mining when Canadian deposits began to become important producers of graphite.

Other names
Historically, graphite was called black lead or plumbago. Plumbago was commonly used in its massive mineral form. Both of these names arise from confusion with the similar-appearing lead ores, particularly galena. The Latin word for lead, plumbum, gave its name to the English term for this grey metallic-sheened mineral and even to the leadworts or plumbagos, plants with flowers that resemble this colour.

The term black lead usually refers to a powdered or processed graphite, matte black in color.

Abraham Gottlob Werner coined the name graphite ("writing stone") in 1789. He attempted to clear up the confusion between molybdena, plumbago and black lead after Carl Wilhelm Scheele in 1778 proved that these were at least three different minerals. Scheele's analysis showed that the chemical compounds molybdenum sulfide (molybdenite), lead(II) sulfide (galena) and graphite were three different soft black minerals.

Uses of natural graphite
Natural graphite is mostly used for refractories, batteries, steelmaking, expanded graphite, brake linings, foundry facings, and lubricants.

Refractories
The use of graphite as a refractory (heat-resistant) material began before 1900 with graphite crucibles used to hold molten metal; this is now a minor part of refractories. In the mid-1980s, the carbon-magnesite brick became important, and a bit later the alumina-graphite shape. the order of importance is: alumina-graphite shapes, carbon-magnesite brick, Monolithics (gunning and ramming mixes), and then crucibles.

Crucibles began using very large flake graphite, and carbon-magnesite bricks requiring not quite so large flake graphite; for these and others there is now much more flexibility in the size of flake required, and amorphous graphite is no longer restricted to low-end refractories. Alumina-graphite shapes are used as continuous casting ware, such as nozzles and troughs, to convey the molten steel from ladle to mold, and carbon magnesite bricks line steel converters and electric-arc furnaces to withstand extreme temperatures. Graphite blocks are also used in parts of blast furnace linings where the high thermal conductivity of the graphite is critical to ensuring adequate cooling of the bottom and hearth of the furnace. High-purity monolithics are often used as a continuous furnace lining instead of carbon-magnesite bricks.

The US and European refractories industry had a crisis in 2000–2003, with an indifferent market for steel and a declining refractory consumption per tonne of steel underlying firm buyouts and many plant closures. Many of the plant closures resulted from the acquisition of Harbison-Walker Refractories by RHI AG and some plants had their equipment auctioned off. Since much of the lost capacity was for carbon-magnesite brick, graphite consumption within the refractories area moved towards alumina-graphite shapes and Monolithics, and away from the brick. The major source of carbon-magnesite brick is now China. Almost all of the above refractories are used to make steel and account for 75% of refractory consumption; the rest is used by a variety of industries, such as cement.

According to the USGS, US natural graphite consumption in refractories comprised 12,500 tonnes in 2010.

Batteries
The use of graphite in batteries has increased since the 1970s. Natural and synthetic graphite are used as an anode material to construct electrodes in major battery technologies.

The demand for batteries, primarily nickel–metal hydride and lithium-ion batteries, caused a growth in demand for graphite in the late 1980s and early 1990s – a growth driven by portable electronics, such as portable CD players and power tools. Laptops, mobile phones, tablets, and smartphone products have increased the demand for batteries. Electric-vehicle batteries are anticipated to increase graphite demand. As an example, a lithium-ion battery in a fully electric Nissan Leaf contains nearly 40 kg of graphite.

Radioactive graphite removed from nuclear reactors has been investigated as a source of electricity for low-power applications. This waste is rich in carbon-14, which emits electrons through beta decay, so it could potentially be used as the basis for a betavoltaic device. This concept is known as the diamond battery.

Graphite Anode Materials
Graphite is 'predominant anode material used today in lithium-ion batteries' EV batteries contain four basic components: anode, cathode, electrolyte, and separator. While there is much focus on the cathode materials – lithium, nickel, cobalt, manganese, etc. – the predominant anode material used in virtually all EV batteries is graphite.

Steelmaking
Natural graphite in steelmaking mostly goes into raising the carbon content in molten steel; it can also serve to lubricate the dies used to extrude hot steel. Carbon additives face competitive pricing from alternatives such as synthetic graphite powder, petroleum coke, and other forms of carbon. A carbon raiser is added to increase the carbon content of the steel to a specified level. An estimate based on USGS's graphite consumption statistics indicates that steelmakers in the US used 10,500 tonnes in this fashion in 2005.

