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Antigonish—Guysborough

Antigonish—Guysborough was a federal electoral district in Nova Scotia, Canada, that was represented in the House of Commons of Canada from 1917 to 1968.

This riding was created in 1914 and combined the former ridings of Antigonish and Guysborough. Antigonish—Guysborough was abolished under redistribution in 1966 forming parts of Cape Breton Highlands—Canso and Central Nova.

Members of Parliament
This riding has elected the following members of Parliament:

title: Antigonish—Guysborough


text:
Cape Breton South and Richmond

Cape Breton South and Richmond was a federal electoral district in the province of Nova Scotia, Canada, that was represented in the House of Commons of Canada from 1917 to 1925. This riding was created in 1917 by a statute passed in 1914 from Cape Breton South and Richmond ridings. It consisted of the electoral district of South Cape Breton and the county of Richmond. It was abolished with a law passed in 1924 and carried out in 1925, when it was redistributed into Cape Breton South and Richmond—West Cape Breton. The riding was a dual-member constituency—it elected two members to Parliament.

Members of Parliament
This riding elected the following members of Parliament:

license: Creative Commons - Attribution Share-Alike - https://creativecommons.org/licenses/by-sa/4.0/

title: Cape Breton South and Richmond


text:
Organopalladium chemistry

Organopalladium chemistry is a branch of organometallic chemistry that deals with organic palladium compounds and their reactions. Palladium is often used as a catalyst in the reduction of alkenes and alkynes with hydrogen. This process involves the formation of a palladium-carbon covalent bond. Palladium is also prominent in carbon-carbon coupling reactions, as demonstrated in tandem reactions.

Organopalladium chemistry timeline

 * 1873 - A. N. Zaitsev reports reduction of benzophenone over palladium with hydrogen.
 * 1894 - Phillips reports that palladium(II) chloride reduces to palladium metal by contact with ethylene.
 * 1907 - Autoclave technology introduced by Vladimir Ipatieff makes it possible to carry out high pressure hydrogenation.
 * 1956 - In the Wacker process ethylene and oxygen react to acetaldehyde with catalyst PdCl2/CuCl2
 * 1957 - Tetrakis(triphenylphosphine)palladium(0) is reported by Malatesta and Angoletta.
 * 1972 - The Heck reaction is a coupling reaction of a halogenide with an olefin. Pd(0) intermediates are implicated.
 * 1973 - The Trost asymmetric allylic alkylation is a nucleophilic substitution.
 * 1975 - The Sonogashira coupling is a coupling reaction of terminal alkynes with aryl or vinyl halides.
 * 1994 - The Pd-catalyzed Buchwald-Hartwig amination for C-N bond-forming reactions.

Alkene complexes
Unlike Ni(II), but similar to Pt(II), Pd(II) halides form a variety of alkene complexes. The premier example is dichloro(1,5‐cyclooctadiene)palladium. In this complex, the diene is easily displaced, which makes it a favored precursor to catalysts. In the industrially important Wacker process, ethylene is converted to acetaldehyde via nucleophilic attack of hydroxide on a Pd(II)-ethylene intermediate followed by formation of a vinyl alcohol complex. Fullerene ligands also bind with palladium(II).

Palladium(II) acetate and related compounds are common reagents because the carboxylates are good leaving groups with basic properties. For example palladium trifluoroacetate has been demonstrated to be effective in aromatic decarboxylation:

Allyl complexes
The iconic complex in this series is allylpalladium chloride dimer (APC). Allyl compounds with suitable leaving groups react with palladium(II) salts to pi-allyl complexes having hapticity 3. These intermediates too react with nucleophiles for example carbanions derived from malonate esters or with amines in allylic amination as depicted below

 * AllylicAmination.svg

Allylpalladium intermediates also feature in the Trost asymmetric allylic alkylation and the Carroll rearrangement and an oxo variation in the Saegusa oxidation.