Brake linings
Natural amorphous and fine flake graphite are used in brake linings or brake shoes for heavier (nonautomotive) vehicles, and became important with the need to substitute for asbestos. This use has been important for quite some time, but nonasbestos organic (NAO) compositions are beginning to reduce graphite's market share. A brake-lining industry shake-out with some plant closures has not been beneficial, nor has an indifferent automotive market. According to the USGS, US natural graphite consumption in brake linings was 6,510 tonnes in 2005.

Foundry facings and lubricants
A foundry-facing mold wash is a water-based paint of amorphous or fine flake graphite. Painting the inside of a mold with it and letting it dry leaves a fine graphite coat that will ease the separation of the object cast after the hot metal has cooled. Graphite lubricants are specialty items for use at very high or very low temperatures, as forging die lubricant, an antiseize agent, a gear lubricant for mining machinery, and to lubricate locks. Having low-grit graphite, or even better, no-grit graphite (ultra high purity), is highly desirable. It can be used as a dry powder, in water or oil, or as colloidal graphite (a permanent suspension in a liquid). An estimate based on USGS graphite consumption statistics indicates that 2,200 tonnes were used in this fashion in 2005. Metal can also be impregnated into graphite to create a self-lubricating alloy for application in extreme conditions, such as bearings for machines exposed to high or low temperatures.

Pencils
The ability to leave marks on paper and other objects gave graphite its name, given in 1789 by German mineralogist Abraham Gottlob Werner. It stems from γράφειν ("graphein"), meaning to write or draw in Ancient Greek.

From the 16th century, all pencils were made with leads of English natural graphite, but modern pencil lead is most commonly a mix of powdered graphite and clay; it was invented by Nicolas-Jacques Conté in 1795. It is chemically unrelated to the metal lead, whose ores had a similar appearance, hence the continuation of the name. Plumbago is another older term for natural graphite used for drawing, typically as a lump of the mineral without a wood casing. The term plumbago drawing is normally restricted to 17th and 18th-century works, mostly portraits.

Today, pencils are still a small but significant market for natural graphite. Around 7% of the 1.1 million tonnes produced in 2011 was used to make pencils. Low-quality amorphous graphite is used and sourced mainly from China.

In art, graphite is typically used to create detailed and precise drawings, as it allows for a wide range of values (light to dark) to be achieved. It can also be used to create softer, more subtle lines and shading. Graphite is popular among artists because it is easy to control, easy to erase, and produces a clean, professional look. It is also relatively inexpensive and widely available. Many artists use graphite in conjunction with other media, such as charcoal or ink, to create a range of effects and textures in their work. Graphite of various hardness or softness results in different qualities and tones when used as an artistic medium.

Pinewood derby
Graphite is probably the most-used lubricant in pinewood derbies.

Other uses
Natural graphite has found uses in zinc-carbon batteries, electric motor brushes, and various specialized applications. Railroads would often mix powdered graphite with waste oil or linseed oil to create a heat-resistant protective coating for the exposed portions of a steam locomotive's boiler, such as the smokebox or lower part of the firebox. The Scope soldering iron uses a graphite tip as its heating element.

Expanded graphite
Expanded graphite is made by immersing natural flake graphite in a bath of chromic acid, then concentrated sulfuric acid, which forces the crystal lattice planes apart, thus expanding the graphite. The expanded graphite can be used to make graphite foil or used directly as a "hot top" compound to insulate molten metal in a ladle or red-hot steel ingots and decrease heat loss, or as firestops fitted around a fire door or in sheet metal collars surrounding plastic pipe (during a fire, the graphite expands and chars to resist fire penetration and spread), or to make high-performance gasket material for high-temperature use. After being made into graphite foil, the foil is machined and assembled into the bipolar plates in fuel cells. The foil is made into heat sinks for laptop computers which keeps them cool while saving weight, and is made into a foil laminate that can be used in valve packings or made into gaskets. Old-style packings are now a minor member of this grouping: fine flake graphite in oils or greases for uses requiring heat resistance. A GAN estimate of current US natural graphite consumption in this end-use is 7,500 tonnes.

Intercalated graphite
Graphite forms intercalation compounds with some metals and small molecules. In these compounds, the host molecule or atom gets "sandwiched" between the graphite layers, resulting in a type of compound with variable stoichiometry. A prominent example of an intercalation compound is potassium graphite, denoted by the formula KC8. Some graphite intercalation compounds are superconductors. The highest transition temperature (by June 2009) Tc = 11.5 K is achieved in CaC6, and it further increases under applied pressure (15.1 K at 8 GPa). Graphite's ability to intercalate lithium ions without significant damage from swelling is what makes it the dominant anode material in lithium-ion batteries.

Invention of a process to produce synthetic graphite
In 1893, Charles Street of Le Carbone discovered a process for making artificial graphite. In the mid-1890s, Edward Goodrich Acheson (1856–1931) accidentally invented another way to produce synthetic graphite after synthesizing carborundum (also called silicon carbide). He discovered that overheating carborundum, as opposed to pure carbon, produced almost pure graphite. While studying the effects of high temperature on carborundum, he had found that silicon vaporizes at about 4150 C, leaving the carbon behind in graphitic carbon. This graphite became valuable as a lubricant.

Acheson's technique for producing silicon carbide and graphite is named the Acheson process. In 1896, Acheson received a patent for his method of synthesizing graphite, and in 1897 started commercial production. The Acheson Graphite Co. was formed in 1899.

Synthetic graphite can also be prepared from polyimide and then commercialized.

Scientific research
Highly oriented pyrolytic graphite (HOPG) is the highest-quality synthetic form of graphite. It is used in scientific research, in particular, as a length standard for the calibration of scanning probe microscopes.

Electrodes
Graphite electrodes carry the electricity that melts scrap iron and steel, and sometimes direct-reduced iron (DRI), in electric arc furnaces, which are the vast majority of steel furnaces. They are made from petroleum coke after it is mixed with coal tar pitch. They are extruded and shaped, then baked to carbonize the binder (pitch). This is finally graphitized by heating it to temperatures approaching 3000 C, at which the carbon atoms arrange into graphite. They can vary in size up to 3.5 m long and 75 cm in diameter. An increasing proportion of global steel is made using electric arc furnaces, and the electric arc furnace itself is becoming more efficient, making more steel per tonne of electrode. An estimate based on USGS data indicates that graphite electrode consumption was 197000 MT in 2005.

Electrolytic aluminium smelting also uses graphitic carbon electrodes. On a much smaller scale, synthetic graphite electrodes are used in electrical discharge machining (EDM), commonly to make injection molds for plastics.

Powder and scrap
The powder is made by heating powdered petroleum coke above the temperature of graphitization, sometimes with minor modifications. The graphite scrap comes from pieces of unusable electrode material (in the manufacturing stage or after use) and lathe turnings, usually after crushing and sizing. Most synthetic graphite powder goes to carbon raising in steel (competing with natural graphite), with some used in batteries and brake linings. According to the United States Geographical Survey, US synthetic graphite powder and scrap production were 95000 MT in 2001 (latest data).

Neutron moderator
Special grades of synthetic graphite, such as Gilsocarbon, also find use as a matrix and neutron moderator within nuclear reactors. Its low neutron cross-section also recommends it for use in proposed fusion reactors. Care must be taken that reactor-grade graphite is free of neutron absorbing materials such as boron, widely used as the seed electrode in commercial graphite deposition systems – this caused the failure of the Germans' World War II graphite-based nuclear reactors. Since they could not isolate the difficulty they were forced to use far more expensive heavy water moderators. Graphite used for nuclear reactors is often referred to as nuclear graphite. Herbert G. McPherson, a Berkeley trained physicist at National Carbon, a division of Union Carbide, was key in confirming a conjecture of Leo Szilard that boron impurities even in "pure" graphite were responsible for a neutron absorption cross-section in graphite that compromised U-235 chain reactions. McPherson was aware of the presence of impurities in graphite because, with the use of Technicolor in cinematography, the spectra of graphite electrode arcs used in movie projectors required impurities to enhance emission of light in the red region to display warmer skin tones on the screen. Thus, had it not been for color movies, chances are that the first sustained natural U chain reaction would have required a heavy water moderated reactor.

Other uses
Graphite (carbon) fiber and carbon nanotubes are also used in carbon fiber reinforced plastics, and in heat-resistant composites such as reinforced carbon-carbon (RCC). Commercial structures made from carbon fiber graphite composites include fishing rods, golf club shafts, bicycle frames, sports car body panels, the fuselage of the Boeing 787 Dreamliner and pool cue sticks and have been successfully employed in reinforced concrete. The mechanical properties of carbon fiber graphite-reinforced plastic composites and grey cast iron are strongly influenced by the role of graphite in these materials. In this context, the term "(100%) graphite" is often loosely used to refer to a pure mixture of carbon reinforcement and resin, while the term "composite" is used for composite materials with additional ingredients.

Modern smokeless powder is coated in graphite to prevent the buildup of static charge.

Graphite has been used in at least three radar absorbent materials. It was mixed with rubber in Sumpf and Schornsteinfeger, which were used on U-boat snorkels to reduce their radar cross section. It was also used in tiles on early F-117 Nighthawk stealth strike fighters.

Graphite composites are used as absorber for high-energy particles, for example in the Large Hadron Collider beam dump.

Graphite rods when filed into shape are used as a tool in glassworking to manipulate hot molten glass.