Palladium-carbon sigma-bonded complexes
Various organic groups can bound to palladium and form stable sigma-bonded complexes. The stability of the bonds in terms of bond dissociation energy follows the trend: Pd-Alkynyl > Pd-Vinyl ≈ Pd-Aryl > Pd-Alkyl and the metal-carbon bond length changes in the opposite direction: Pd-Alkynyl < Pd-Vinyl ≈ Pd-Aryl <  Pd-Alkyl.

Palladium(0) compounds
Zerovalent Pd(0) compounds include tris(dibenzylideneacetone)dipalladium(0) and tetrakis(triphenylphosphine)palladium(0). These complexes react with halocarbon R-X in oxidative addition to R-Pd-X intermediates with covalent Pd-C bonds. This chemistry forms the basis of a large class of organic reactions called coupling reactions (see palladium-catalyzed coupling reactions). An example is the Sonogashira reaction:

 * Sonogashira reaction mechanism.png

Organopalladium(IV)
The first organopalladium(IV) compound was described in 1986. This complex is Me3Pd(IV)(I)bpy (bpy = bidentate 2,2'-bipyridine ligand) It was synthesized by oxidative addition of methyl iodide to Me2Pd(II)bpy.

Palladium compounds owe their reactivity to the ease of interconversion between Pd(0) and palladium(II) intermediates. There is no conclusive evidence however for the involvement of Pd(II) to Pd(IV) conversions in palladium mediated organometallic reactions. One reaction invoking such mechanism was described in 2000 and concerned a Heck reaction. This reaction was accompanied by a 1,5-hydrogen shift in the presence of amines:

 * HeckReactionWang2000.svg

The hydride shift was envisaged as taking place through a Pd(IV) metallacycle:

 * HeckReactionWang2000Mechanism.svg

In related work the intermediate associated with the hydride shift remains Pd(II):

 * OrganopalladiumShiftKarig2002.svg

and in other work (a novel synthesis of indoles with two Pd migrations) equilibria are postulated between different palladacycles:

 * CPd shift Larock 2004 rev.svg

and in certain intramolecular couplings synthetic value was demonstrated regardless of oxidation state:

 * OrganopalladiumMigrationHuang2004.svg

title: Organopalladium chemistry


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Digby and Annapolis

Digby and Annapolis was a federal electoral district in the province of Nova Scotia, Canada, that was represented in the House of Commons of Canada from 1917 to 1935.

This riding was created in 1914 from parts of Digby and Annapolis ridings. It consisted of the county of Annapolis and the county of Digby without the municipality of Clare. In 1924, the municipality of Clare was added to the riding, so that it consisted of the counties of Digby and Annapolis. Its name was changed in 1924 to Digby—Annapolis.

The riding was abolished in 1933 when it was divided between Digby—Annapolis—Kings and Shelburne—Yarmouth—Clare ridings.

Members of Parliament
This riding elected the following members of Parliament:

title: Digby and Annapolis


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W. H. L. Wallace

William Hervey Lamme Wallace (July 8, 1821 – April 10, 1862), more commonly known as W. H. L. Wallace, was a lawyer and a Union general in the American Civil War, considered by Ulysses S. Grant to be one of the Union's greatest generals.

Early life
Wallace was born in Urbana, Ohio on July 8, 1821, the son of John and Mary Lamme Wallace. In 1840, his family moved to Mount Morris, Illinois for a better education where Rock River Seminary was located.

Education and career
Although he planned to study law with Abraham Lincoln in Springfield, he joined Theophilus Lyle Dickey's practice in Ottawa, Illinois, instead. (Dickey was a friend of Lincoln's and would eventually be a justice of the Illinois Supreme Court.) Wallace became licensed in law in 1846 and that same year he joined the 1st Illinois Infantry as a private. He rose to the rank second lieutenant and adjutant and participated in the Battle of Buena Vista along with a few other minor engagements. After this brief experience in the Mexican–American War, he became district attorney in 1853.