Graphite mining, beneficiation, and milling
Graphite is mined by both open pit and underground methods. Graphite usually needs beneficiation. This may be carried out by hand-picking the pieces of gangue (rock) and hand-screening the product or by crushing the rock and floating out the graphite. Beneficiation by flotation encounters the difficulty that graphite is very soft and "marks" (coats) the particles of gangue. This makes the "marked" gangue particles float off with the graphite, yielding impure concentrate. There are two ways of obtaining a commercial concentrate or product: repeated regrinding and floating (up to seven times) to purify the concentrate, or by acid leaching (dissolving) the gangue with hydrofluoric acid (for a silicate gangue) or hydrochloric acid (for a carbonate gangue). In milling, the incoming graphite products and concentrates can be ground before being classified (sized or screened), with the coarser flake size fractions (below 8 mesh, 8–20 mesh, 20–50 mesh) carefully preserved, and then the carbon contents are determined. Some standard blends can be prepared from the different fractions, each with a certain flake size distribution and carbon content. Custom blends can also be made for individual customers who want a certain flake size distribution and carbon content. If flake size is unimportant, the concentrate can be ground more freely. Typical end products include a fine powder for use as a slurry in oil drilling and coatings for foundry molds, carbon raiser in the steel industry (Synthetic graphite powder and powdered petroleum coke can also be used as carbon raiser). Environmental impacts from graphite mills consist of air pollution including fine particulate exposure of workers and also soil contamination from powder spillages leading to heavy metal contamination of soil.

According to the United States Geological Survey (USGS), world production of natural graphite in 2016 was 1,200,000 tonnes, of which the following major exporters are: China (780,000 t), India (170,000 t), Brazil (80,000 t), Turkey (32,000 t) and North Korea (6,000 t). Graphite is not currently mined in the United States, but there are many historical mine sites including ones in Alabama, Montana, and in the Adirondacks of NY. Westwater Resources is in the development stages of creating a pilot plant for their Coosa Graphite Mine near Sylacauga, Alabama. U.S. production of synthetic graphite in 2010 was 134,000 t valued at $1.07 billion.

Occupational safety
Potential health effects include:
 * Inhalation: No inhalation hazard in manufactured and shipped state. Dust and fumes generated from the material can enter the body by inhalation. High concentrations of dust and fumes may irritate the throat and respiratory system and cause coughing. Frequent inhalation of fume/dust over a long period of time increases the risk of developing lung diseases. Prolonged and repeated overexposure to dust can lead to pneumoconiosis. Pre-existing pulmonary disorders, such as emphysema, may possibly be aggravated by prolonged exposure to high concentrations of graphite dusts.
 * Eye contact: Dust in the eyes will cause irritation. Exposed may experience eye tearing, redness, and discomfort.
 * Skin contact: Under normal conditions of intended use, this material does not pose a risk to health. Dust may irritate skin.
 * Ingestion: Not relevant, due to the form of the product in its manufactured and shipped state. However, ingestion of dusts generated during working operations may cause nausea and vomiting.
 * Potential physical / chemical effects: Bulk material is non-combustible. The material may form dust and can accumulate electrostatic charges, which may cause an electrical spark (ignition source). High dust levels may create potential for explosion.

United States
The Occupational Safety and Health Administration (OSHA) has set the legal limit (permissible exposure limit) for graphite exposure in the workplace as a time weighted average (TWA) of 15 million particles per cubic foot (1.5 mg/m3) over an 8-hour workday. The National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit (REL) of TWA 2.5 mg/m3 respirable dust over an 8-hour workday. At levels of 1250 mg/m3, graphite is immediately dangerous to life and health.

Graphite recycling
The most common way of recycling graphite occurs when synthetic graphite electrodes are either manufactured and pieces are cut off or lathe turnings are discarded for reuse, or the electrode (or other materials) are used all the way down to the electrode holder. A new electrode replaces the old one, but a sizeable piece of the old electrode remains. This is crushed and sized, and the resulting graphite powder is mostly used to raise the carbon content of molten steel.

Graphite-containing refractories are sometimes also recycled, but often are not due to their low graphite content: the largest-volume items, such as carbon-magnesite bricks that contain only 15–25% graphite, usually contain too little graphite to be worthwhile to recycle. However, some recycled carbon–magnesite brick is used as the basis for furnace-repair materials, and also crushed carbon–magnesite brick is used in slag conditioners.

While crucibles have a high graphite content, the volume of crucibles used and then recycled is very small.

A high-quality flake graphite product that closely resembles natural flake graphite can be made from steelmaking kish. Kish is a large-volume near-molten waste skimmed from the molten iron feed to a basic oxygen furnace and consists of a mix of graphite (precipitated out of the supersaturated iron), lime-rich slag, and some iron. The iron is recycled on-site, leaving a mixture of graphite and slag. The best recovery process uses hydraulic classification (which utilizes a flow of water to separate minerals by specific gravity: graphite is light and settles nearly last) to get a 70% graphite rough concentrate. Leaching this concentrate with hydrochloric acid gives a 95% graphite product with a flake size ranging from 10 mesh (2 mm) down.

Research and innovation in graphite technologies
Globally, over 60,000 patent families in graphite technologies were filed from 2012 to 2021. Patents were filed by applicants from over 60 countries and regions. However, graphite-related patent families originated predominantly from just a few countries. China was the top contributor with more than 47,000 patent families, accounting for four in every five graphite patent families filed worldwide in the last decade. Among other leading countries were Japan, the Republic of Korea, the United States and the Russian Federation. Together, these top five countries of applicant origin accounted for 95 percent of global patenting output related to graphite.

Among the different graphite sources, flake graphite has the highest number of patent families, with more than 5,600 filed worldwide from 2012 to 2021. Supported by active research from its commercial entities and research institutions, China is the country most actively exploiting flake graphite and has contributed to 85 percent of global patent filings in this area.

At the same time, innovations exploring new synthesis methods and uses for artificial graphite are gaining interest worldwide, as countries seek to exploit the superior material qualities associated with this man-made substance and reduce reliance on the natural material. Patenting activity is strongly led by commercial entities, particularly world-renowned battery manufacturers and anode material suppliers, with patenting interest focused on battery anode applications.

The exfoliation process for bulk graphite, which involves separating the carbon layers within graphite, has been extensively studied between 2012 and 2021. Specifically, ultrasonic and thermal exfoliation have been the two most popular approaches worldwide, with 4,267 and 2,579 patent families, respectively, significantly more than for either the chemical or electrochemical alternatives.

Global patenting activity relating to ultrasonic exfoliation has decreased over the years, indicating that this low-cost technique has become well established. Thermal exfoliation is a more recent process. Compared to ultrasonic exfoliation, this fast and solvent-free thermal approach has attracted greater commercial interest.

As the most widespread anode material for lithium-ion batteries, graphite has drawn significant attention worldwide for use in battery applications. With over 8,000 patent families filed from 2012 to 2021, battery applications were a key driver of global graphite-related inventions. Innovations in this area are led by battery manufacturers or anode suppliers who have amassed sizable patent portfolios focused strongly on battery performance improvements based on graphite anode innovation. Besides industry players, academia and research institutions – Chinese universities, in particular – have been an essential source of innovation in graphite anode technologies.

Graphite for polymer applications was an innovation hot topic from 2012 to 2021, with over 8,000 patent families recorded worldwide. However, in recent years, in the top countries of applicant origin in this area, including China, Japan and the United States of America (US), patent filings have decreased.

Graphite for manufacturing ceramics represents another area of intensive research, with over 6,000 patent families registered in the last decade alone. Specifically, graphite for refractory accounted for over one-third of ceramics-related graphite patent families in China and about one-fifth in the rest of the world. Other important graphite applications include high-value ceramic materials such as carbides for specific industries, ranging from electrical and electronics, aerospace and precision engineering to military and nuclear applications.

Carbon brushes represent a long-explored graphite application area. There have been few inventions in this area over the last decade, with less than 300 patent families filed from 2012 to 2021, very significantly less than between 1992 and 2011.

Biomedical, sensor, and conductive ink are emerging application areas for graphite that have attracted interest from both academia and commercial entities, including renowned universities and multinational corporations. Typically for an emerging technology area, related patent families were filed by various organizations without any players dominating. As a result, the top applicants have a small number of inventions, unlike in well-explored areas, where they will have strong technology accumulation and large patent portfolios. The innovation focus of these three emerging areas is highly scattered and can be diverse, even for a single applicant. However, recent inventions are seen to leverage the development of graphite nanomaterials, particularly graphite nanocomposites and graphene.

title: Graphite


text:
Garry Trudeau

Garretson Beekman Trudeau (born July 21, 1948) is an American cartoonist, best known for creating the Doonesbury comic strip. Trudeau is also the creator and executive producer of the Amazon Studios political comedy series Alpha House.

Trudeau won the Pulitzer Prize for Editorial Cartooning in 1975, making him the first comic strip artist to win a Pulitzer. He is one of only two comic strip artists to win the award, the other being Berkeley Breathed, whose work was influenced by Trudeau.