Civil War service and death
At the start of the Civil War, Wallace volunteered as a private with the 11th Illinois Infantry, which was assembled in Springfield. He was then elected the unit's colonel. He rose up the ranks and commanded a brigade of Brig. Gen. John A. McClernand's division of Grant's Army of the Tennessee at the Battle of Fort Donelson in 1862. During the battle, much of McClernand's division had been driven back with heavy losses and Wallace's coolness under fire was especially noted. Brig. Gen. Lew Wallace described the colonel as looking like a "farmer coming from a hard day's plowing". After this first time meeting upon the Fort Donelson battlefield, the two quickly learned each possessed the same surname and had commanded their respective states' 11th regiments, prompting Lew Wallace to muse the coincidence must have caused "great profanity in the army post office".

For his service at Fort Donelson, Colonel Wallace was appointed a brigadier general of volunteers. During the expedition to Savannah, Tennessee, Maj. Gen. Charles Ferguson Smith injured his leg and was forced to turn over command of his division to Wallace. At the Battle of Shiloh, Wallace was a new division commander, yet he managed to withstand six hours of assaults by the Confederates, directly next to the famous Hornet's Nest, or Sunken Road. When his division was finally surrounded, he ordered a withdrawal and many escaped, but he was wounded and only later found barely alive on the battlefield by his troops. They carried him to his wife, who coincidentally had arrived for a surprise visit to her husband on the very morning of the battle. She helped tend to him on the way back to General Grant's headquarters in the Cherry Mansion in Savannah, Tennessee. He died three days later in his wife's arms; his last words were "We meet in heaven." He is buried in LaSalle County, Illinois, in Ottawa.

He was the brother of future Brevet Brigadier General Martin R. M. Wallace.

Personal life
In 1851 he married Dickey's daughter, Martha Ann.

Tribute
Wallace County, Kansas, was named in his honor in 1868.

title: W. H. L. Wallace


text:
Yarmouth and Clare

Yarmouth and Clare was a federal electoral district in Nova Scotia, Canada, that was represented in the House of Commons of Canada from 1917 to 1925. This riding was created in 1914 from Digby and Yarmouth ridings. It consisted of the County of Yarmouth and the municipality of Clare. It was abolished in 1924 when it was redistributed into Digby and Annapolis and Shelburne—Yarmouth ridings.

Members of Parliament
This riding elected the following members of Parliament:

title: Yarmouth and Clare


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title: Template:User id-1


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Restigouche—Madawaska

Restigouche—Madawaska was a federal electoral district in New Brunswick, Canada, that was represented in the House of Commons of Canada from 1917 to 1968.

This riding was created in 1914 from parts of Restigouche and Victoria ridings.

With the 1966 redistribution, Madawaska County was moved to the new Madawaska—Victoria riding, while Restigouche County became the district of Restigouche.

Members of Parliament
This riding elected the following members of Parliament:

Election results

 * bgcolor="EEBBBB"|
 * Farmer-Labour
 * John Lewis Gordon Annett
 * align="right"|2,117
 * align="right"|10.8
 * align="right"|*
 * align="right"|*

title: Restigouche—Madawaska


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Victoria—Carleton

Victoria—Carleton was a federal electoral district in New Brunswick, Canada, that was represented in the House of Commons of Canada from 1917 to 1968.

This riding was created in 1914 from Carleton and Victoria ridings. It was first used in the Canadian federal election of 1917. It was abolished in 1966 when it was redistributed into Carleton—Charlotte and Madawaska—Victoria ridings.

Members of Parliament
This riding elected the following members of the House of Commons of Canada:

title: Victoria—Carleton


text:
User:David Newton/SVG Graphics/USN Jack

This is the SVG for the United States Navy Jack. It is the based on the American Flag at Open Clip Art which is public domain. This code is also released into the public domain.

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title: User:David Newton/SVG Graphics/USN Jack


text:
Category:Organometallic chemistry

Organometallic chemistry is the study of chemical compounds containing bonds between carbon and a metal.

The term "metal" is defined deliberately broadly in this context and may include elements, such as silicon or boron, which are not metallic but are considered to be metalloids. Organometallic chemistry combines aspects of inorganic chemistry and organic chemistry.

title: Category:Organometallic chemistry


text:
Châteauguay—Huntingdon

Châteauguay—Huntingdon was a federal electoral district in Quebec, Canada, that was represented in the House of Commons of Canada from 1917 to 1949.