Background and education
Trudeau was born in New York City, the son of Jean Douglas ( Moore, daughter of New York Assembly member Thomas Channing Moore) and Francis Berger Trudeau Jr. He is the great-grandson of Edward Livingston Trudeau, who created Adirondack Cottage Sanitarium for the treatment of pulmonary tuberculosis at Saranac Lake, New York. Edward was succeeded by his son Francis and grandson Francis Jr. The latter founded the Trudeau Institute at Saranac Lake, with which Garry Trudeau retains a connection.

His ancestry is French Canadian, English, Dutch, German, and Swedish.

Raised in Saranac Lake, Trudeau attended St. Paul's School in Concord, New Hampshire. He enrolled in Yale University in 1966. As an art major, Trudeau initially focused on painting, but soon discovered a greater interest in the graphic arts. He spent much of his time cartooning and writing for Yale's humor magazine The Yale Record, eventually serving as the magazine's editor-in-chief. At the same time, Trudeau began contributing to the Yale Daily News, which eventually led to the creation of Bull Tales, a comic strip parodying the exploits of Yale quarterback Brian Dowling. This strip was the progenitor of Doonesbury.

While still an undergraduate at Yale, Trudeau published two collections of Bull Tales: Bull Tales (1969, published by the Yale Daily News) and Michael J. (1970, published by The Yale Record).

As a senior, Trudeau became a member of Scroll and Key. He did postgraduate work at the Yale School of Art, earning a master of fine arts degree in graphic design in 1973. It was there that Trudeau first met photographer David Levinthal, with whom he collaborated on Hitler Moves East, an influential "graphic chronicle" of the German invasion of the Soviet Union.

Creative works
Soon after Bull Tales began running in the Yale student newspaper, the strip caught the attention of the newly formed Universal Press Syndicate. The syndicate's editor, James F. Andrews, recruited Trudeau, changed the strip's name to Doonesbury, and began distributing it following the cartoonist's graduation in 1970. Today Doonesbury is syndicated to 1,000 daily and Sunday newspapers worldwide and is accessible online in association with The Washington Post.

In 1975, Trudeau became the first comic strip artist to win a Pulitzer, traditionally awarded to editorial-page cartoonists. He was also a Pulitzer finalist in 1990, 2004, and 2005. Other awards during this time include the National Cartoonist Society Newspaper Comic Strip Award in 1994, the Reuben Award from the National Cartoonist Society in 1995, the George Orwell Award in 1994, and the Forte dei Marmi Prize for Satire 1990 in Italy,

Awards received in the 21st century include: The Max & Moritz Award for Best Comic Strip (2006, Germany) the Harvey Award, Best Syndicated Strip (2011), the George Polk Award, Lifetime Achievement (2015), and the National Cartoonist Society's Gold T-Square (2021). .

Trudeau's work has been recognized by fellowships and halls of fame. In 1993, Trudeau was made a fellow of the American Academy of Arts and Sciences. In 2021, he was inducted into the New York State Writers Hall of Fame, and the Eisner Hall of Fame in 2023.

Wiley Miller, fellow comic-strip artist responsible for Non Sequitur, called him "far and away the most influential editorial cartoonist in the last 25 years". A regular graduation speaker, Trudeau has received 37 honorary degrees. In addition to his creating his strip, Trudeau has worked in both theater and television. He was nominated for an Oscar in 1977 in the category of Animated Short Film for A Doonesbury Special, created for NBC in collaboration with John and Faith Hubley. The film won the Cannes Film Festival Jury Prize in 1978. In 1984, with composer Elizabeth Swados, he wrote the book and lyrics for the Broadway musical Doonesbury, for which he was nominated for two Drama Desk Awards. A cast album of the show, recorded for MCA, received a Grammy nomination. Trudeau again collaborated with Swados in 1984, this time on Rap Master Ronnie, a satirical revue about the Reagan Administration that opened off-Broadway at the Village Gate. A filmed version, featuring Jon Cryer, the Smothers Brothers, and Carol Kane, was broadcast on Cinemax in 1988.

Also in 1988, Trudeau wrote and co-produced with director Robert Altman HBO's critically acclaimed Tanner '88, a satiric look at that year's presidential election campaign. The show won the gold medal for Best Television Series at the Cannes Television Festival, the British Academy Television Award for Best Foreign Program, and Best Imported Program from the British Broadcasting Press Guild. It earned an Emmy Award, as well as four ACE Award nominations. In 2004, Trudeau reunited with Altman to write and co-produce a sequel mini-series, Tanner on Tanner, for the Sundance Channel.

In 1996, Newsweek and The Washington Post speculated that Trudeau had written the novel Primary Colors, which was later revealed to have been written by Joe Klein. In February 2000, Trudeau, working with Dotcomix, launched Duke2000, a web-based presidential campaign featuring a real-time, 3-D, streaming-animation version of Duke. Nearly 30 campaign videos were created for the site, and Ambassador Duke was interviewed live by satellite on the Today Show, Larry King Live, The Charlie Rose Show, and dozens of local TV and radio news shows.

In 2013, Trudeau created, wrote and co-produced Alpha House, a political sitcom starring John Goodman that revolves around four Republican U.S. Senators who live together in a townhouse on Capitol Hill. Trudeau was inspired to write the show's pilot after reading a 2007 New York Times article about a real D.C. townhouse shared by New York Senator Chuck Schumer, Illinois Senator Dick Durbin, and California Representative George Miller, all Democrats. The pilot for Alpha House was produced by Amazon Studios and aired in early 2013. Due to positive response, Amazon picked up the show to develop into a full series, streaming eleven episodes for its first season. On March 31, 2014, Amazon announced that Alpha House had been renewed. Production began in July 2014, and the entire second season became available for streaming on October 24, 2014.

While writing Alpha House, Trudeau put the daily Doonesbury into rerun mode. On March 3, 2014, the "Classic Doonesbury" series began, featuring approximately four weeks of daily strips from each year of the strip's run. He continues to produce new strips for Sundays. Although Alpha House has not been in production since the end of 2014, Trudeau has not returned to creating daily Doonesbury strips; new material remains a Sunday-only event.

Trudeau has contributed to such publications as Harper's, Rolling Stone, The New Republic, The New Yorker, New York, and The Washington Post. From 1990 to 1994, he wrote and drew an occasional column for The New York Times op-ed page, and was a contributing essayist for Time magazine from 1996 to 2001.

Beginning with the Gulf War in 1991, Trudeau has written about military issues extensively. In recognition for his work on injured soldiers, he has been presented with the Commander's Award for Public Service by the Department of the Army, the Commander's Award from Disabled American Veterans, the President's Award for Excellence in the Arts from Vietnam Veterans of America, the Distinguished Public Service Award from the American Academy of Physical Medicine and Rehabilitation, the Mental Health Research Advocacy Award from the Yale School of Medicine, and a special citation from the Vet Centers.

He received several unit commendations from the field during the Gulf War, and he traveled with the USO to visit troops in Iraq and Afghanistan. From 2005 to 2014, his website hosted The Sandbox, a milblog posting over 800 essays by deployed soldiers, returned vets, caregivers, and spouses. For most of the strip's run, Trudeau has eschewed merchandising, but starting in 1998 he teamed up with Starbucks to create Doonesbury products to raise funds for local literacy programs. The items were offered for sale in Starbucks stores for nearly two years and raised over $1 million. Also for charity, Trudeau licensed the strip to Ben & Jerry's, which created a bestselling sorbet flavor called Doonesberry.

Trudeau's son Ross, a digital media producer, is also a crossword constructor who has been published in the New York Times. As part of the ongoing celebrity partnership series, father and son collaborated on a crossword puzzle that was published on May 15, 2018, in the Times.

Trudeau, formerly a member of Writers Guild of America, East, left and maintained financial core status.

Private life and public appearances
Trudeau married Jane Pauley on June 14, 1980; they have three children. He maintains a low personal profile. A rare early appearance on television was as a guest on To Tell the Truth in 1971, where only one of the three panelists guessed his identity. In 1990, Trudeau appeared on the cover of Newsweek for Inside Doonesbury's Brain, a story written by Jonathan Alter. This was the first interview Trudeau had given in 17 years.

Trudeau cooperated extensively with Wired magazine for a 2000 profile, "The Revolution Will be Satirized". He later spoke with the writer of that article, Edward Cone, for a 2004 newspaper column in the Greensboro, North Carolina, News & Record, about the war wounds suffered by the Doonesbury character "B.D.", and in 2006 did a Q&A at Cone's personal blog about The Sandbox. Trudeau granted an interview to Rolling Stone in 2004 in which he discussed his time at Yale, which he attended two years behind George W. Bush. He granted another Rolling Stone interview in 2010. In 2006, The Washington Post printed an extensive profile of Trudeau by writer Gene Weingarten. He appeared on the Charlie Rose television program, and at signings for The Long Road Home: One Step at a Time, his Doonesbury book about B.D.'s struggle with injuries received during the second Gulf War.

On August 1, 2016, Trudeau appeared on MSNBC on The Rachel Maddow Show. He was brought on to discuss his prediction about Donald Trump's plans to run for president almost three decades earlier. Maddow presented cartoon strips from as far back as 1987. Trudeau was on her show to promote his new book Yuge, which covers 30 years of Trump appearing in Doonesbury. On November 7, 2016, Trudeau appeared on Fresh Air with Terry Gross to discuss Yuge. On the CBS News Sunday Morning broadcast of December 2, 2018, he was featured and was interviewed by his wife, Jane Pauley.