History
This riding was created in 1914 from Châteauguay and Huntingdon ridings.

It initially consisted of the Counties of Châteauguay and Huntingdon.

In 1933, it was redefined to consist of:
 * the county of Châteauguay except the municipalities of Ste-Philomène, St-Joachim, and the towns of De Léry and of Châteauguay;
 * the county of Huntingdon except the municipality of Ste-Barbe;
 * in the county of Beauharnois, the municipality of St-Etienne; and
 * in the county of St. Johns, the municipalities of St-Bernard-de-Lacolle, Notre-Dame-du-Mont-Carmel and the village of Lacolle.

It was abolished in 1947 when it was merged into Châteauguay—Huntingdon—Laprairie.

Members of Parliament
This riding elected the following members of Parliament:

Election results
By-election: On Mr. Robb accepting an office of emolument under the Crown, 29 December 1921

By-election: On Mr. Robb accepting an office of emolument under the Crown, 5 October 1926

By-election: On Mr. Robb's death, 11 November 1929

title: Châteauguay—Huntingdon


text: User talk:82.33.127.46

title: User talk:82.33.127.46


text:
George-Étienne Cartier (electoral district)

George-Étienne Cartier was a federal electoral district in Quebec, Canada, that was represented in the House of Commons of Canada from 1917 to 1925.

This riding was created in 1914 from parts of Maisonneuve and St. Lawrence ridings. It consisted of the St. Louis and St. Jean Baptiste wards of the city of Montreal.

The electoral district was abolished in 1924 when it was redistributed into Cartier, St. James and St. Lawrence—St. George ridings.

It was named in honour of the Quebec politician George-Étienne Cartier.

Members of Parliament
This riding elected the following members of Parliament:


text:
L'Assomption—Montcalm

L'Assomption—Montcalm was a federal electoral district in Quebec, Canada, that was represented in the House of Commons of Canada from 1917 to 1935.

This riding was created in 1914 from parts of L'Assomption and Montcalm ridings. It consisted of the Counties of Montcalm and L'Assomption.

The district was abolished in 1933 when it was redistributed into Joliette—L'Assomption—Montcalm and Terrebonne ridings. Its only member of parliament was Paul-Arthur Séguin of the Liberal Party of Canada.

Members of Parliament
This riding elected the following members of Parliament:

title: L'Assomption—Montcalm


text:
Wikipedia:Peer review/LinuxQuestions.org/archive1

LinuxQuestions.org
The consensus on Votes for deletion/LinuxQuestions.org is currently for a Keep and Expand, so I'd like someone knowledgeable on the subject to do so. Master Thief Garrett 22:20, 24 Apr 2005 (UTC)
 * Archived, poster has been advised to put it on Requests for expansion instead.--Bishonen | talk 12:56, 25 Apr 2005 (UTC)


text:
Laurier—Outremont

Laurier—Outremont was a federal electoral district in Quebec, Canada, that was represented in the House of Commons of Canada from 1917 to 1935.

This riding was created in 1914 from parts of Jacques Cartier, St. Antoine and St. Lawrence ridings.

It initially consisted of Laurier and Outremont wards, Côte-des-Neiges ward, the town of Mount Royal, Mount Royal ward and Mount Royal Park of the city of Montreal.

In 1924, it was redefined to consist of the city of Outremont, and the part of the city of Montreal bounded by a line starting from the north-eastern boundary of the city of Outremont, following Mount Royal Avenue, Henri Julien Avenue, Mozart Street, Drolet Street, the extension of Isabeau Street. St. Lawrence Boulevard, Baby Street, the Canadian Pacific Railway track,  Atlantic Avenue, to the northern limit of the city of Outremont, and along that boundary to Mount Royal Avenue.

The electoral district was abolished in 1933 when it was divided into Laurier and Outremont ridings.

Members of Parliament
This riding elected the following members of Parliament:

Election results
By-election: Acceptance by the Honourable Sir Lomer Gouin of an office of emolument under the Crown, 29 December 1921

title: Laurier—Outremont