Appraisals and controversies
Eric Alterman, writing in The Nation, called Doonesbury "one of the great intellectual/artistic accomplishments of the past half-century, irrespective of category".

Trudeau has also attracted criticism both for the comic strip and for his own opinions. In 1985, responding to changes after his 1983–1984 hiatus in Doonesbury, readers of The Saturday Review voted Trudeau one of the "Most Overrated People in American Arts and Letters", stating that after his hiatus, his comic strip was "predictable, mean-spirited, and not as funny as before." Trudeau's acceptance speech on the occasion of receiving a Polk Award in 2015 for lifetime achievement stirred controversy. In the speech, Trudeau criticized the cartoonists of Charlie Hebdo—after a number of Charlie Hebdo writers, editors and cartoonists had been murdered execution-style in their own Paris offices by Muslim terrorists—for "punching downward... attacking a powerless, disenfranchised minority with crude, vulgar drawings closer to graffiti than cartoons", and thereby wandering "into the realm of hate speech" with cartoons of Muhammad. Writing in The Atlantic, in which Trudeau had published his speech, political commentator David Frum criticized what he called Trudeau's "moral theory" that calls for identifying "the bearer of privilege", then holding "the privilege-bearer responsible". Trudeau was labeled a "terror apologist" by the editors of New York Post for his comments, with his choice of the venue in which to make them "adding to the insult".

Non-Doonesbury publications

 * Hitler Moves East: A Graphic Chronicle, 1941–43 (with David Levinthal), Sheed, Andrews and McMeel, 1977. . The cover shows two Wehrmacht motorcyclists. The book relates the story of Nazi Germany's Army Group Centre on the Eastern Front through archival photos and new photography of model soldiers (ISBN 0-8362-0708-4)
 * Finding Your Religion: When the Faith You Grew Up With Has Lost Its Meaning by Rev. Scotty McLennan, HarperSanFrancisco, 1999. Trudeau drew the cover cartoon and wrote the introduction.
 * Doonesbury.com's The Sandbox: Dispatches from Troops in Iraq and Afghanistan, introduction by G.B. Trudeau; edited by David Stanford, Duty Officer, Doonesbury Town Hall, Andrews McMeel Publishing (2007), ISBN 0-7407-6945-6. More than 100 blog posts by soldiers in Iraq and Afghanistan, returned vets, caregivers, and family members.
 * Doonesbury.com's The War in Quotes, introduction by G.B. Trudeau; edited by David Stanford, Duty Officer, Doonesbury Town Hall, Andrews McMeel Publishing (2008) ISBN 0-7407-7231-7

Collections
Most of Trudeau's original drawings for Doonesbury, along with letters, notebooks, and other archival materials, are in the collection of the Beinecke Rare Book and Manuscript Library at Yale University. Original drawings are also in the collections of the Library of Congress; the Smithsonian Institute's Museum of American History; the National Portrait Gallery; the National Museum of Health and Medicine; and the Billy Ireland Cartoon Library and Museum at Ohio State University.

Honorary degrees

 * 1976 – Yale University
 * 1977 – Grinnell College
 * 1978 – Clarkson College
 * 1979 – Colgate University
 * 1979 – Long Island University
 * 1979 – University of Pennsylvania
 * 1979 – Lewis and Clark University
 * 1980 – Lafayette College
 * 1981 – University of Vermont
 * 1981 – Colby College
 * 1981 – Wittenberg University
 * 1982 – Williams College
 * 1982 – Wheaton College
 * 1982 – William and Mary College
 * 1983 – DePauw University
 * 1983 – Fairleigh Dickinson University
 * 1984 – Western Maryland College (now McDaniel College)
 * 1986 – Wake Forest University
 * 1986 – Rensselaer Polytechnic Institute
 * 1987 – Smith College
 * 1987 – SUNY Potsdam
 * 1988 – Duke University
 * 1990 – Johns Hopkins University
 * 1990 – Wheelock College (now merged with Boston University)
 * 1997 – Colorado College
 * 1997 – CCS College of Art and Design
 * 1998 – Tufts University
 * 2003 – Trinity College
 * 2007 – Muhlenberg College
 * 2007 – Goucher College
 * 2007 – Brown University
 * 2011 – University College Dublin
 * 2012 – St. Lawrence University
 * 2012 – Queens University at Kingston
 * 2016 – Marist College
 * 2017 – Macaulay College
 * 2024 - New England College

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title: Garry Trudeau